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Remsberg, E. E.

Publications and source records attributed to Remsberg, E. E..

52 records · Page 3

A diagnostic model for studying daytime urban air quality trends

A single cell Eulerian photochemical air quality simulation model was developed and validated for selected days of the 1976 St. Louis Regional Air Pollution Study (RAPS) data sets; parameterizations of variables in the model and validation studies using the model are discussed. Good agreement was obtained between measured and modeled concentrations of NO, CO, and NO2 for all days simulated. The maximum concentration of O3 was also predicted well. Predicted species concentrations were relatively insensitive to small variations in CO and NOx emissions and to the concentrations of species which are entrained as the mixed layer rises.

Brewer, D. A.↗

Satellite observations of upper atmosphere O3 and HNO3 from the Limb Infrared Monitor of the Stratosphere /LIMS/ experiment on Nimbus 7

The Limb Infrared Monitor of the Stratosphere (LIMS) experiment, launched on-board the Nimbus satellite, was designed to measure both day and night limb radiance which is used to infer upper atmosphere temperature profiles and chemical compound concentrations important in the study of ozone chemistry. The LIMS instrument is a six channel, limb scanning, thermal radiometer which uses HgCdTe detectors, cooled to approximately 64 K. Measurements include ozone, water vapor, nitrogen dioxide, and nitric acid. The ozone and nitric acid channels are centered at approximately 9.6 microns and 11.3 microns, respectively. Results from the channels are described with an emphasis on data validation. The O3 and HNO3 channels have demonstrated high measurement precision.

Russell, J. M., III↗

The validation of LIMS ozone profiles using correlative rocket, ECC, and Dobson data sets

The Limb Infrared Monitor of the Stratosphere (LIMS) experiment is a limb scanning infrared sounder designed to measure vertical temperature profiles and the concentrations of key chemical compounds which are important in the stratospheric ozone-nitrogen photochemistry. Preliminary ozone profiles are being intercompared with correlative rocket and balloonsonde ozone data sets as part of the Nimbus 7 LIMS data validation activity. The LIMS ozone retrievals extend from the lower mesosphere to the tropopause (or cloud-top altitudes). In this paper, preliminary statistics of comparisons of ECC (electrochemical concentration cell) ozonesonde and rocket ozone profiles with LIMS ozone profiles are presented. ECC ozonesonde data taken at times of LIMS overpasses are also used to extend the LIMS retrieval down to ground level. Each combined profile is then integrated to obtain total column ozone. These integrated results are compared to Dobson data obtained at approximately the same time and location.

Remsberg, E. E.↗

Stratospheric water vapor results from the limb infrared monitor of the stratosphere /LIMS/ experiment on Nimbus 7

Stratospheric water vapor results taken from the limb infrared monitor of the stratosphere experiment on Nimbus 7 are presented with emphasis on validation studies. Basic radiance data, the indicated orbital precision of the experiment and comparisons made with data collected in simultaneous balloon underflights are described. A plot of pressure versus H2O channel radiance shows the radiance variability as a function of pressure and latitude. Measured precision is in good agreement with calculated values using simulations.

Russell, J. M., III↗

Diffusion in the lower stratosphere as determined from lidar measurements of volcanic aerosol dispersion

Lidar measurements of the stratospheric aerosol layer from the Fuego volcanic eruption in 1974 are analyzed to yield estimates of effective vertical mixing coefficients K(z). The data at 19 deg N latitude give K(z) = 6.6 x 10 to the 2nd sq cm/sec for the altitude range of 19 + or - 1.5 km, while the data at 37 deg N yield K(z) = 13 x 10 to the 2nd sq cm/sec for 19 + or - 3.5 km. The variability in these values is about a factor of 2. These derived K(z) values are interpreted as being due mainly to diffusion.

Remsberg, E. E.↗

Air quality model studies with application for southeastern Virginia

A single-cell photochemical air quality model incorporating (1) a published chemical mechanism, (2) advection, and (3) entrainment and emissions processes was constructed and compared with data from the EPA Regional Air Pollution Study. While agreement with measured CO and NO2 was established, O3 production was found to occur too rapidly and in excess. Calculated O3 levels improved when a 20% reduction in photolytic rate constants and a doubling of wind speed were applied. The results of the model sensitivity studies are being incorporated into the design and conduct of field measurement programs for the characterization of the vertical and horizontal homogeneity of an air quality region.

Brewer, D. A.↗

The 1977 emissions inventory for southeastern Virginia

Regional tropospheric air pollution modeling and data compilation to simulate the time variation of species concentrations in and around an urban area is discussed. The methods used to compile an emissions inventory are outlined. Emissions factors for vehicular travel in the urban area are presented along with an analysis of the emission gases. Emission sources other than vehicular including industrial wastes, residential solid waste disposal, aircraft emissions, and emissions from the railroads are investigated.

Brewer, D. A.↗

Lidar backscattering measurements of background stratospheric aerosols

A comparative lidar-dustsonde experiment was conducted in San Angelo, Texas, in May 1974 in order to estimate the uncertainties in stratospheric-aerosol backscatter for the NASA Langley 48-inch lidar system. The lidar calibration and data-analysis procedures are discussed. Results from the Texas experiment indicate random and systematic uncertainties of 35 and 63 percent, respectively, in backscatter from a background stratospheric-aerosol layer at 20 km.

Remsberg, E. E.↗

Analysis of differential absorption lidar from the Space Shuttle

A parametric analysis of the Shuttle-borne differential absorption lidar concept for the measurement of atmospheric trace constituent profiles in the nadir viewing mode is presented. The criterion of an optimum constituent optical depth is developed and applied to generate estimates of range resolved measurement errors. These errors emphasize the fundamental limitations for establishing the feasibility of range-resolved differential absorption lidar measurements from Shuttle. With current lidar system technology, atmospheric backscatter density profiles may be adequately determined up to about 60-km altitude at the doubled-ruby wavelength, 3472 A, for a 1-J/pulse laser and a 1-sq m receiver. Potential range-resolved measurements of stratospheric and mesospheric trace constituents by differential absorption from Shuttle altitudes are limited to H2O, CH4, N2O, O3, and CO, species which can be more easily measured by passive limb viewing techniques. Range-resolved water vapor data for the lower troposphere may be obtained with accuracies which would be competitive with those from passive sensors.

Remsberg, E. E.↗

Lidar measurement of stratospheric dust from St. Augustine Volcano

The detection of a stratospheric dust layer of probable volcanic origin over Hampton, Va., on the evening of Jan. 28, 1976, with a 20-inch lidar system is reported. A digitized cathode-ray-tube trace of a return signal from altitudes of 12 to 24 km on January 28 is provided, and it is shown that 38% of the return was due to stratospheric aerosol. Noting that measurements on January 22 and February 2 showed no traces of this stratospheric dust layer, trajectories of dust-laden air parcels are followed from initiation at 0000 GMT on January 24 at the St. Augustine Volcano on Augustine Island, Alaska (59 deg N, 153 deg W). Analysis of the trajectories indicates that dust injected into the stratosphere at 59 deg N, 153 deg W could have been transported to Virginia in about 4 days. It is concluded that if the St. Augustine Volcano was the source of the dust, at least 23 deg of meridional transport from polar latitudes was observed.

Remsberg, E. E.↗

A comparison of dustsonde and LIDAR measurements of stratospheric aerosols

This paper describes the results and analysis of an experiment to compare the stratospheric aerosol profiles as measured by a balloon-borne in situ particle counter and by the backscattered light from a ground-based laser radar (LIDAR) operating at a wavelength of 6943 A. The profile comparison agrees within the experimental errors for particles with radii greater than 0.25 micrometer and for altitudes between 15 and 28 kilometers. Following the calibration tests, the LIDAR was used to monitor the stratospheric aerosols at Hampton, Virginia. Enhanced backscatter appeared sporadically in November and December of 1974 over Hampton; scattering ratios averaged over altitude increments of 450 meters range from 1.10 at 20 kilometers in early November to 3.3 at 17 kilometers on December 18. The source of this enhanced backscattering is attributed to the aerosols associated with the eruption of the Fuego volcano in Guatemala in mid-October.

Remsberg, E. E.↗

Effect of aerosol emission on the inference of trace gas concentrations from limb radiance data

This note reports on an analysis of atmospheric emission spectra in the 10-12 micron region measured with a limb-oriented balloon-borne spectrometer. Data clearly show the existence of an additional feature at 10.8 microns which is probably due to measurement contamination from aerosols. The 10.8 micron emitter has a strong reducing effect on the HNO3 mixing ratio profile as determined by application of a symmetrical band shape model to the 10.8 spectral feature.

Remsberg, E. E.↗

Optical constants of concentrated aqueous ammonium sulfate.

Using experimental data obtained from applying spectroscopy to a 39-wt-% aqueous ammonium sulfate solution, it is shown that, even though specific aerosol optical constants appear quite accurate, spectral variations may exist as functions of material composition or concentration or both. Prudent users of optical constant data must then include liberal data error estimates when performing calculations or in interpreting spectroscopic surveys of collected aerosol material.

Remsberg, E. E.↗

Stratospheric aerosol properties and their effects on infrared radiation.

This paper presents a stratospheric aerosol model and infers its effects on terrestrial radiation. Composition of the aerosol is assumed to be concentrated sulfuric acid. An appropriate size distribution has been determined from available size distribution measurements of other investigators. Aerosols composed of concentrated sulfuric acid emit energy in the atmospheric window region of the infrared spectrum, 8-13 microns. Laboratory measurements of optical constant data obtained at room temperature are presented for 75 and 90% aqueous sulfuric acid. Calculations of an aerosol extinction coefficient are then performed by using the above data. Effects of changes in aerosol phase and temperature are discussed but not resolved.

Remsberg, E. E.↗