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Rosemary M Killen

Publications and source records attributed to Rosemary M Killen.

Temporary Atmospheres Produced By Human Activities on the Moon

Outgassing from materials, whether through the ascent/descent stages of lunar vehicles, airlock depressurizing, rover or astronaut suit outgassing, may cause an effect of unwanted accumulation of volatiles at the surface and exosphere. This is especially important at (or proximal) to permanently shadowed regions (PSRs) at the lunar poles. Herein, we provide estimates of expected outgassing from various human-landed objects on the Moon, including backpacks, airlocks, rovers, landers, trash and mining operations. Astronaut suits produce some level of oxygen outgassing (Helou et al., 2022), which may transport and condense in these PSRs, even in micro- cold traps (Glavin et al., 2010).We estimate the outgassing from drill mining and trash-to-gas conversion assuming a specific technology is operating. These outgassing systems can create local, temporary atmospheres in the vicinity (∼100 km radius) of the sources. The atmosphere may be particularly high within meters of the source. To obtain column densities for these temporary atmospheres, we first bracket ranges for the gas number loss as a function of time. We then derive the maximum distance traveled and the time the released molecules remain in the exosphere for a single ballistic hop, assuming the molecules are ejected from the surface of the object at its surface temperature. In some cases, such as the astronaut backpack and the rover, the temperature is that of the source. Given this information, an average and peak local exospheric density and column density can be estimated. We find that backpacks, airlock releases, and the Starship lander can create relatively high-density local atmospheres, with local near-lander outgassing water densities exceeding 107/cm3. This local water exosphere is over 106 times greater than the LADEE-derived lower limit of the natural water exosphere at ∼3/cm3. Thus, the anthropogenic temporary water exosphere will likely dominate the environment near the lander, making an assessment of the natural exospheric water environment difficult.

Rosemary M Killen

Moon: Handle With Care

The exploration of the Moon involves multiple and complex competing interests, including those of nation states and commercial entities. The goal of this paper is to identify science questions with answers that may be obscured by human activities unless precautions are taken. We aim to encourage follow-on work to produce environmental impact assessments for various lunar activities in order to understand the degree of contamination generated by different processes. We also encourage the preservation of scientifically important regions, as proposed by others (e.g., Committee on Planetary Protection, 2020; Farrell et al., 2021; Krolikowski, 2023). In the following sections, we discuss what measurements are necessary to determine how and where science investigations and exploration (commercial or otherwise) can be carried out concurrently. We advocate a strategy of concurrent exploration and science where possible, and for a science-first approach in cases where exploration may obscure scientific evidence that is uniquely preserved on the Moon.

Rosemary M Killen

Lunar Solar Occultation Explorer (Lunasox)

In the present decade and beyond, now 51 years after the last Apollo landing, the NASA Artemis human exploration program will offer abundant opportunities for heliophysics investigations from, by, and of the Moon from the vantage points of the lunar orbit and the surface. The Lunar Solar Occultation Explorer (LunaSOX) concept uses the lunar limb to occult the solar disk for high-resolution coronal observations at hourly, daily, to biweekly cadences from spacecraft either in the lunar orbit or at the surface. A 0.2 m diameter solar telescope in orbit with white light and narrow-band visible filters would provide arcsecond spectroscopic imaging of the low-to-high corona (1–10 R☉) with an upper limit of 10 –12 B☉ on the local scattered light background from lunar atmospheric dust, as compared to 10 –9 B☉ for Earth ground-based solar eclipse observations looking up through the atmosphere at totality. For eclipse observations from and by the Moon, there would be no significant atmospheric disturbances that otherwise limit seeing to arcsec resolution from Earth’s surface. The present eccentric orbits of the ARTEMIS P1 and P2 spacecraft are used as models for a 1 × 10 Rm orbit of LunaSOX to compute the times of solar eclipse intervals, up to 2 hours in duration between the east and west solar hemispheres at a daily cadence for coronal observations at 1–16 R☉ when the orbital aposelene is in anti-sunward directions. In a low-altitude circular orbit and from the surface, the observational cadences would, respectively, be hourly and biweekly. LunaSOX satellites also carrying in situ space environment instruments could integrate into a network of orbital platforms for space weather monitoring and communications relay to far-side surface lander and permanent base sites, e.g., for low-frequency radio cosmology and detection of exoplanet magnetospheres.

John F Cooper

Solar Wind Ion Sputtering of Sodium from Silicates Using Molecular Dynamics Calculations of Surface Binding Energies

For nearly 40 yr, studies of exosphere formation on airless bodies have been hindered by uncertainties in our understanding of the underlying ion collisional sputtering by the solar wind (SW). These ion impacts on airless bodies play an important role in altering their surface properties and surrounding environment. Much of the collisional sputtering data needed for exosphere studies come from binary collision approximation (BCA) sputtering models. These depend on the surface binding energy (SBE) for the atoms sputtered from the impacted material. However, the SBE is not reliably known for many materials important for planetary science, such as plagioclase feldspars and sodium pyroxenes. BCA models typically approximate the SBE using the cohesive energy for a monoelemental solid. We use molecular dynamics (MD) to provide the first accurate SBE data we are aware of for Na sputtered from the above silicate minerals, which are expected to be important for exospheric formation at Mercury and the Moon. The MD SBE values are ∼8 times larger than the Na monoelemental cohesive energy. This has a significant effect on the predicted SW ion sputtering yield and energy distribution of Na and the formation of the corresponding Na exosphere. We also find that the SBE is correlated with the coordination number of the Na atoms within the substrate and with the cohesive energy of the Na-bearing silicate. Our MD SBE results will enable more accurate BCA predictions for the SW ion sputtering contribution to the Na exosphere of Mercury and the Moon.

Lunar surface

Sputtering of Surfaces by Ion Irradiation: A Comparison of Molecular Dynamics and Binary Collision Approximation Models to Laboratory Measurements

We compare various sputtering simulation methods to experimental results in both the low energy (<1 keV) and high energy (≥1 keV) impact regimes for argon ions impacting a pure copper substrate at normal incidence. Our results indicate that for high energy impacts, both binary collision approximation (BCA) and molecular dynamics methods can be used to generate reasonable predictions for the yield and energy distribution of the sputtered atoms. We also find reasonable agreement between the theoretical and experimental results down to impact energies of 600 eV. However, at 200 eV impact energies, significant discrepancies appear between the experimental and theoretical ejecta energy distributions in the peak position, the width of the energy distribution, and the magnitude of the high energy tail. These discrepancies appear to arise from the experimental results being only for atoms sputtered normal to the substrate surface, whereas the theoretical results are integrated over all 2π solid angles above the surface. Using the BCA code SDTrimSP and limiting the results to only atoms emitted within ±15° of the surface normal brings theory and experiment into reasonable agreement. These results suggest that for low energy impacts, the energy distribution of sputtered atoms is highly dependent on the emission angle of the ejecta.

Solar wind

Was the Sun a Slow Rotator? Sodium and Potassium Constraints from the Lunar Regolith

While the Earth and Moon are generally similar in composition, a notable difference between the two is the apparent depletion in moderately volatile elements in lunar samples. This is often attributed to the formation process of the Moon, and it demonstrates the importance of these elements as evolutionary tracers. Here we show that paleo space weather may have driven the loss of a significant portion of moderate volatiles, such as sodium and potassium, from the surface of the Moon. The remaining sodium and potassium in the regolith is dependent on the primordial rotation state of the Sun. Notably, given the joint constraints shown in the observed degree of depletion of sodium and potassium in lunar samples and the evolution of activity of solar analogs over time, the Sun is highly likely to have been a slow rotator. Because the young Sun's activity was important in affecting the evolution of planetary surfaces, atmospheres, and habitability in the early Solar System, this is an important constraint on the solar activity environment at that time. Finally, as solar activity was strongest in the first billion years of the Solar System, when the Moon was most heavily bombarded by impactors, evolution of the Sun's activity may also be recorded in lunar crust and would be an important well-preserved and relatively accessible record of past Solar System processes.

Prabal Saxena

Evidence Connecting Mercury's Magnesium Exosphere to Its Magnesium‐Rich Surface Terrane

Mercury is surrounded by a tenuous, collisionless exosphere where the surface of the planet is directly exposed to the space environment. As a consequence, impacts and space weathering processes are expected to eject atoms and molecules from the surface into the exosphere, implying a direct link between the exospheric composition and the planet's regolith material. However, observational evidence demonstrating this link has been elusive. Here we report that exospheric magnesium, a species recently discovered and systematically measured by the Mercury Surface, Space ENvironment, GEochemistry, and Ranging mission, is enhanced when observed over a portion of the planet's surface regolith rich in magnesium. These observations confirm a direct link between Mercury's magnesium exosphere and the underlying crustal surface composition, providing strong evidence supporting theoretical arguments that impact vaporization can directly supply material to the exosphere from the regolith of a rocky, airless body.

Aimee W. Merkel

Exospheric Escape: A Parametrical Study

The study of exospheres can help us understand the long-term loss of volatiles from planetary bodies due to interactions of planets, satellites, and small bodies with the interplanetary medium, solar radiation, and internal forces including diffusion and outgassing. Recent evidence for water and OH on the Moon has spurred interest in processes involving chemistry and sequestration of volatile species at the poles and in voids. In recent years, NASA has sent spacecraft to asteroids including Vesta and Ceres, and ESA sent Rosetta to comet 67P/Churyumov–Gerasimenko and the asteroids Lutetia and Steins. Japan's Hayabusa spacecraft returned a sample from asteroid Itakowa, and OSIRIS-REX will return a sample from a primitive asteroid, Bennu, to Earth. In a surface-bounded exosphere, the gases are derived from the surface and thus reflect the composition of the body's regolith, although not in a one-to-one ratio. Observation of an escaping exosphere, termed a corona, is challenging. We have therefore embarked on a parametrical study of exospheres as a function of mass of the exospheric species, mass of the primary body and source velocity distribution, specifically thermal (Maxwell-Boltzmann) and sputtering. The goal is to provide a quick look to determine under what conditions and for what mass of the primary body the species of interest are expected to be bound or escaping and to quickly estimate the observability of exospheric species. This work does not provide a comprehensive model but rather serves as a starting point for further study. These parameters will be useful for mission planning as well as for students beginning a study of planetary exospheres.

Exospheres