Electron energy-loss and soft X-ray emission spectroscopy of electronic structure of MgB{sub 4}
The electronic structure of MgB{sub 4}, with the characteristic crystal structure comprising one-dimensional pentagonal B{sub 6} cluster chain, was investigated using electron energy-loss spectroscopy and soft X-ray emission spectroscopy based on transmission electron microscopy. The dielectric function and density of state of unoccupied and occupied states were clarified experimentally for the first time. Although theoretical calculations has predicted MgB{sub 4} to be a semiconductor, the electron energy-loss spectrum in this study show a plasmon peak at 0.4 eV, which might be due to carrier electrons. Theoretical calculations suggested that the electronic states near the Fermi energy are localized along the one dimensional B{sub 6} cluster chain. Therefore, one–dimensional electric conductivity is expected. - Graphical abstract: Crystal structure of MgB{sub 4} consists of one-dimensional B{sub 6} cluster chain. The electronic structure characteristic to one-dimensionality is explored by using experimental EELS and SXES measurements based on TEM and first principle calculation. Display Omitted - Highlights: • The electronic structure of MgB{sub 4} is investigated using EELS and SXES based on TEM. • The peak at 0.4 eV in low-loss spectrum implies carriers with low density. • DOSs in VB and CB were revealed from B K emission and B K-shell excitation spectra. • Wien2K shows electronic states near Fermi level located along B{sub 6} cluster chains. • One dimensional behavior of the carriers is expected in MgB{sub 4}.