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Pruess, Karsten

Publications and source records attributed to Pruess, Karsten.

T2Well/ECO2N Version 1.0: Multiphase and Non-Isothermal Model for Coupled Wellbore-Reservoir Flow of Carbon Dioxide and Variable Salinity Water

T2Well/ECO2N is a coupled wellbore and reservoir model for simulating the dynamics of CO2 injection and leakage through wellbores. It can be seen as an extension to standard TOUGH/ECO2N V2.0, and can be applied to situations relevant to geologic CO2 storage involving upward flow (e.g., leakage) and downward flow (injection). The new simulator integrates a wellbore-reservoir system by assigning the wellbore and reservoir to two different sub-domains in which flow is controlled by appropriate physical laws. In the reservoir, we model flow using a standard multiphase Darcy flow approach. In the wellbores, we use the Drift-Flux Model and related conservation equations for describing transient two-phase non-isothermal wellbore flow of CO2-water mixtures. The mass and thermal energy balance equations are solved numerically by a finite difference scheme with wellbore heat transmission to the surrounding rock handled either semi-analytically or numerically. The momentum balance equation for the flow in the wellbore is solved numerically with a semi-explicit scheme.

Oldenburg, CurtM↗

ECO2N V2.0: A TOUGH2 fluid property module for modeling CO 2 -H 2 O-NACL systems to elevated temperatures of up to 300°C

Here, we have improved ECO2N, the TOUGH2 fluid property module of the CO 2 -H 2 O-NaCl system. The major enhancements include: (i) the upper temperature limit is increased from 110 to about 300°C; (ii) the thermophysical properties of the CO 2 -rich phase are more accurately calculated as a non-ideal mixture of CO 2 and H 2 O; (iii) the approach to calculate the specific enthalpy of dissolved CO 2 has been improved to make the code more robust in modeling phase transitions under non-isothermal conditions; and (iv) more sophisticated models for effective heat conductivity of formations saturated with supercritical CO 2 have been provided. The new module includes a comprehensive description of the thermodynamic and thermophysical properties of H 2 O–NaCl–CO 2 mixtures, that reproduces fluid properties largely within experimental error for the temperature, pressure and salinity conditions 10°C < T < 300°C, P < 600 bar, and salinity up to halite saturation. This includes density, viscosity, and specific enthalpy of fluid phases as functions of temperature, pressure, and composition, as well as partitioning of mass components H 2 O, NaCl and CO 2 among the different phases. ECO2N with the TOUGH2 reservoir simulator can be applied to a wide range of problems in geologic sequestration of CO 2 in saline aquifers, and in enhanced geothermal reservoirs. Finally, ECO2N can describe both sub- and supercritical states of CO 2 , but applications that involve subcritical conditions are limited to systems in which there is no change of phase between liquid and gaseous CO 2 , and in which no mixtures of liquid and gaseous CO 2 occur.

54 ENVIRONMENTAL SCIENCES↗

ECO2N V2.0

ECO2N V2.0 is a fluid property module for the TOUGH2 simulator (Version 2.1) that was designed for applications to geologic sequestration of CO2 in saline aquifers and enhanced geothermal reservoirs. ECO2N V2.0 is an enhanced version of the previous ECO2N V1.0 module (Pruess, 2005). It expands the temperature range up to about 300oC whereas V1.0 can only be used for temperatures below about 110oC. V2.0 includes a comprehensive description of the thermodynamic and thermophysical properties of H2O - NaCl - CO2 mixtures, that reproduces fluid properties largely within experimental error for the temperature, pressure and salinity conditions 10 °C < T < 300 °C, P < 600 bar, and salinity up to halite saturation. This includes density, viscosity, and specific enthalpy of fluid phases as functions of temperature, pressure, and composition, as well as partitioning of mass components H2O, NaCl and CO2 among the different phases. In particular, V2.0 accounts for the effects of water on the thermophysical properties of the CO2-rich phase, which was ignored in V1.0, using a model consistent with the solubility models developed by Spycher and Pruess (2005, 2010). In terms of solubility models, V2.0 uses the same model for partitioning of mass components among the different phases (Spycher and Pruess, 2005) as V1.0 for the low temperature range (<99oC) but uses a new model (Spycher and Pruess, 2010) for the high temperature range (>109oC). In the transition range (99-109oC), a smooth interpolation is applied to estimate the partitioning as a function of the temperature. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO2-rich) phase, as well as two-phase (brine-CO2) mixtures. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. Note that the model cannot be applied to subcritical conditions that involves both liquid and gaseous CO2 unless thermol process is ignored (i.e.,isothermal run). For those cases, a user may use the fluid property module ECO2M (Pruess, 2011) instead.

Pan, Lehua↗