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Pickett, Herbert M.

Publications and source records attributed to Pickett, Herbert M..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2007

Terahertz local oscillator for the Microwave Limb Sounder on the Aura satellite

The Microwave Limb Sounder on the Aura satellite has a radiometer at 2.5 THz to perform global mapping of OH in the atmosphere. The OH radiometer utilizes two Schottky-diode mixers pumped by an optically pumped THz gas laser local oscillator. The laser was first turned on in space on July 22, 2004, and has performed without issue for more than 30 months. The specifications, design, and modeling of this 2.5 THz laser local oscillator are presented here, along with some of the important design validation and test results.

Pickett, Herbert M.↗
NASA NTRS2006

The Earth Observing System Microwave Limb Sounder (EOS MLS) on the Aura Satellite

The Earth Observing System Microwave Limb Sounder measures several atmospheric chemical species (OH, HO2, H2O, O3, HCl, ClO, HOCl, BrO, HNO3, N2O, CO, HCN, CH3CN, volcanic SO2), cloud ice, temperature, and geopotential height to improve our understanding of stratospheric ozone chemistry, the interaction of composition and climate, and pollution in the upper troposphere. All measurements are made simultaneously and continuously, during both day and night. The instrument uses heterodyne radiometers that observe thermal emission from the atmospheric limb in broad spectral regions centered near 118, 190, 240, and 640 GHz, and 2.5 THz. It was launched July 15, 2004 on the National Aeronautics and Space Administration's Aura satellite and started full-up science operations on August 13, 2004. An atmospheric limb scan and radiometric calibration for all bands are performed routinely every 25 s. Vertical profiles are retrieved every 165 km along the suborbital track, covering 82 S to 82 N latitudes on each orbit. Instrument performance to date has been excellent; data have been made publicly available; and initial science results have been obtained.

submillimeter wave↗
NASA NTRS2005

On Orbit Commissioning of the Earth Observing System Microwave Limb Sounder (EOS MLS) On the Aura Spacecraft

The Microwave Limb Sounder instrument was launched aboard NASA's EOS AURA satellite in July, 2004. The overall scientific objectives for MLS are to measure temperature, pressure, and several important chemical species in the upper troposphere and stratosphere relevant to ozone processes and climate change. MLS consists of a suite of radiometers designed to operate from 11 8 GHz to 2.5 THz, with two antennas (one for 2.5 THz, the other for the lower frequencies) that scan vertically through the atmospheric limb, and spectrometers with spectral resolution of 6 MHz at spectral line centers. This paper describes the on-orbit commissioning the MLS instrument which includes activation and engineering functional verifications and calibrations.

Earth observing system (EOS)↗
NASA NTRS2005

EOS Aura MLS, first year post-launch engineering assessment

This paper discusses the current status of the MLS instrument which now continuously provides data to produce global maps of targeted chemical species as well as temperature, cloud ice, and gravity wave activity. Performance trends are assessed with respect to characterization during initial on-orbit activiation of the instrument, and with data from ground test verification prior to launch.

Microwave Limb Sounder (MLS)↗
NASA NTRS2000

THz Spectroscopy of the Atmosphere

THz spectroscopy of the atmosphere has been driven by the need to make remote sensing measurements of OH. While the THz region can be used for sensitive detection on many atmospheric molecules, the THz region is the best region for measuring the diurnal behavior of stratospheric OH by remote sensing. The infrared region near 3 microns suffers from chemiluminescence and from spectral contamination due to water. The ultraviolet region near 300 nm requires solar illumination. The three techniques for OH emission measurements in the THz region include Fourier Transform interferometry, Fabry-Perot interferometry, and heterodyne radiometry. The first two use cryogenic direct detectors while the last technique uses a local oscillator and a mixer to down convert the THz signal to GHz frequencies. All techniques have been used to measure stratospheric OH from balloon platforms. OH results from the Fabry-Perot based FILOS instrument will be given. Heterodyne measurement of OH at 2.5 THz has been selected to be a component of the Microwave Limb Sounder on the Earth Observing System CHEM-1 polar satellite. The design of this instrument will be described. A balloon-based prototype heterodyne 2.5 THz radiometer had its first flight on, 24 May 1998. Results form this flight will be presented.

Pickett, Herbert M.↗
NASA NTRS2000

An Analysis of the Torsion-Rotation-Vibration Rotational Spectrum of the Lowest In-Plane Bend and First Excited Torsional State of the C(3V) Internal Rotor C2H5CN

C2H5CN (Propionitrile or ethyl cyanide) is a well known interstellar species abundantly observed in hot cores during the onset of star formation. The onset of star formation generally results in elevated temperature, which thermally populates may low lying vibrational states such as the 206/cm in-plane bend and the 212/cm first excited torsional state in C2H5CN. Unfortunately, these two states are strongly coupled through a complex series of torsion-vibration-rotation interactions, which dominate the spectrum. In order to understand the details of these interactions and develop models capable of predicting unmeasured transitions for astronomical observations in C2H5CN and similar molecules, several thousand rotational transitions in the lowest excited in-plane bend and first excited torsional state have been recorded, assigned and analyzed. The analysis reveals very strong a- and b-type Coriolis interactions and a number of other smaller interactions and has a number of important implications for other C3V torsion-rotation-vibration systems. The relative importance and the physical origins of the coupling among the rotational, vibrational and torsional motions will be presented along with a full spectroscopic analysis and supporting astronomical observations.

Pearson, J. C.↗
NASA NTRS1999

Construction and Calibration of a Difference Frequency Laser Spectrometer and New THZ Frequency Measurements of water and Ammonia

A three laser system based on 852nm DBR lasers has been constructed and used to generate radiation in the 750 GHz to 1600 GHz frequency region. The system works by locking two of the three lasers to modes of an ultra low expansion Fabry-Perot cavity. The third laser is offset locked to one of the cavity locked lasers with conventional microwave techniques. The signal from the offset laser and the other cavity locked laser are injected into a Master Oscillator Power Amplifier (MOPA), amplified and focused on a low temperature grown GaAs photomixer, which radiates the difference frequency. The system has been calibrated with molecular lines to better than one part in 10(exp 7). In this paper we present the application of this system to the v(sub 2) in inversion band of Ammonia and the ground and v(sub 2) states of water. A discussion of the system design, the calibration and the new spectral measurements will be presented.

Pearson, J. C.↗
NASA NTRS1993

Far-Infrared Spectrometer Measures Stratospheric Hydroxyl

Far Infrared Limb Observing Spectrometer is balloon-borne instrument measuring far-infrared emission from limb of atmosphere. Operates in two spectral channels in wave-number range of 101 to 118 cm(to the negative 1st power). Range contains spectral lines of several molecules and radicals of current scientific interest. Instrument designed primarily to obtain data on distribution of hydroxyl radicals, which play central role in chemistry of ozone in stratosphere. Measurements contribute to understanding of "ozone hole" in stratosphere.

Peterson, Dean B.↗
NASA NTRS1993

Far-IR Fabry-Perot spectrometer for OH measurements

The Far Infrared Limb Observing Spectrometer (FILOS) is an instrument designed to measure chemical species in the upper atmosphere using limb emission in the FIR region of the spectrum. FILOS uses three Fabry-Perot etalons in series to obtain a resolution of 0.0017/cm near 100/cm (100 microns). It is compact and has low power and low data rate requirements so that it may be flown as an auxiliary balloon payload with larger instruments. FILOS has two 0.05/cm bandwidth channels which are currently tuned to a HCl line at 104.2/cm and a pair of OH lines at 101.3/cm. The instrument is described in further detail and results are presented from two recent balloon flights in which OH was measured as a function of time on one hour centers from sunrise to sunset.

Pickett, Herbert M.↗
NASA NTRS1990

High resolution spectroscopy in the microwave and far infrared

High resolution rotational spectroscopy has long been central to remote sensing techniques in atmospheric sciences and astronomy. As such, laboratory measurements must supply the required data to make direct interpretation of data for instruments which sense atmospheres using rotational spectra. Spectral measurements in the microwave and far infrared regions are also very powerful tools when combined with infrared measurements for characterizing the rotational structure of vibrational spectra. In the past decade new techniques were developed which have pushed high resolution spectroscopy into the wavelength region between 25 micrometers and 2 mm. Techniques to be described include: (1) harmonic generation of microwave sources, (2) infrared laser difference frequency generation, (3) laser sideband generation, and (4) ultrahigh resolution interferometers.

Pickett, Herbert M.↗
NASA NTRS1989

The rotational spectrum and structure of chlorine peroxide

The dimerization products of the ClO + ClO reaction were investigated in a flowing chemical reactor using submillimeter wave spectroscopy. The major products were identified as the chlorine peroxide (Cl2O2) and chlorine dioxide (OClO). The rotational constants as well as a complete set of quartic centrifugal distortion constants were determined. The identification of the chlorine peroxide supports the earlier proposed ClO-dimer mechanisms, which partly explain the ozone hole formation during the Antarctic springtime.

Birk, Manfred↗
NASA NTRS1989

Stable 1.25-W CW Methanol Laser

Far-infrared (FIR) laser operating at 119-micrometer-wavelength transition of methanol achieves very low drift in frequency. Continuous-wave (CW) FIR output is 1.25 W when laser pumped by 125-W commercial CO2 laser. Rate of drift of output frequency less than plus or minus 100 kHz per hour because laser designed to have low thermal-expansion coefficients and because temperatures of input and output couplers held within 0.1 degree C of fixed values.

Farhoomand, Jam↗
NASA NTRS1988

The measurement of absolute absorption of millimeter radiation in gases - The absorption of CO and O2

An apparatus is described that will measure absolute absorption of millimeter radiation in gases. The method measures the change in the quality factor of a Fabry-Perot resonator with and without gas present. The magnitude of the change is interpreted in terms of the absorption of the lossy medium inside the resonator. Experiments have been performed on the 115-GHz CO line and the 119-GHz O2 line at two different temperatures to determine the linewidth parameter and the peak absorption value. These numbers can be combined to give the integrated intensity which can be accurately calculated from results of spectroscopy measurements. The CO results are within 2 percent percent of theoretically predicted valves. Measurements on O2 have shown that absorption can be measured as accurately as 0.5 dB/km with this technique. Results have been obtained for oxygen absolute absorption in the 60-80-GHz region.

Read, William G.↗
NASA NTRS1988

A dual-frequency 183/380 GHz receiver for airborne applications

A complete dual-frequency cryogenic heterodyne receiver operating at 183 and 380 GHz is described. The cooled mixers are whisker-contacted GaAs Schottky diodes mounted in reduced-height fundamental-mode waveguide. The local oscillators are Gunn-oscillator-driven multipliers using GaAs varactor diodes as the harmonic generators. Quasi-optical techniques are used extensively for coupling the remote and local oscillator signals into the mixers. The overall system double side-band (DSB) noise temperature is 320 K for the 183-GHz receiver and 650 K for the 380 GHz receiver.

Batelaan, Paul D.↗
NASA NTRS1988

A stable, high power optically pumped far infrared laser system

The generation of 1.25 watts of CW laser power at the 119-micron (2522.8 GHz) methanol line is reported. The maximum frequency fluctuation of the free running laser is less than + or - 100 kHz per hour. This laser has also been tested on numerous other lines ranging from 403.7 GHz (HCOOH) to 5260 GHz (CH3OD) with improved power and stability.

Farhoomand, Jam↗
NASA NTRS1987

Method and means for generation of tunable laser sidebands in the far-infrared region

A method for generating tunable far-infrared radiation is described. The apparatus includes a Schottky-barrier diode which has one side coupled through a conductor to a waveguide that carries a tunable microwave frequency; the diode has an opposite side which is coupled through a radiating whisker to a bias source. Infrared light is directed at the diode, and infrared light with tunable sidebands is radiated by the whisker through an open space to a reflector. The original infrared is separated from a tunable infrared sideband by a polarizing Michelson interferometer.

Pickett, Herbert M.↗