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Orsini, N.

Publications and source records attributed to Orsini, N..

Nitric oxide in the upper stratosphere - Measurements and geophysical interpretation

A rocket-borne parachute-deployed chemiluminescence instrument has obtained seven new measurements of atmospheric nitric oxide for altitudes between 30 and 50 km at mid-latitudes. These results, when combined with profiles measured by an earlier version of the instrument, cover all four seasons and provide a more comprehensive picture of upper stratospheric nitric oxide than has been available previously. At the highest altitudes studied, the vertical gradient in mixing ratio displays positive and negative values during different observations, with the largest values tending to appear at the greatest heights in summer. Examination of the differences among the profiles, which exceed a factor of 3 near the stratopause, suggests that they arise from the action of transport processes which carry air into the mid-latitude upper stratosphere from regions of the atmosphere that contain widely different odd-nitrogen abundances.

Harvath, J. J.↗

The distribution and variability of mesospheric odd nitrogen - A theoretical investigation

Model calculations of the distribution of mesospheric odd nitrogen (NOx) predict large differences between the summer and winter hemispheres. The smallest mixing ratios occur in summer where dissociation of NO followed by recombination provides an efficient sink and creates a sharp minimum between 70 and 75 km. No such minimum occurs in the winter where a downward flux of NOx extends from the lower thermosphere into the upper stratosphere. However, dissociation still exerts a major influence on the NOx abundance in the winter hemisphere and limits the downward flow of nitric oxide to values much smaller than expected in the polar night.

Frederick, J. E.↗

Solar disturbances and mesospheric odd nitrogen

The odd nitrogen (NOx) abundance of the high latitude mesosphere exhibits a large variability in response to energetic particle precipitation. Model calculations for a very large particle event predict increases in the NOx mixing ratio that can exceed a factor of ten over time periods of the order of one week in the summer hemisphere. A more typical sized event can still lead to an enhancement of a factor of three in summer. Relative changes in the winter hemisphere are less dramatic due to a larger ambient NOx mixing ratio predicted here. However, a factor of two increase in NOx is possible during a very large event. Owing to the large variability, it is difficult to define a physically meaningful mean state profile in the high latitude mesosphere. Rather, the NOx abundance likely displays an erratic behavior which is correlated with the level of solar activity.

Orsini, N.↗

The effect of N2/+/ recombination on the aeronomic determination of the charge exchange rate coefficient of O/+//2D/ with N2

The Atmosphere Explorer (AE) data are reexamined in the light of new laboratory measurements of the N2(+) recombination rate coefficient alpha. The new measurements support earlier measurements which yielded values of alpha significantly lower than the AE values. It is found that the values for alpha determined from the satellite data can be reconciled with the laboratory measurements, if the charge exchange rate coefficient for O(+)(2D) with N2 is less than one-quarter of that derived in the laboratory by Rutherford and Vroom (1971).

Torr, D. G.↗

Charge exchange of metastable 2D oxygen ions with N2 in the thermosphere

The charge exchange of metastable 2D oxygen ions with N2 in the thermosphere is investigated through analysis of N2 (+) measurements and related data obtained by the Atmosphere Explorer-C satellite. The rate coefficient for the charge exchange process is found to be 5 + or - 1.7 times 10 to the negative 10th power cu cm per sec. A rate coefficient is also developed for atomic oxygen quenching of the metastable 2D oxygen ions.

Torr, D. G.↗

Determination of the N2 recombination rate coefficient in the ionosphere

Measurements of aeronomic parameters made by the Atmosphere Explorer-C satellite are used to determine the recombination rate coefficient of N2(+) in the ionosphere. The rate is found to increase significantly with decreasing electron density. Values obtained range from approximately 1.4 x 10 to the -7th to 3.8 x 10 to the -7th cu cm/sec. This variation is explained in a preliminary way in terms of an increase in the rate coefficient with vibrational excitation. Thus, high electron densities depopulate high vibrational levels reducing the effective recombination rate, whereas, low electron densities result in an enhancement in the population of high vibrational levels, thus, increasing the effective recombination rate.

Orsini, N.↗

Determination of the rate coefficient for the N2/+/ + O reaction in the ionosphere

Using approximately 400 simultaneous measurements of ion and neutral densities and temperatures, and the spectrum of the solar flux measured by the Atmosphere Explorer C satellite, we have determined the rate constant k1 for the reaction between N2(+) and O in the ionosphere for ion temperatures between 600 and 700 K. We find that k1 = 1.1 x 10 to the minus 10th power cu cm per sec, with a standard deviation of + or - 15%. If we use the temperature dependence for this reaction determined in the laboratory then at 300 K we find excellent agreement with the recommended laboratory value.

Torr, D. G.↗