Engineering topics

Rinsland, C. P.

Publications and source records attributed to Rinsland, C. P..

174 records · Page 10

NASA NTRS1984

A Search for Formic Acid in the Upper Troposphere: A Tentative Identification of the 1105-cm(exp -1) nu(sub 6) Band Q Branch in High-Resolution Balloon-Borne Solar Absorption Spectra

Infrared solar absorption spectra recorded at 0.02/cm resolution during a balloon flight from Alamogordo, N.M. (33 deg N), on March 23, 1981, have been analyzed for the possible presence of absorption by formic acid (HCOOH). An absorption feature at 1105/ cm has been tentatively identified in upper tropospheric spectra as due to the nu(sub 6) band Q branch. A preliminary analysis indicates a concentration of approx. = 0.6 ppbv and approx. = 0.4 ppbv near 8 and 10 km, respectively.

Goldman, A.↗

NASA NTRS1984

Atlas of high resolution infrared spectra of carbon dioxide

An atlas of long-path room-temperature absorption spectra of carbon dioxide is presented for the spectral intervals 1830-2100 cm, 2395-2680 cm, and 3140-3235 cm. The spectral data were recorded at high signal to noise with the 0.01 cm resolution Fourier transform interferometer. The spectra were obtained with pressures between 1 and 10 Torr of CO2 and with total paths between 24 and 384 meters. A compilation of the measured line positions and the assignments derived from the analysis are presented. Of the 3336 lines in the atlas, 94 percent were identified as CO2 lines or as residual lines H2O and CO. Calculated positions are presented for the carbon dioxide lines; a total of 52 bands of C-12O2-16, C-13O2-16, C-12O-16O-18, C-12O-16O-17, and C-13O-16O18 were identified. The weakest carbon dioxide lines marked in the atlas have intensities of approximately 0.5 x 10 to the negative 26th power cm/molecule at room temperature.

Rinsland, C. P.↗

NASA NTRS1984

Balloon-borne and aircraft infrared measurements of ethane (C2H6) in the upper troposphere and lower stratosphere

Quantitative infrared measurements of ethane (C2H6) in the upper troposphere and lower stratosphere are reported. The results have been obtained from the analysis of absorption features of the nu9 band at 12.2 microns, which have been identified in high-resolution balloon-borne and aircraft solar absorption spectra. The balloon-borne spectral data were recorded at sunset with the 0.02/cm resolution University of Denver interferometer system, from a float altitude of 33.5 km near Alamogordo, New Mexico, on March 23, 1981. The aircraft spectra were recorded at sunset in July 1978 with a 0.06/cm resolution interferometer aboard a jet aircraft at 12 km altitude, near 35 deg N, 96 deg W. The balloon analysis indicates the C2H6 mixing ratio decreased from 3.5 ppbv near 8.8 km to 0.91 ppbv near 12.1 km. The results are consistent with the column value obtained from the aircraft data.

Goldman, A.↗

NASA NTRS1983

Absolute intensity measurements of the (11/1/0)II-00/0/0 band of (C-12)(O-16)2 at 5.2 microns

A nonlinear least-squares fitting procedure has been used to derive absolute intensities for lines in the P, R, and Q branches of the (11/1/0)II-00/0/0 band of (C-12)(O-16)2 (band center = 1932/cm) from long-path 0.01/cm resolution laboratory spectra. The spectral data were recorded at room temperature and low pressure (less than 10 torr) with the Fourier transform spectrometer in the McMath solar telescope complex at Kitt Peak National Observatory. The observed line intensities were analyzed to derive the vibrational band intensity and F-factor coefficients. To obtain a good fit to the data, it was necessary to include terms in the expression for the F factor, which account for Coriolis-type and Fermi-type interactions and centrifugal distortion effects.

Rinsland, C. P.↗

NASA NTRS1983

Stratospheric temperature profile from balloon-borne measurements of the 10.4-micron band of CO2

The technique of nonlinear least squares spectral curve fitting has been used to derive the stratospheric vertical temperature profile from balloon-borne measurements of the 10.4 micron band of CO2. The spectral data were obtained at sunset with the approximately 0.02 per cm resolution University of Denver interferometer system from a float altitude of 33.5 km near Alamogordo, New Mexico, on 23 March 1981. The r.m.s. deviation between the retrieved temperature profile and correlative radiosonde measurements is 2.2 K.

Rinsland, C. P.↗

NASA NTRS1982

Ground-based infrared spectroscopic measurements of atmospheric hydrogen cyanide

A number of lines of the nu-3 band of hydrogen cyanide have been detected in solar absorption spectra recorded near sunrise and sunset at Kitt Peak National Observatory (elevation 2095 m) with a 0.01/cm resolution Fourier transform spectrometer. Analysis of two of the strongest and best isolated lines has led to a value of 2.73 x 10 to the 15th molecules/sq cm for the vertical column abundance of HCN above Kitt Peak. The accuracy of this value is estimated as + or - 25%. This result, combined with the stratospheric concentration of HCN derived by Coffey, Mankin, and Cicerone (1981), yields 166 parts per trillion by volume for the average mixing ratio of HCN between 2 and 12 km. This is the first determination of the HCN concentration in the nonurban troposphere.

Rinsland, C. P.↗

NASA NTRS1982

Stratospheric N2O mixing ratio profile from high-resolution balloon-borne solar absorption spectra and laboratory spectra near 1880/cm

A nonlinear least-squares fitting procedure is used to derive the stratospheric N2O mixing ratio profile from balloon-borne solar absorption spectra and laboratory spectra near 1880/cm. The atmospheric spectra analyzed here were recorded during sunset from a float altitude of 33 km with the University of Denver's 0.02/cm resolution interferometer near Alamogordo, N.M. (33 deg N) on Oct. 10, 1979. The laboratory data are used to determine the N2O line intensities. The measurements suggest an N2O mixing ratio of 264 ppbv near 15 km, decreasing to 155 ppbv near 28 km.

Rinsland, C. P.↗

NASA NTRS1982

Stratospheric measurements of collision-induced absorption by molecular oxygen

High-resolution stratospheric solar absorption spectra recorded at sunset with a balloon-borne interferometer, from an altitude of 33 km, are used in a study of collision-induced absorption by the fundamental vibration-rotation band of O2, whose continuum has been identified in the 1400-1700/cm region in spectra obtained at tangent altitudes below 22 km. It is found that transmittance measurements in intervals free of atmospheric line absorption agree with values calculated with the O2 absorption coefficients of Timofeyev and Tonkov (1978), and that the measurements indicate a 20% upper limit for the uncertainty of the available O2 absorption coefficients at lower stratospheric temperatures, on the order of 220 K.

Rinsland, C. P.↗

NASA NTRS1982

Spectroscopic requirements for HALOE: An analysis of the HCl and HF channels

Spectral line parameters that have absorption features within the HCl and HF channels of the Halogen Occultation Experiment (HALOE) were evaluated. Line positions and identification of stratospheric and solar absorption features in both channels are presented based on an analysis of high-resolution, balloon-borne solar occultation spectra. For the relevant HCl and HF lines and for transitions of the interfering species, the accuracy of the following spectral parameters was assessed: line positions, line strengths, lower state energies, air-broadened collisional half-widths, and temperature dependence of the air-broadened half-widths. In addition, since the HALOE instrument and calibration cells are filled with mixtures of HCl in N2 and HF in N2, the self-broadened and N2-broadened HF and HCl half-widths were also considered.

Rinsland, C. P.↗

NASA NTRS1982

Science support for the atmospheric trace molecule spectroscopy (ATMOS) experiment

The experiment is a satellite solar occultation interferometer spectrometer experiment under development for flight on Spacelab 3. Launch is expected in March 1985. ATMOS will provide high spectral resolution (0.02/cm) and high spatial resolution (2 km from Shuttle altitude) data over the spectral range from 2 micrometers to 16 micrometers. This region of the spectrum is rich in absorption features of major and minor trace gases which are critical to the understanding of the chemistry and physics of the Earth's upper atmosphere. The broad objectives of the ATMOS experiment are to: identify and measure, on a global scale, the volume mixing ratios of known and newly discovered molecular species; determine vertical profiles for these species; and provide spectral data on the atmosphere for use in optimizing the design of future instruments to monitor specific gases.

Rinsland, C. P.↗

NASA NTRS1981

Stratospheric measurements of continuous absorption near 2400 per cm

Measurements of continuous absorption near 2400 per cm by N2 and CO2 over long path lengths in the lower stratosphere are presented. The continua were measured in a stratospheric solar spectrum obtained during sunset with a balloon-borne Michelson interferometer in the 2380-2500 per cm region, and transmittances were calculated by ratioing the amplitudes to those of a high-sun spectrum in order to eliminate the wavelength dependence of the measured flux. Comparison of the measured transmittances with those calculated for a multilayered atmospheric model using laboratory absorption measurements results in a fair agreement, and reveals the primary component of the absorption throughout most of the range to be N2, with the CO2 contribution equal to that of N2 only at the CO2 band head. In this region, the shape of the continuum is very sensitive to the sub-Lorentzian line shape assumed in the calculations, and so, if the shape of the N2 continuum at low temperatures can be determined through laboratory measurements, may be used to infer air-broadened far-wing CO2 line shape.

Rinsland, C. P.↗

NASA NTRS1981

Atlas of absorption lines from 0 to 17 900 cm(-1)

Plots of absorption line strength versus line position for wavenumbers from 0 to 17,900 cm(-1) are shown for 20 atmospheric gases (H2O, CO2, O3, N2O, CO, CH4, O2, NO, SO2, NO2, NH3, HNO3, OH, HF, HCl, HBr, HI, ClO, OCS, H2CO). Also shown are similar plots of lower-state energy values for adsorption lines for the strongly adsorbing atmospheric gases (H2O, CO2, O3, and CH4) for wavenumbers from 0 to 5000 cm(-1).

Park, J. H.↗