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Orient, O.

Publications and source records attributed to Orient, O..

21 records · Page 2

Observation of CH A->X, Cn B->X, and NH A->X Emissions in Gas-phase Collisions of Fast O ((sup 3)P) Atoms with Hydrazines

Optical emissions in single-collision reactions of fast (20 eV laboratory translational energy) O((sup 3)P) atoms with hydrazine, methylhydrazine, and 1,1-dimethylhydrazine have been measured in a crossed-beams geometry. The emissions were observed in the wavelength range 325-440 nm, and were identified as the CH (A 2(sub A))-->X(sup 2)pi(sub r), (for methylhydrazine), CN (B sup 2) Sigma(sup +) --> X(sup 2) Sigma(sup +) (for methylhydrazine)and NH(A(sup 3)pi --> X(sup3 Sigma) transitions (for all three hydraz vibration-rotation bands were fit to a synthetic spectrum of CH, CN and NH with given vibrational and rotational temperatures.

chemical reactions

High-Flux Atomic-Oxygen Source

Beams of pure ground-state oxygen atoms produced. Accelerated electrons strike beam of O2 gas in dissociative-attachment region, producing O- ions. O- ions accelerated to desired final energy and pass through photodetachment region to form 0(3P) atoms. These pass between electric field plates to remove O- and e and strike target. Designed specifically to study degradation of materials and spacecraft glow phenomena in low Earth orbits, used to study gas-phase collision phenomena involving energetic oxygen atoms.

Chutjian, A.