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Pines, A.

Publications and source records attributed to Pines, A..

6 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Hyperpolarized relaxometry based nuclear T 1 noise spectroscopy in diamond

The origins of spin lifetimes in quantum systems is a matter of importance in several areas of quantum information. Spectrally mapping spin relaxation processes provides insight into their origin and motivates methods to mitigate them. In this paper, we map nuclear relaxation in a prototypical system of 13 C nuclei in diamond coupled to Nitrogen Vacancy (NV) centers over a wide field range (1 mT-7 T). Nuclear hyperpolarization through optically pumped NV electrons allows signal measurement savings exceeding million-fold over conventional methods. Through a systematic study with varying substitutional electron (P1 center) and 13 C concentrations, we identify the operational relaxation channels for the nuclei at different fields as well as the dominant role played by 13 C coupling to the interacting P1 electronic spin bath. These results motivate quantum control techniques for dissipation engineering to boost spin lifetimes in diamond, with applications including engineered quantum memories and hyperpolarized 13 C imaging.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2017

Optically detected magnetic resonance of nitrogen vacancies in a diamond anvil cell using designer diamond anvils

Optically detected magnetic resonance of nitrogen vacancy centers in diamond offers a route to both DC and AC magnetometry in diamond anvil cells under high pressures (>3 GPa). However, a serious challenge to realizing experiments has been the insertion of microwave radiation into the sample space without screening by the gasket material. We utilize designer anvils with lithographically deposited metallic microchannels on the diamond culet as a microwave antenna. We detected the spin resonance of an ensemble of microdiamonds under pressure and measured the pressure dependence of the zero field splitting parameters. Furthermore, these experiments enable the possibility for all-optical magnetic resonance experiments on nanoliter sample volumes at high pressures.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Measuring molecular parity nonconservation using nuclear-magnetic-resonance spectroscopy

Here, the weak interaction does not conserve parity and therefore induces energy shifts in chiral enantiomers that should in principle be detectable in molecular spectra. Unfortunately, the magnitude of the expected shifts are small and in spectra of a mixture of enantiomers, the energy shifts are not resolvable. We propose a nuclear-magnetic-resonance (NMR) experiment in which we titrate the chirality (enantiomeric excess) of a solvent and measure the diasteriomeric splitting in the spectra of a chiral solute in order to search for an anomalous offset due to parity nonconservation (PNC). We present a proof-of-principle experiment in which we search for PNC in the 13 C resonances of small molecules, and use the 1 H resonances, which are insensitive to PNC, as an internal reference. We set a constraint on molecular PNC in 13 C chemical shifts at a level of 10 –5 ppm, and provide a discussion of important considerations in the search for molecular PNC using NMR spectroscopy.

74 ATOMIC AND MOLECULAR PHYSICS↗