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Ryan, M. A.

Publications and source records attributed to Ryan, M. A..

At least 73 records · Page 4

Monitoring the Air Quality in a closed Chamber Using an Electronic Nose

An Electronic Nose is being developed at JPL and Caltech for use in environmental monitoring in the International Space Station. The Electronic Nose (ENose) is an array of 32 polymer film conductometric sensors; the pattern of response may be deconvoluted to identify contaminants in the environment.

Air↗

Temperature and Humidity Dependence of a Polymer-Based Gas Sensor

This paper quantifies the temperature and humidity dependence of a polymer-based gas sensor. The measurement and analysis of three polymers indicates that resistance changes in the polymer films, due to temperature and humidity, can be positive or negative. The temperature sensitivity ranged from +1600 to -320 ppm/nd the relative sensitivity ranged from +1100 to -260 ppm/%.

temperature humidity gas sensor polymers↗

High Temperature Stability of Potassium Beta Alumina

None. From Objectives section: Evaluate the stability of potassium beta alumina under potassium AMTEC operating conditions. Evaluate the stability regime in which potassium beta alumina can be fabricated.

potassium beta aluminum AMTEC potassium AMTEC oper↗

Gas Sensor Test Chip

The use of organic polymers to detect gasses has been known for several years to be an effective means for gas detection via conductivity changes. These chemoresistors offer significant advantages over other gas detectors in that they operate near room temperature and thus can be used in compact, low-power applications.

organic polymers sheet resistance conduction aniso↗

Directly Deposited Current Collecting Grids for Alkali Metal Thermal-to-Electric Converter Electrodes

Current collection in porous thin film electrodes on solid electrolytes has been improved by using thick film grids to decrease sheet and contact resistance in RhW and PtW electrodes. The grids are directly deposited on the solid electrolyte either by sputter- or photodeposition, and the electrode deposited over the grid. Comparison of the performance of electrodes having such underlying grids with that of electrodes without such grids has shown performance, as measured by current or power produced, to be improved by 10-30% in electrodes with grids.

Ryan, M. A.↗

Directly Deposited Current Collecting Grids for AMTEC Electrodes

Current collection in porous thin film electrodes on solid electrolytes has been improved by using thick film grids to decrease sheet and contact resistance in RhW and PtW electrodes. The grids are directly deposited on the solid electrolyte, either by sputter or photodepostion, and the electrode is deposited over the grid. Comparison of the performance of electrodes having such underlying grids with that of electodes without such grids has shown performance, as measured by current or power produced, to be improved by 10-30% in electrodes with grids.

Ryan, M. A.↗

Lifetimes of Electrodes for AMTEC Cells

The lifetime of an AMTEC electrode depends on the rate of grain growth, which in turn depends on the surface self-diffusion coefficient of the electrode material under AMTEC operating conditions. Grain growth rates for molybdenum and platinum-tungsten alloy electrodes have been determined, and have been used to predict operating lifetimes of AMTEC electrodes. For lifetimes of 10 years of more, Mo may be used in AMTEC cells only at operating temperatures under 1100 K. Pt(sub 2.5)W electrodes may be used at much higher temperatures, up to 1300 K.

lifetime surface self-diffusion coefficient↗

Thin Film Electrodes with an Integral Current Collection Grid for Use with Solid Electrolytes

Thin film, high performance electrodes which can operate in high temperature environments are necessary for many devices which use a solid electrolyte. Electrodes of rhodium-tungsten alloy have been deposited on solid electrolyte using photolytic chemical vapor deposition (PCVD). A technique for depositing electrodes and current collection grids simultaneously has been developed using the prenucleation characteristics of PCVD. This technique makes it possible to fabricate electrodes which allow vapor transport through the thin (<1 (micro)m) portions of the electrode while integral thick grid lines improve the electronic conductivity of the electrode, thus improving overall performance.

thin film electrodes solid electrolyte vapor depos↗