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Roscoe, H. K.

Publications and source records attributed to Roscoe, H. K..

10 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2006

Ozone Profiles in the High-latitude Stratosphere and Lower Mesosphere Measured by the Improved Limb Atmospheric Spectrometer (ILAS)-II: Comparison with other Satellite Sensors and Ozonesondes

A solar occultation sensor, the Improved Limb Atmospheric Spectrometer (ILAS)-II, measured 5890 vertical profiles of ozone concentrations in the stratosphere and lower mesosphere and of other species from January to October 2003. The measurement latitude coverage was 54-71degN and 64-88degS, which is similar to the coverage of ILAS (November 1996 to June 1997). One purpose of the ILAS-II measurements was to continue such high-latitude measurements of ozone and its related chemical species in order to help accurately determine their trends. The present paper assesses the quality of ozone data in the version 1.4 retrieval algorithm, through comparisons with results obtained from comprehensive ozonesonde measurements and four satellite-borne solar occultation sensors. In the Northern Hemisphere (NH), the ILAS-II ozone data agree with the other data within +/-10% (in terms of the absolute difference divided by its mean value) at altitudes between 11 and 40 km, with the median coincident ILAS-II profiles being systematically up to 10% higher below 20 km and up to 10% lower between 21 and 40 km after screening possible suspicious retrievals. Above 41 km, the negative bias between the NH ILAS-II ozone data and the other data increases with increasing altitude and reaches 30% at 61-65 km. In the Southern Hemisphere, the ILAS-II ozone data agree with the other data within 10% in the altitude range of 11-60 km, with the median coincident profiles being on average up to 10% higher below 20 km and up to 10% lower above 20 km.

Sugita, T.↗
NASA NTRS1990

The Balloon Intercomparison Campaigns - An introduction and overview

The Balloon Intercomparison Campaigns of 1982 and 1983 involved a comparison of measurements by 21 instruments from seven countries, assembled on four gondolas, assigned to collect data on the vertical profiles of HCl, HNO3, NO2, NO, O3, and many other stratospheric constituents. Most of these sensors supplied data on more than two constituents. This paper describes the instruments and the constituents measured by each of the sensor and the parameters of each balloon flight, together with some results.

Watson, R. T.↗
NASA NTRS1990

Intercomparison of remote measurements of stratospheric NO and NO2

During the 1982 and 1983 Balloon Intercomparison Campaigns, the vertical profile of stratospheric NO2 was measured remotely by nine instruments and that of NO by two. Total overhead columns were measured by two more instruments. Between 30 and 35 km, where measurements overlapped, agreement between NO profiles was within + or - 30 percent, which is better than the accuracies claimed by the experimenters. Between 35 and 40 km, there was similarly good agreement between NO2 profiles, but below 30 km, differences of greater than a factor of 3 were found. In the second campaign, NO2 values from most instruments agreed within their quoted errors, except that the Oxford radiometer gave much lower values; the first campaign and the column measurements show a more uniform spread of results.

Roscoe, H. K.↗
NASA NTRS1987

About a possible reference model for stratospheric NO2

After a brief review of observations of the global distribution of stratospheric NO2, the possibiliy of combining different data sets to construct a NO2 reference model is discussed. It is shown that difficulties mainly arise from the diversity of techniques and variability of NO2 in the stratosphere. The diurnal variation and possibly a long term trend present special problems.

Naudet, J. P.↗
NASA NTRS1980

Observations of interstellar H2O emission at 183 gigahertz

Observations of the 183-GHz rotational transition of water vapor in interstellar molecular clouds are reported. The observations were made with a portable double-sideband superheterodyne radiometer used with the 91-cm Cassegrain telescope on board the Kuiper Airborne Observatory. An emission feature was detected in the direction of the Kleinmann-Low nebula in Orion with a peak antenna temperature of 15 K, a local standard of rest velocity of 8 km/sec, and a width of 15 km/sec. A plateau component of the emission profile is attributed to the 1-arcmin region characteristic of plateau emission from other observed molecules, with emission enhanced over that expected for thermal excitation, while the spike component observed is consistent with an optically thick source of the size of the molecular ridge in Orion at a temperature of 50 K and a column density greater than or equal to 3 x 10 to the 17th/sq cm, implying that H2O is one of the more abundant species in the Orion Molecular Cloud. Emission at 183 GHz was not detected in Sgr A, Sgr B2, W3, W43, W49, W51, DR 21, NGC 1333, NGC 7027, GL 2591 or the Rho Oph cloud; it may have been detected in M 17.

Waters, J. W.↗
NASA NTRS1979

Aircraft search for millimeter-wavelength emission by stratospheric ClO

Three millimeter-wavelength transitions of ClO were searched for in the stratospheric emission spectrum during May-August 1977 using aircraft-based instruments. The measurements indicate that if stratospheric ClO has a vertical distribution of the form predicted by present photochemical models, then the ClO volume mixing ratio at the profile peak did not exceed 10 to the -9th at the time and place of the measurements. The observed spectra suggest the presence of ClO in the stratosphere but do not provide a definitive detection.

Waters, J. W.↗
NASA NTRS1978

Infra-red measurements of stratospheric composition. I - The balloon instrument and water vapour measurements

The design and construction of a balloon-borne instrument for remote-sensing of stratospheric composition is described. Thermal emission from the constituents is detected and the spectral selectivity of the instrument is tailored to a specific gas by the use of a cell of the same gas in the optical path of the radiometer. The pressure of the gas in the cell is cycled and the resultant transmission function is shown to be highly selective to radiation from the same gas in the atmosphere. The first flight of the instrument and the retrieval of a water vapour profile in the range 15-40 km is described.

Chaloner, C. P.↗
NASA NTRS1977

Radiometric measurement of stratospheric HCl

On March 17, 1976, the atmospheric absorption of solar infrared radiation at sunset was measured by a balloon-borne pressure modulator, whose major feature was a cell containing gaseous HCl, through which the incoming radiation passed. The side-band:wide-band ratio which is related to the amount of atmospheric HCl in the path between the instrument and the sun, was also measured. The vertical mixing ratio profile for gaseous HCl for the altitude range 16-39 km, was derived from the data by using a computer model. The shape of the profile implies that the major source of HCl in the stratosphere is around 32 km. The importance of this profile in determining the effects of man-made chlorine compounds on atmospheric ozone is stressed.

Eyre, J. R.↗