Engineering topics

Ramanathan, Anand

Publications and source records attributed to Ramanathan, Anand.

9 records

DOE OSTI2024

Insights into Dopant-Mediated Tuning of Silica-Supported Mo Metal Centers for Enhanced Olefin Metathesis

Here, we show that the electronic environment around active Mo centers supported on mesoporous silicates can be tuned by the addition of transition metals creating highly dispersed bimetallic catalysts that display enhanced activity for ethylene + 2-butene metathesis to propylene. The bimetallic catalysts are prepared by incorporating electrophilic Lewis acid metals (M) such as Nb, Ta, Zr, or Hf as dopant promoters into mesoporous KIT-6 supports using a one-pot sol–gel technique followed by impregnation of the Mo species. All the bimetallic Mo/M-KIT-6 catalysts display better activity than monometallic Mo/KIT-6 catalyst (28.7 ± 1.1 mmol (mol Mo s ) –1 ), with (Mo/Nb-KIT-6) catalysts exhibiting maximum propylene formation rates (54.2 ± 0.5 mmol (mol Mo s ) –1 ) at an identical Mo loading.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2018

Measurement of Atmospheric CO2 Column Concentrations to Cloud Tops With a Pulsed Multi-Wavelength Airborne Lidar

We have measured the column-averaged atmospheric CO2 mixing ratio to a variety of cloud tops by using an airborne pulsed multi-wavelength integrated-path differential absorption (IPDA) lidar. Airborne measurements were made at altitudes up to 13 km during the 2011, 2013 and 2014 NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) science campaigns flown in the United States West and Midwest and were compared to those from an in situ sensor. Analysis of the lidar backscatter profiles shows the average cloud top reflectance was approx. 5% for the CO2 measurement at 1572.335 nm except to cirrus clouds, which had lower reflectance. The energies for 1 micro-s wide laser pulses reflected from cloud tops were sufficient to allow clear identification of CO2 absorption line shape and then to allow retrievals of atmospheric column CO2 from the aircraft to cloud tops more than 90% of the time. Retrievals from the CO2 measurements to cloud tops had minimal bias but larger standard deviations when compared to those made to the ground, depending on cloud top roughness and reflectance. The measurements show this new capability helps resolve CO2 horizontal and vertical gradients in the atmosphere. When used with nearby full-column measurements to ground, the CO2 measurements to cloud tops can be used to estimate the partial-column CO2 concentration below clouds, which should lead to better estimates of surface carbon sources and sinks. This additional capability of the range-resolved CO2 IPDA lidar technique provides a new benefit for studying the carbon cycle in future airborne and space-based CO2 missions.

atmospheric↗

NASA NTRS2017

A 4 U Laser Heterodyne Radiometer for Methane (CH4) and Carbon Dioxide (CO2) Measurements from an Occultation-Viewing CubeSat

We present a design for a 4 U (20 cm 20 cm 10 cm) occultation-viewing laser heterodyne radiometer (LHR) that measures methane (CH4), carbon dioxide (CO2) and water vapor(H2O) in the limb that is designed for deployment on a 6 U CubeSat. The LHR design collects sunlight that has undergone absorption by the trace gas and mixes it with a distributive feedback (DFB) laser centered at 1640 nm that scans across CO2, CH4, and H2O absorption features. Upper troposphere lower stratosphere measurements of these gases provide key inputs to stratospheric circulation models: measuring stratospheric circulation and its variability is essential for projecting how climate change will affect stratospheric ozone.

occultation↗

NASA NTRS2013

Airborne Measurements of CO2 Column Concentration and Range Using a Pulsed Direct-Detection IPDA Lidar

We have previously demonstrated a pulsed direct detection IPDA lidar to measure range and the column concentration of atmospheric CO2. The lidar measures the atmospheric backscatter profiles and samples the shape of the 1,572.33 nm CO2 absorption line. We participated in the ASCENDS science flights on the NASA DC-8 aircraft during August 2011 and report here lidar measurements made on four flights over a variety of surface and cloud conditions near the US. These included over a stratus cloud deck over the Pacific Ocean, to a dry lake bed surrounded by mountains in Nevada, to a desert area with a coal-fired power plant, and from the Rocky Mountains to Iowa, with segments with both cumulus and cirrus clouds. Most flights were to altitudes >12 km and had 5-6 altitude steps. Analyses show the retrievals of lidar range, CO2 column absorption, and CO2 mixing ratio worked well when measuring over topography with rapidly changing height and reflectivity, through thin clouds, between cumulus clouds, and to stratus cloud tops. The retrievals shows the decrease in column CO2 due to growing vegetation when flying over Iowa cropland as well as a sudden increase in CO2 concentration near a coal-fired power plant. For regions where the CO2 concentration was relatively constant, the measured CO2 absorption lineshape (averaged for 50 s) matched the predicted shapes to better than 1% RMS error. For 10 s averaging, the scatter in the retrievals was typically 2-3 ppm and was limited by the received signal photon count. Retrievals were made using atmospheric parameters from both an atmospheric model and from in situ temperature and pressure from the aircraft. The retrievals had no free parameters and did not use empirical adjustments, and >70% of the measurements passed screening and were used in analysis. The differences between the lidar-measured retrievals and in situ measured average CO2 column concentrations were <1.4 ppm for flight measurement altitudes >6 km.

Lidar↗

NASA NTRS2012

Detecting Methane From Leaking Pipelines and as Greenhouse Gas in the Atmosphere

Laser remote sensing measurements of trace gases from orbit can provide unprecedented information about important planetary science and answer critical questions about planetary atmospheres. Methane (CH4) is the second most important anthropogenically produced greenhouse gas. Though its atmospheric abundance is much less than that of CO2 (1.78 ppm vs. 380 ppm), it has much larger greenhouse heating potential. CH4 also contributes to pollution in the lower atmosphere through chemical reactions, leading to ozone production. Atmospheric CH4 concentrations have been increasing as a result of increased fossil fuel production, rice farming, livestock, and landfills. Natural sources of CH4 include wetlands, wild fires, and termites, and perhaps other unknown sources. Important sinks for CH4 include non-saturated soils and oxidation by hydroxyl radicals in the atmosphere. Remotely measuring CH4 and other biogenic molecules (such as ethane and formaldehyde) on Mars also has important implications on the existence of life on Mars. Measuring CH4 at very low (ppb) concentrations from orbit will dramatically improve the sensitivity and spatial resolution in the search for CH4 vents and sub-surface life on other planets. A capability has been developed using lasers and spectroscopic detection techniques for the remote measurements of trace gases in open paths. Detection of CH4, CO2, H2O, and CO in absorption cells and in open paths, both in the mid- IR and near-IR region, has been demonstrated using an Optical Parametric Amplifier laser transmitter developed at GSFC. With this transmitter, it would be possible to develop a remote sensing methane instrument. CH4 detection also has very important commercial applications. Pipeline leak detection from an aircraft or a helicopter can significantly reduce cost, response time, and pinpoint the location. The main advantage is the ability to rapidly detect CH4 leaks remotely. This is extremely important for the petrochemical industry. This capability can be used in manned or unmanned airborne platforms for the detection of leaks in pipelines and other areas of interest where a CH4 leak is suspected.

Riris, Haris↗

NASA NTRS2012

Ground and Airborne Methane Measurements using Optical Parametric Amplifiers

We report on an initial airborne demonstration of atmospheric methane column measurements at 1.65 micrometers using a widely tunable, seeded optical parametric amplifier (OPA) lidar and a photon counting detector. Methane is an important greenhouse gas and accurate knowledge of its sources and sinks is needed for climate modeling. Our lidar system uses 20 pulses at increasing wavelengths and integrated path differential absorption (IPDA) to map a methane line at 1650.9 nanometers. The wavelengths are generated by using a Nd:YAG pump laser at 1064.5 nanometers and distributed feedback diode laser at 1650.9 nanometers and a periodically-poled lithium niobate (PPLN) crystal. The pulse width was 3 nanoseconds and the pulse repetition rate was 6.28 KHz. The outgoing energy was approximately 13 microJoules/pulse. A commercial 20 nanometer diameter fiber-coupled telescope with a photon counting detector operated in analog mode with a 0.8 nanometer bandpass filter was used as the lidar receiver. The lidar system was integrated on NASA's DC-8 flying laboratory, based at Dryden Airborne operations Facility (DAOF) in Palmdale CA. Three flights were performed in the central valley of California. Each flight lasted about 2.5 hours and it consisted of several flight segments at constant altitudes at approximately 3, 4.5, 6, 7.6, 9.1, 10.6 km (l0, 15, 20, 25, 30, 35 kft). An in-situ cavity ring down spectrometer made by Picarro Inc. was flown along with the lidar instrument provided us with the "truth" i.e. the local CH4, CO2 and H2O concentrations at the constant flight altitude segments. Using the aircraft's altitude, GPS, and meteorological data we calculated the theoretical differential optical depth of the methane absorption at increasing altitudes. Our results showed good agreement between the experimentally derived optical depth measurements from the lidar instrument and theoretical calculations as the flight altitude was increased from 3 to 10.6 kilometers, assuming a constant methane mixing ratio of 1.8 parts per million. The in-situ spectrometer did not show any significant deviations from the ambient concentrations. Further analysis using meteorological data from the Global Modeling and Assimilation Office (http://gmao.gsfc.nasa.gov/) to derive the theoretical optical depth also showed good agreement with the experimentally derived values. The OPA lidar system with slight modifications has also been used to measure CO2, water vapor, and CO in the near and mid-infrared spectral regions on the ground.

Riris, Haris↗

NASA NTRS2012

Ground and Airborne Methane Measurements with an Optical Parametric Amplifier

Here we report on measurements made with an improved CO2 Sounder lidar during the ASCENDS 2014 and 2016 airborne campaigns. The changes made to the 2011 version of the lidar included incorporating a rapidly wavelength-tunable, step-locked seed laser in the transmittter, using a much more sensitive HgCdTe APD detector andusing an analog digitizer with faster readout time in the receiver. We also improved the lidar's calibration approach and the XCO2 retrieval algorithm. The 2014 and 2016 flights were made over several types of topographic surfaces from3 to 12 km aircraft altitudes in the continental US. The results are compared to the XCO2 values computed from an airborne in situ sensor during spiral-down maneuvers. The 2014 results show significantly better performance and include measurement of horizontal gradients in XCO2 made over the Midwestern US that agree with chemistry transport models. The results from the 2016 airborne lidar retrievals show precisions of 0:7 parts per million (ppm) with 1 s averaging over desert surfaces, which is an improvement of about 8 times compared to similar measurements made in 2011. Measurements in 2016 were also made over fresh snow surfaces that have lower surface reflectance at the laser wavelengths. The results from both campaigns showed that the mean values of XCO2 retrieved from the lidar consistently agreed with those based on the in situ sensor to within 1 ppm. The improved precision and accuracy demonstrated in the 2014 and 2016 flights should benefit future airborne science ampaigns and advance the technique's readiness for a spacebased instrument.

Numata, Kenji↗

NASA NTRS2012

Pulsed Lidar Measurements of Atmospheric CO2 Column Absorption in the ASCENDS 2011 Airborne Campaign

We have previously demonstrated an efficient pulsed, wavelength-resolved IPDA lidar technique for measuring the tropospheric CO2 concentrations as a candidate for NASA's ASCENDS mission. Our team participated in the 2010 ASCENDS airborne campaigns we flew airborne version of the CO2 and O2 lidar on the NASA DC-8. The CO2 lidar measures the atmospheric backscatter profiles and shape of the 1572.33 nm absorption line using 250 mW average laser power, 30 wavelength samples per scan and 300 scans per second. Most flights had 5-6 altitude steps to greater than 12 km, and clear CO2 line shapes were observed at all altitudes. Our post-flight analysis estimated the Iidar range and pulse energies at each wavelength every second. We then solved for the best-fit CO2 absorption line shape, and calculated the Differential Optical Depth (DOD) at the line peak. We compared these to CO2 DODs calculated from spectroscopy based on HITRAN 2008 and the conditions from airborne in-situ readings. Analysis of the 2010 measurements over the Pacific Ocean and Lamont OK shows the expected -linear change of the peak DOD with altitude. For measurements at altitudes greater than 6 km the random errors were approximately 0.3 ppm for 80 sec averaging times. After the 2010 flights we improved the airborne lidar's scan uniformity, calibration and receiver sensitivity. Our team participated in the seven ASCENDS science flights during late July and August 2011. These flights were made over a wide variety of surface and cloud conditions near the US, including over the central valley of California, over several mountain ranges, over both broken and solid stratus cloud deck over the Pacific Ocean, snow patches on mountain tops, over thin and broken clouds above the US Southwest and Iowa, and over forests near the WLEF tower in Wisconsin. Analyses show the retrievals of lidar range and CO2 column absorption, as wen as estimates of CO2 mixing ratio worked well when measuring over topography with rapidly changing height and reflectivity, through thin clouds and to stratus cloud tops. For regions where the CO2 concentration was relatively constant, the measured CO2 absorption profile (averaged for 50 sec) matched the predicted profile to better than 1% RMS error for all flight altitudes. For 1 & 10 second averaging, the scatter in the retrievals was limited by signal shot noise (i.e. the sigual photon count). Analysis to date shows the decrease in CO2 due to vegetation when flying easterward over the Great Plains as well as the increase in CO2 concentration in the vicinity ofthe coal-fired power plant in New Mexico. Examples of these and other results will be presented.

Abshire, James B.↗

NASA NTRS2011

Ground and Airborne Methane Measurements Using Optical Parametric Amplifiers

We report on ground and airborne methane measurements with an active sensing instrument using widely tunable, seeded optical parametric generation (OPG). The technique has been used to measure methane, CO2, water vapor, and other trace gases in the near and mid-infrared spectral regions. Methane is a strong greenhouse gas on Earth and it is also a potential biogenic marker on Mars and other planetary bodies. Methane in the Earth's atmosphere survives for a shorter time than CO2 but its impact on climate change can be larger than CO2. Carbon and methane emissions from land are expected to increase as permafrost melts exposing millennial-age carbon stocks to respiration (aerobic-CO2 and anaerobic-CH4) and fires. Methane emissions from c1athrates in the Arctic Ocean and on land are also likely to respond to climate warming. However, there is considerable uncertainty in present Arctic flux levels, as well as how fluxes will change with the changing environment. For Mars, methane measurements are of great interest because of its potential as a strong biogenic marker. A remote sensing instrument that can measure day and night over all seasons and latitudes can localize sources of biogenic gas plumes produced by subsurface chemistry or biology, and aid in the search for extra-terrestrial life. In this paper we report on remote sensing measurements of methane using a high peak power, widely tunable optical parametric generator (OPG) operating at 3.3 micrometers and 1.65 micrometers. We have demonstrated detection of methane at 3.3 micrometers and 1650 nanometers in an open path and compared them to accepted standards. We also report on preliminary airborne demonstration of methane measurements at 1.65 micrometers.

Numata, Kenji↗