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Peter Marshall

Publications and source records attributed to Peter Marshall.

PROTECT: Production and Reuse of Thermally Efficient Ceramic Thermal Protection Systems

PROTECT (Production and Reuse Of Thermally Efficient Ceramic TPS) is a NASA Early Career Initiative focused on developing the next generation of reusable ceramic thermal protection systems (TPS). This project addresses key challenges in TPS design, including temperature capability, thermal stability, and refurbishment time, by integrating novel material development with predictive modeling. Leveraging enhanced capabilities in NASA’s Porous Microstructure Analysis (PuMA) software, PROTECT introduces new modeling tools to predict the thermal and mechanical behavior of fibrous ceramic materials. These tools enable accurate prediction of performance metrics such as thermal conductivity and structural integrity, reducing reliance on costly physical testing. Preliminary advances in these areas will be presented. To support model validation, PROTECT is building a comprehensive database of raw material properties using advanced characterization techniques, including micro computed tomography (CT) scanning in collaboration with the University of Illinois Urbana-Champaign (UIUC). The presentation will detail the sampling workflows and analysis methods used to generate this detailed microstructural data and how it is used to develop improved models in PuMA. This multi-center collaboration, spanning NASA (JSC, ARC, KSC, GRC), Oak Ridge National Laboratory, UIUC, and SpaceX, is developing tailored TPS solutions for LEO, lunar, and Martian missions. By bridging heritage systems with the demands of modern spaceflight, PROTECT contributes to the advancement of reusable TPS technologies for future exploration missions.

Propulsion, Refractory, and Coating Materials↗

Response of Ablative Thermal Protection Materials to Degradation in Low Earth Orbit –Characterization of Specimens from MISSE-13

The environment of low Earth orbit presents unique material interactions due to the presence of atomic oxygen and solar spectrum UV. A variety of degradation mechanisms can occur depending, inlarge part, on the specific material system involved. This talk will review the characterization of two ablative materials, PICA-D and HEEET, as well as relevant adhesive joints and coatings. PICA-D is a variant of the phenolic impregnated carbon ablator (PICA) and is the baseline thermal protection system (TPS) on Dragonfly and the lander for Mars Sample Return (MSR). HEEET is a 3D woven system from which MSR’s Earth entry TPS is derived. The samples for these materials were flown in orbit during the Materials International Space Station Experiment-13 (MISSE-13) which launched on March 6, 2020 and returned to Earth on January 13, 2021. Changes to surface microstructure and reflectivity will be presented along with tomographic analysis. The effect of differential erosion rates on the composites and the impacts of the orbit environment on coating performances will be discussed in the context of TPS performance and mission design aspects.

MISSE↗

Response of Ablative Thermal Protection Materials to Degradation in Low Earth Orbit – Characterization of Specimens from MISSE-13

The environment of low Earth orbit presents unique material interactions due to the presence of atomic oxygen and solar spectrum UV. A variety of degradation mechanisms can occur depending, in large part, on the specific material system involved. This talk will review the characterization of two ablative materials, PICA-D and HEEET, as well as relevant adhesive joints and coatings. PICA-D is a variant of the phenolic impregnated carbon ablator (PICA) and is the baseline thermal protection system (TPS) on Dragonfly and the lander for Mars Sample Return (MSR). HEEET is a 3D woven system from which MSR’s Earth entry TPS is derived. The samples for these materials were flown in orbit during the Materials International Space Station Experiment-13 (MISSE-13) which launched on March 6, 2020 and returned to Earth on January 13, 2021. Changes to surface microstructure and reflectivity will be presented along with tomographic analysis. The effect of differential erosion rates on the composites and the impacts of the orbit environment on coating performances will be discussed in the context of TPS performance and mission design aspects.

MISSE↗

New Development Activities at NASA Ames in Reusable TPS Materials

Over the last few years, new activities in rapid, low-cost access to low-earth orbit (LEO) and hypersonic flight have refreshed interest in reusable thermal protection systems (RTPS) that have not had broad application since the Space Shuttle era. Development of novel systems having a greater consideration of full cycle cost (lower cost raw materials, manufacturing, integration, and refurbishment) in addition to improved performance are needed to enable this new generation of space flight. NASA Ames has a long history of RTPS development including invention of flexible blankets such as Advanced Flexible Reusable Surface Insulation (AFRSI), rigid ceramic tiles like Fibrous Refractory Composite Insulation (FRCI) and Alumina Enhanced Thermal Barrier (AETB), and multi-component systems like Toughened Uni-piece Fibrous Reinforced Oxidation-resistant Composite (TUFROC). In much more recent times, NASA Ames is supporting the growing commercial space field through internal research and development efforts for high-risk low TRL materials and collaboration with commercial partners including technology transfer. This talk will discuss the current development efforts that span broadly from updating legacy insulating systems with modern raw materials and processes to totally novel designs for heat pipes with various low-TRL activities in between. It will also discuss Ames’ recent re-investment in experimental capabilities to enable characterization and material testing.

Reusable thermal protection materials↗

New Development Activities at NASA Ames in Reusable TPS Materials

Over the last few years, new activities in rapid, low-cost access to low-earth orbit (LEO) and hypersonic flight have refreshed interest in reusable thermal protection systems (RTPS) that have not had broad application since the Space Shuttle era. Development of novel systems having a greater consideration of full cycle cost (lower cost raw materials, manufacturing, integration, and refurbishment) in addition to improved performance are needed to enable this new generation of space flight. NASA Ames has a long history of RTPS development including invention of flexible blankets such as Advanced Flexible Reusable Surface Insulation (AFRSI), rigid ceramic tiles like Fibrous Refractory Composite Insulation (FRCI) and Alumina Enhanced Thermal Barrier (AETB), and multi-component systems like Toughened Uni-piece Fibrous Reinforced Oxidation-resistant Composite (TUFROC). In much more recent times, NASA Ames is supporting the growing commercial space field through internal research and development efforts for high-risk low TRL materials and collaboration with commercial partners including technology transfer. This talk will discuss the current development efforts that span broadly from updating legacy insulating systems with modern raw materials and processes to totally novel designs for heat pipes with various low-TRL activities in between. It will also discuss Ames’ recent re-investment in experimental capabilities to enable characterization and material testing.

Reusable thermal protection materials↗

Developments on Reusable TPS Materials Based Upon Shuttle Tile

The insulating tiles used on the Space Shuttler Orbiter, principally AETB (Alumina Enhanced Thermal Barrier), have been seen by new vehicle developers in the aerospace industry as a fast-track approach for fielding a reusable thermal protection system (TPS) given the extensive use by both the Orbiter program and the current Orion vehicle. NASA has, and is, supporting the industry through technology transfer and commercial crew and payloads programs. However, the reusable TPS community is rapidly encountering challenges rooted in Orbiter’s and Orion’s dependence on legacy material and processes. With the aim of alleviating these issues, improving availability of reusable TPS, and strengthening the nation’s space economy, ongoing efforts at NASA Ames have focused on understanding process-property relationships in AETB as well as novel materials and technologies for reusable TPS. The first portion of this talk will address the effects of raw materials and processing conditions on the properties of AETB-8, including the raw materials used, mixing and casting parameters, and thermal history. Understanding these relationships, and how they extend to aerothermal performance, is instrumental in alleviating supply chain constraints and improving manufacturability. The implications of these finding on development of novel TPS materials and systems will be discussed. AETB will likely continue to fill a niche of relatively high performance with associated costs. There exists, therefore, a gap in developed reusable TPS for a lower cost, moderate performing material system. The later portion of this talk will touch on current development efforts at Ames focusing on reduced cost and ease of integration, which are being pursued in addition to AETB and higher performing systems. In addition to summarizing these efforts, an outlook for these projects and collaborations will be given.

Thermal Protection Systems↗

Modernization of Insulative Reusable Thermal Protection Systems (IRTPS)

Insulative thermal protection systems, such as Flexible Reusable Surface Insulation blankets and High Temperature Reusable Surface Insulation tiles, were developed for the Shuttle Orbiter to enable reuse of the vehicle for low-earth orbit missions. Since reusability is essential to many new industry launch and space vehicles, Shuttle-derived thermal protection materials (TPMs) are being sought for their flight proven performance. Alumina Enhanced Thermal Barrier (AETB) is the state-of-the-art tile material that was developed in the 90’s. AETB along with associated coatings, reaction cured glass (RCG) and Toughened Unipiece Fibrous Insulation (TUFI), are currently made by NASA using heritage raw materials derived from lifetime purchases. Finding viable replacements for raw materials that have changed in nature or are obsolete is important for continuation of these TPMs. In some cases, the use of modern raw materials has been shown to yield tile with reduced performance, most notably in mechanical properties. ​ In this work, the production of AETB will be discussed to better understand the process-structure-property relationships and for allowing use of these modern alternatives. A small-scale tile casting system was developed for rapid and efficient exploration of the manufacturing variables such raw material selection and pre-processing, casting process parameters, and billet firing protocols. An optical transmission defect characterization technique was implemented to correlate process variables to structure. Comparisons between TUFI/RCG coated AETB derived from heritage and modern raw materials will be shown including AHF arc jet test results completed under a collaboration with Stratolaunch.

thermal protection materials↗

Nasa’S Development of Merino - A New Family of Advanced, Low-Cost, Non-Woven Ablative Tps Materials

The Mars Exploration Program (MEP) and NASAs Space Technology Mission Directorate (STMD) are investing in approaches to reduce the cost and increase the frequency of future Mars missions while also seeking to help emerging commercial space companies which have an immediate need to demonstrate their capability to return samples from space - at a fraction of the cost of a conventional NASA mission. Of particular interest and relevance to commercial space and low-cost Mars, is the work developing and advancing MERINO-LD, an ablative carbon/phenolic blanket that is ~75% faster to produce with an estimated ~75% reduction in cost when compared to rigid PICA or Conformal-PICA TPS.

Matthew Gasch↗

Three Dimensionally Woven Mid-Density Carbon Phenolic (3MDCP) is a Novel Single Piece Ablative TPS for Extreme Entry Environments

Three Dimensionally Woven Mid-Density Carbon Phenolic (3MDCP) is robust, single piece, carbon phenolic ablative thermal protection system under development at NASA Ames Research Center initially for the Mars Sample Return Earth Entry System (MSR EES). The MSR EES requirements drove the need for TPS with no seams, capable of surviving the highest entry conditions for any NASA Earth return capsule with heat fluxes >2000 W/cm2 and pressures >1.5 atmospheres. To produce 3MDCP required development of new weaving infrastructure to enable weaving of preforms large enough to form into a single piece heatshield. It required development of forming techniques to transform a flat woven panel into a sphere cone shape and enhanced infusion processes to support larger scale infusion of resin into the formed preforms. A rigorous performance testing campaign was conducted to develop and validate the materials thermal response model used to determine the required material thickness and to demonstrate the material can survive the extreme entry conditions. The end of the development effort (end of FY26) will result in a TPS at Technical Readiness Level (TRL) 6 and Manufacturing Readiness Level (MRL) 6+ for the MSR EES mission and a mature system ready to support other missions. This poster will provide a snapshot of where 3MDCP is in its development phase.

Ablator↗