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Redden, George D.

Publications and source records attributed to Redden, George D..

3 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Impact of mineral precipitation on flow and mixing in porous media determined by microcomputed tomography and MRI

Here, precipitation reactions in porous media influence transport properties of the environment and can control advective and dispersive transport. In subsurface environments, mixing of saline groundwater or injected solutions for remediation with fresh groundwater can induce supersaturation of constituents and drive precipitation reactions. Magnetic resonance imaging (MRI) and micro-computed tomography (µ-CT) were employed as complimentary techniques to evaluate advection, dispersion and formation of precipitate in a 3D porous media flow cell. Two parallel fluids were flowed concentrically through the porous media under two flow rate conditions with Na 2 CO 3 and CaCl 2 in the inner and outer fluids, respectively. Upon mixing, calcium carbonate became supersaturated and formed a precipitate at the interface of the two fluids. Spatial maps of changing local velocity fields and dispersion in the flow cell were generated from MRI, while high resolution imaging of the precipitate formed in the porous media was achieved via µ-CT imaging. Formation of a precipitate layer minimized dispersive and advective transport between the two fluids and the shape of the precipitation was influenced by the flow rate condition.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2011

EMSL Pore Scale Modeling Challenge/Workshop

The design and implementation of cost-effective remediation strategies for subsurface contamination not only relies on descriptive models of contaminant distribution but predictive models of contaminant fate and transport. The development of such predictive models is of great importance to many government agencies including the Department of Energy (DOE), Department of Defense, and the Environmental Protection Agency. Accurate prediction of the fate and transport of environmental contaminants in the subsurface has driven development of increasingly sophisticated subsurface flow and transport models. Even without considering spatial and temporal scalability, contaminant transport at the field scale is complex, and this almost inevitably results in an especially sophisticated model being developed for a specific field site. Unfortunately, these models are not easily generalizable to other field sites or and can only be used by the model authors to generate meaningful results. Over time, this results in the existence of numerous specialized models that are not readily comparable to each other and difficult to cross-validate. There is a lack of fundamental experimental observations at the pore scale that can be used to support model development and validation at the field scale.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗