Search NASA⌕ Search

Engineering topics

Rudisill, T. S.

Publications and source records attributed to Rudisill, T. S..

Flowsheet for the Neutralization of Accelerated Basin De-inventory (ABD) Material

Under the Accelerated Basin De-inventory (ABD) program H-Canyon will be dissolving aluminum spent nuclear fuel (ASNF) and then neutralizing that solution without performing head-end strike or uranium recovery operations. After dissolution in H-Canyon the material will be neutralized to a free hydroxide concentration of either 0.6 M or 1.2 M to meet the waste acceptance criteria for transfer to the SRS Concentration, Storage and Transfer Facility (CSTF). In order to ensure the material could be successfully neutralized and transferred, SRNL completed experiments with simulated H-Canyon dissolver solutions. Two bounding simulants were developed based on the expected compositions of ASNF to be dissolved, one containing only Gd as the neutron poison and one containing Fe as an additional poison.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Analysis of H-Canyon 6.4D Dissolver Solid

During reconfiguration of the 6.4D dissolver for the dissolution of High Flux Isotope Reactor (HFIR) fuel, solid material was observed on the bottom of the dissolver pot. Samples of the solids were taken from the north and south side of the 6.4D pot and were transported to the Savannah River National Laboratory (SRNL) for characterization. The samples were initially dried, and then a small portion of each sample set was removed, and rinsed with either 1 M HNO 3 or 6 M HNO 3 . A portion of each unrinsed and rinsed sample was dissolved and analyzed for elemental and radiochemical concentrations. Results from the analyses indicated that the solids were primarily Si, Fe, Al, and Cr. The U content in the initial dried, unrinsed solids was 0.380 wt %, but was reduced to 0.057 wt % in the rinsed solids, indicating the majority of the U was mostly soluble in HNO 3 . Small amounts of Pu were measured at 0.010 wt % in both the rinsed and unrinsed solids.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗