Engineering topics
Publications and source records attributed to Ribas-Ariño, Jordi.
The engineered supramolecular recognition of coordination complexes achieved by ligand design is shown in the solid state and in solution via X-ray diffraction and paramagnetic H-NMR spectroscopy.
We discuss the anion SiF 6 2– , which exerts a strong template effect, driving the assembly of two different bispiridylpyrazolyl ligands into a triple stranded Fe(II) dinuclear heteroleptic helicate, engendering a new class within the large family of cordination helicates.
To identify the genesis of the differing magnetic behaviors for the ferro- (FO) and metamagnetic (MM) polymorphs of [FeCp* 2 ][TCNQ] the low temperature structures of each polymorph were determined from high-resolution synchrotron powder diffraction data.