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S. N. Milam

Publications and source records attributed to S. N. Milam.

5 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2023

Gas Sources from the Coma and Nucleus of Comet 46P/Wirtanen Observed Using ALMA

Gas-phase molecules in cometary atmospheres (comae) originate primarily from (1) outgassing by the nucleus, (2) sublimation of icy grains in the near-nucleus coma, and (3) coma (photo)chemical processes. However, the majority of cometary gases observed at radio wavelengths have yet to be mapped, so their production/release mechanisms remain uncertain. Here we present observations of six molecular species toward comet 46P/Wirtanen, obtained using the Atacama Large Millimeter/submillimeter Array during the comet's unusually close (∼0.1 au) approach to Earth in 2018 December. Interferometric maps of HCN, CH 3 OH, CH 3 CN, H 2 CO, CS, and HNC were obtained at an unprecedented sky-projected spatial resolution of up to 25 km, enabling the nucleus and coma sources of these molecules to be accurately quantified. The HCN, CH 3 OH, and CH 3 CN spatial distributions are consistent with production by direct outgassing from (or very close to) the nucleus, with a significant proportion of the observed CH 3 OH originating from sublimation of icy grains in the near-nucleus coma (at a scale length L p = 36 ± 7 km). On the other hand, H 2 CO, CS, and HNC originate primarily from distributed coma sources (with L p values in the range 550–16,000 km), the identities of which remain to be established. The HCN, CH 3 OH, and HNC abundances in 46P are consistent with the average values previously observed in comets, whereas the H 2 CO, CH 3 CN, and CS abundances are relatively low.

Short period comets↗
NASA NTRS2022

Phosphine in the Venusian Atmosphere: A Strict Upper Limit from SOFIA GREAT Observations

The presence of phosphine (PH3) in the atmosphere of Venus was reported by Greaves et al. based on observations of the J = 1–0 transition at 267 GHz using ground-based, millimeter-wave spectroscopy. This unexpected discovery presents a challenge for our understanding of Venus's atmosphere, and has led to a reappraisal of the possible sources and sinks of atmospheric phosphorous-bearing gases. Here we present results from a search for PH3 on Venus using the German REceiver for Astronomy at Terahertz Frequencies instrument aboard the Stratospheric Observatory for Infrared Astronomy aircraft, over three flights conducted in November 2021. Multiple PH3 transitions were targeted at frequencies centered on 533 and 1,067 GHz, but no evidence for atmospheric PH3 was detected. Through radiative transfer modeling, we derived a disk-averaged upper limit on the PH3 abundance of 0.8 ppb in the altitude range 75–110 km, which is more stringent than previous ground-based studies.

M. A. Cordiner↗
NASA NTRS2022

A SUBLIME 3D Model for Cometary Coma Emission: The Hypervolatile-rich Comet C/2016 R2 (PanSTARRS)

The coma of comet C/2016 R2 (PanSTARRS) is one of the most chemically peculiar ever observed, in particular due to its extremely high CO/H2O and N(+2)/H2O ratios, and unusual trace volatile abundances. However, the complex shape of its CO emission lines, as well as uncertainties in the coma structure and excitation, has lead to ambiguities in the total CO production rate. We performed high-resolution, spatially, spectrally, and temporally resolved CO observations using the James Clerk Maxwell Telescope and Submillimeter Array to elucidate the outgassing behavior of C/2016 R2. Results are analyzed using a new, time-dependent, three-dimensional radiative transfer code (SUBlimating gases in LIME; SUBLIME, based on the open-source version of the LIne Modeling Engine), incorporating for the first time, accurate state-to-state collisional rate coefficients for the CO–CO system. The total CO production rate was found to be in the range of (3.8 − 7.6) × 10^(28) per s between 2018 January 13 and February 1 (at r(H) = 2.8–2.9 au), with a mean value of (5.3 ± 0.6) × 10^(28) per s. The emission is concentrated in a near-sunward jet, with a half-opening angle of ∼62° and an outflow velocity of 0.51 ± 0.01 km/s, compared to 0.25 ± 0.01 km/s in the ambient (and nightside) coma. Evidence was also found for an extended source of CO emission, possibly due to icy grain sublimation around 1.2 × 10^(5) km from the nucleus. Based on the coma molecular abundances, we propose that the nucleus ices of C/2016 R2 can be divided into a rapidly sublimating apolar phase, rich in CO, CO2, N2, and CH3OH, and a predominantly frozen (or less abundant), polar phase containing more H2O, CH4, H2CO, and HCN.

Martin Andrew Cordiner↗
NASA NTRS2021

Sublimation of Laboratory Ices Millimeter/Submillimeter Experiment (SubLIME): Structure-Specific Identifications of Products from UV-photolyzed Methanol Ice

Submillimeter/far-IR spectroscopy was used to detect and quantify organic molecules sublimated after the ultraviolet photolysis (at 12 K) and warm-up (up to 300 K) of a methanol (CH3OH) ice sample. Eleven sublimated photoproducts were uniquely identified: carbon monoxide (CO), formaldehyde (H2CO), ketene (C2H2O), acetaldehyde (CH3CHO), ethylene oxide (CH2OCH2), vinyl alcohol (CH2CHOH), ethanol (CH3CH2OH), dimethyl ether (CH3OCH3), methyl formate (HCOOCH3), glycolaldehyde (HOCH2CHO), and acetone ((CH3)2CO). Two additional products were detected in the photolyzed ice by Fourier-transform infrared (FTIR) spectroscopy: carbon dioxide (CO2) and methane (CH4). The rotational temperatures and gas densities were calculated for the organics containing two or more C atoms via a rotation diagram analysis, and the gas-phase submillimeter/far-IR technique was used in tandem with mass spectrometry and FTIR spectroscopy of the ice during photolysis. The abundance ratios of the sublimated species (normalized to methanol) were compared to those observed in hot cores (Orion-KL, Sagittarius B2(N), and IRAS 16293-2422(B)) and in comets C/2014 Q2 (Lovejoy) and 67P/Churyumov–Gerasimenko.

K. M. Yocum↗