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Salama, Farid

Publications and source records attributed to Salama, Farid.

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Introducing NASA Ames' New Infrared Optical Constant Facility. Determinations of Complex Refractive Indices for Titan Aerosol Analogs and Other Applications

A new optical constant facility has been developed at NASA Ames that will allow the determination of optical constants in the infrared of various materials, analogs of (exo)planetary hazes and cloud particles. Our facility is composed of a Fourier Transform Infrared (FTIR) spectrometer continuously covering the Near-IR to Far-IR range (from 0.74 to 200 μm), coupled to variable angle transmittance and reflectance accessories that allow the characterization of the scattering properties of non-homogeneous samples (laboratory (exo)planetary aerosol analogs, films, slabs of material, crystals, powders, etc.) over a wide incidence and emittance angle range (0-90 degrees). This new experimental setup allows the characterization of angular light distribution in both transmission and reflection measurements, and enables the determination of the complex indices of refraction, n and k, over the full NIR-FIR range via modeling of the laboratory measurements. The resulting refractive indices are critical input parameters in radiative transfer models, microphysical models, cloud models, protoplanetary disk simulations and other models used for the interpretation of observational data from past, current and future (exo)planetary NASA missions. Here we present a description of the facility along with the first determination of optical constants for Titan aerosol analogs produced in the Titan Haze Simulation (THS) experiment on COSmIC, a unique experimental setup developed at NASA Ames that allows the simulation of Titan’s complex atmospheric chemistry at Titan-like temperature (200 K). We also introduce a new study of the optical properties of ammonium-bearing phosphates, potential cloud particles forming in temperate exoplanets and brown dwarfs.

Sciamma-O'Brien, Ella M.↗
NASA NTRS2019

Laboratory Investigations of Cloud Particle Formation and Sublimation on Titan, Mars, and Earth

Microphysical modeling of cloud formation and growth relies on fundamental measurements of the properties of condensable gases which form cloud particles. NASA's Ames Chemistry Laboratory has the capability to measure vapor pressures and heterogeneous nucleation conditions for a variety of gases found in the atmospheres of solar system bodies. Highlights from work for Earth, Mars, and Titan demonstrate the range of conditions and atmospheres studied to date.

Iraci, Laura T.↗
NASA NTRS2019

Laboratory Astrophysics Studies of the Evolution of Organic Matter with the COSmIC Facility.

Understanding the origin of organic matter in astrophysical environments ranging from circumstellar (CS) outflows to diffuse and dense interstellar (IS) clouds to protoplanetary disks and planetary bodies has become a central objective in astrophysics. Experimental facilities dedicated to the formation and characterization of laboratory analogs generated under conditions relevant to the targeted environments have been developed in the past recent years. Recent advances achieved in laboratory astrophysics using COSmIC’s laboratory data in synergy with observational data will be presented. These results include the use of laboratory spectra to search for IS organic molecules and ions in astronomical spectra, the formation of laboratory analogs of CS and IS dust grains and planetary atmospheres aerosols from molecular precursors.

Salama, Farid↗
NASA NTRS2019

Laboratory Astrophysics at NASA Ames: Recent Results and Advances

The Cosmic SImulation Chamber (COSmIC) facility was developed at NASA Ames to study, in the laboratory, neutral and ionized molecules and nanoparticles under the low temperature and high vacuum conditions representative of interstellar, circumstellar and planetary environments. COSmIC is composed of a Pulsed Discharge Nozzle expansion that generates a plasma in a free supersonic jet expansion coupled to highsensitivity, complementary in situ diagnostic tools, used for the detection and characterization of the species present in the expansion: a Cavity Ring Down Spectroscopy and fluorescence spectroscopy systems operating in the UV-Visible range, and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS). We will present recent advances that were achieved in laboratory astrophysics using COSmIC. These include advances in the domain of the diffuse interstellar bands (DIBs) and in the formation of dust grains and aerosols from their gas-phase molecular precursors in environments as varied as circumstellar outflows and planetary atmospheres. An extension of the spectral response of the facility into the infrared (IR) range is in progress with the addition of a high-resolution near-IR to mid-IR CRDS system that will allow to further investigate cosmic molecules and grains with COSmIC. Acquisition of laser induced fluorescence spectra of cosmic molecule analogs and the laser induced incandescence spectra of cosmic grain analogs are also planned. Preliminary results in these fronts will presented and the implications of the on-going studies for astronomy will be addressed.

Laboratory↗
NASA NTRS2019

The New NASA Ames Infrared Optical Constant Facility. Determinations for Titan Aerosol-, and Exoplanet and Brown Dwarf Cloud Particle Analogs

Here we present a new optical constant facility developed at NASA Ames that will allow the determination of optical constants in the infrared of various materials, analogs of hazes and cloud particles in (exo)planet atmospheres and brown dwarfs. Our facility is composed of a Fourier Transform Infrared (FTIR) spectrometer continuously covering the Near-IR, mid-IR and Far-IR range (from 0.74 to 200 µm), coupled to variable angle transmittance and reflectance accessories that allow the characterization of the scattering properties of nonhomogeneous samples (laboratory planetary aerosol analogs, films, slabs of material, crystals, powders...) over a wide incidence and emittance angle range (0-90 degrees). This permits the angular light distribution in both transmission and reflection measurements to be characterized, enabling the determination of the complex indices of refraction, n and k, over the full NIR-FIR range via modeling of the laboratory observations. The resulting refractive indices are critical input parameters in radiative transfer models, exoplanet and brown dwarf cloud models, protoplanetary disk simulations and other models used for the interpretation of observational data from past, current and future (exo)planetary NASA missions. We will present preliminary data obtained on Titan aerosol analogs produced in the Titan Haze Simulation (THS) experiment on COSmIC, a unique experimental platform developed at NASA Ames that allows the simulation of Titan's complex atmospheric chemistry at Titan-like temperature (200 K). We will also introduce a new study of the optical properties of ammonium-bearing phosphates, potential cloud particles forming in temperate exoplanets and brown dwarfs.

Planetary Science↗
NASA NTRS2018

Interstellar PAHs: From Ground to Space, Expanding Spectroscopic Frontiers

Recent progress in astrochemistry and in our understanding of the Molecular Universe has been driven by new detector technologies and advances in ground-, airborne- and space astronomy coupled to new, innovative approaches in molecular spectroscopy. The search for the complex carbon-based molecules (PAHs, Fullerenes, nanoparticles) thought to be responsible for the ubiquitous infrared emission bands (UIBs) and optical absorption bands (DIBs) that are observed in various regions of the interstellar medium of local- and extragalactic environments illustrates the progress in spectroscopy techniques that has been driven by astronomy. Recent progresses reached in this domain will be discussed together with the laboratory techniques that have been developed to measure the spectra of laboratory analogs of cosmic molecules in the UV Visible-NIR range under experimental conditions that attempt to reproduce the interstellar conditions.

Laboratory astrophysics and astrochemistry↗
NASA NTRS2018

NASA Ames' COSmIC Laboratory Astrophysics Facility: Recent Results and Progress

The COSmIC facility was developed at NASA Ames to study interstellar, circumstellar and planetary analogs in the laboratory]. COSmIC stands for "Cosmic Simulation Chamber" and is dedicated to the study of neutral and ionized molecules and nanoparticles under the low temperature and high vacuum conditions that are required to simulate space environments. COSmIC integrates a variety of instruments that allow generating; processing and monitoring simulated space conditions in the laboratory. It is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a plasma in a free supersonic jet expansion coupled to high-sensitivity, complementary in situ diagnostic tools, used for the detection and characterization of the species present in the expansion: a Cavity Ring Down Spectroscopy (CRDS) and fluorescence spectroscopy systems for photonic detection, and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent advances achieved in laboratory astrophysics using COSmIC will be presented, in particular in the domain of the diffuse interstellar bands (DIBs) and the monitoring, in the laboratory, of the formation of dust grains and aerosols from their gasphase molecular precursors in environments as varied as circumstellar outflows and planetary atmospheres. Plans for future laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics (NIR-MIR CRDS, Laser Induced Fluorescence spectra of cosmic molecule analogs and the laser induced incandescence spectra of cosmic grain analogs) will also be addressed as well as the implications of the on-going studies for astronomy.

Laboratory Astrophysics↗
NASA NTRS2017

The Diffuse Interstellar Bands: Solving a Century Old Problem

The Diffuse Interstellar Bands (DIBs) are a set of apporoximately 500 absorption bands that are seen in the spectra of reddened stars (i.e., stars obscured by the presence of interstellar clouds in their line of sight). The first DIBs were detected in the visible over a century ago. Diffuse Interstellar Bands are now detected from the near ultraviolet to the near infrared in the spectra of reddened stars spanning a variety of interstellar environments in our local, and in other galaxies. Although DIB carriers are a significant part of the interstellar chemical inventory as they account for a noticeable fraction of the interstellar extinction, the nature of their carriers is still unknown over a century after the detection of the first bands. DIB carriers are stable and ubiquitous in a broad variety of interstellar environments and play a unique role in interstellar physics and chemistry. It has long been realized that the solving of the DIB problem requires a strong synergy between astronomical observations, laboratory astrophysics and astrochemistry, quantum chemistry calculations and astrophysical modeling of line-of-sights. In this review, we'll present and discuss the current state of this perplexing problem. We'll review the progress and the failures that have been encountered in the long quest for the identification of the carriers of these ubiquitous interstellar bands.

Molecules in Space↗
NASA NTRS2017

Recent Progress in Laboratory Astrophysics and Astrochemistry Achieved with the COSmIC Facility

We describe the characteristics and the capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for "Cosmic Simulation Chamber" and is dedicated to the study of neutral and ionized molecules and nanoparticles under the low temperature and high vacuum conditions that are required to simulate various space environments such as diffuse interstellar clouds, circumstellar outflows and planetary atmospheres. COSmIC integrates a variety of state-of-the-art instruments that allow recreating simulated space conditions to generate, process and monitor cosmic analogs in the laboratory. The COSmIC experimental setup is composed of a Pulsed Discharge Nozzle (PDN) expansion, that generates a plasma in the stream of a free supersonic jet expansion, coupled to high-sensitivity, complementary in situ diagnostics: cavity ring down spectroscopy (CRDS) and laser induced fluorescence (LIF) systems for photonic detection, and Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent results obtained using COSmIC will be highlighted. In particular, the progress that has been achieved in the domain of the diffuse interstellar bands (DIBs) and in monitoring, in the laboratory, the formation of circumstellar dust grains and planetary atmosphere aerosols from their gas-phase molecular precursors. Plans for future laboratory experiments on interstellar and planetary molecules and grains will also be addressed, as well as the implications of the studies underway for astronomical observations and past and future space mission data analysis.

Salama, Farid↗
NASA NTRS2016

Formation of Cosmic Carbon Dust Analogues in Plasma Reactors

Cosmic carbon dust analogs are produced, processed and analyzed in the laboratory using NASA's COSmIC (COSmIC Simulation Chamber) Facility. These experiments can be used to derive information on the most efficient molecular precursors in the chemical pathways that eventually lead to the formation of carbonaceous grains in the stellar envelopes of carbon stars.

Astrophysics↗
NASA NTRS2016

The Past and Future of AstroPAH Research and the Diffuse Interstellar Bands

Here, we present a critical assessment of the PAHs as DIB Carriers and discuss the progress and the advances that have been achieved so far through a series of complementary studies involving astronomical observations of DIBs, laboratory simulation of interstellar analogs for PAHs (neutrals and ions), space exposure experiments of PAHs, theoretical calculations of PAH spectra and the modeling of diffuse and translucent interstellar clouds. We will discuss what we have learned from these complementary studies, the constraints that can be derived from these studies for the PAHs as DIB carriers and the future studies that are required to address the open questions. These involve extending the laboratory and astronomical PAH-DIB studies from the NUV-Visible range into the NIR and MIR domains where DIBs have also been observed and developing tools in the laboratory to help generate more complex, PAH-related species for comparison with astronomical data. For the laboratory part, we will present the COSmIC facility at NASA-Ames that provides experimental conditions that closely mimic the interstellar conditions and helps address these issues. The comparison of astronomical data with laboratory data measured under realistic conditions is the only way to derive clear and unambiguous conclusions regarding the expected abundances for PAHs of various sizes and charge states in interstellar environments. From the observational aspect we will explore the new opportunities offered by JWST to connect the DIBs to MIR PAH emission and to search for NIR DIBs that may trace the presence of PAHs.

Salama, Farid↗
NASA NTRS2016

ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES) - Merging Observations and Laboratory Data

The Diffuse Interstellar Bands (DIBs) are a set of ~500 absorption bands that are detected in the spectra of stars with interstellar clouds in the line of sight. DIBs are found from the NUV to the NIR in the spectra of reddened stars spanning different interstellar environments in our local, and in other galaxies. DIB carriers are a significant part of the interstellar chemical inventory. They are stable and ubiquitous in a broad variety of environments and play a unique role in interstellar physics/chemistry. It has long been realized that the solving of the DIB problem requires a strong synergy between astronomical observations, laboratory astrophysics, and astrophysical modeling of line-of-sights. PAHs are among the molecular species that have been proposed as DIB carriers. We will present an assessment of the PAH-DIB model in view of the progress and the advances that have been achieved over the past years through a series of studies involving astronomical observations of DIBs, laboratory simulation of interstellar analogs for neutrals and ionized PAHs, theoretical calculations of PAH spectra and the modelization of diffuse and translucent interstellar clouds. We will present a summary of what has been learned from these complementary studies, the constraints that can now be derived for the PAHs as DIB carriers in the context of the PAH-DIB model and how these constraints can be applied to the EDIBLES project. The spectra of several neutral and ionized PAHs isolated in the gas phase at low temperature have been measured in the laboratory under experimental conditions that mimic interstellar conditions and are compared with an extensive set of astronomical spectra of reddened, early type stars. The comparisons of astronomical and laboratory data provide upper limits for the abundances of specific neutral PAH molecules and ions along specific lines-of-sight. Something that is not attainable from infrared observations alone. We present the characteristics of the laboratory facilities, MIS and COSmIC, that have been developed for this study and discuss the findings resulting from the comparison of the laboratory data with high resolution, high S/N ratio astronomical observations. MIS stands for Matrix Isolation Spectroscopy, a well-proven technique for isolating cold molecular species in inert solid environments. COSmIC stands for Cosmic Simulation Chamber. It combines a supersonic free jet expansion with discharge plasma and high-sensitivity cavity ringdown spectroscopy and time-of-flight mass spectrometry detection tools for the generation and the detection of cold, isolated gas-phase molecules and ions under experimental conditions that closely mimic interstellar conditions. The column densities of the individual neutral PAH molecules and ions probed in these surveys are derived from the comparison of these unique laboratory data with high resolution, high S/N ratio astronomical observations. The comparisons of astronomical and laboratory data lead to clear and unambiguous conclusions regarding the expected abundances for PAHs of various sizes and charge states in the interstellar environments probed in the surveys. Band profile comparisons between laboratory and astronomical spectra lead to information regarding the molecular structures and characteristics associated with the DIB carriers in the corresponding lines-of-sight. These quantitative surveys of neutral and ionized PAHs in the optical range open the way for unambiguous quantitative searches of PAHs and complex organics in a variety of interstellar and circumstellar environments.

astrophysics↗
NASA NTRS2015

Organics in Space: Results from Space Exposure Platforms and Nanosatellites

A series of successful laboratory astrophysics experiments performed on International Space Station(ISS) external platforms such as EXPOSE have provided insights into the evolution of organic and biological materials in space and planetary environments. The study of the reactions, destruction, and longevity of organics in the space environment is of fundamental interest. To provide an accurate outer space environment for extended durations, exposure experiments in low Earth orbit have been conducted in the last decades in order to examine the consequences of actual space conditions including combinations of solar and cosmic radiation, space vacuum, and microgravity. The OOREOS (OrganismORganic Exposure to Orbital Stresses) nanosatellite studied in situ during the 6-month primary and 1-year extended mission the photochemical processing of selected PAHs in low Earth orbit (650 km altitude); results were autonomously telemetered to Earth. We report on the methods and flight preparation of samples for space exposure platforms and results on the stability of organic thin-films. The UV-vis degradation process of thin-films was recorded over time, which revealed intriguing and counter-intuitive photolytic kinetics that will be re-investigated on the ISS in a space environment.

Space weathering↗
NASA NTRS2015

The THS Experiment: Simulating Titans Atmospheric Chemistry at Low Temperature (200K)

In Titan's atmosphere, composed mainly of N2 (95-98%) and CH4 (2-5%), a complex chemistry occurs at low temperature, and leads to the production of heavy organic molecules and subsequently solid aerosols. Here, we used the Titan Haze Simulation (THS) experiment, an experimental setup developed at the NASA Ames COSmIC simulation facility to study Titan's atmospheric chemistry at low temperature. In the THS, the chemistry is simulated by plasma in the stream of a supersonic expansion. With this unique design, the gas is cooled to Titan-like temperature ( approximately 150K) before inducing the chemistry by plasma, and remains at low temperature in the plasma discharge (approximately 200K). Different N2-CH4-based gas mixtures can be injected in the plasma, with or without the addition of heavier precursors present as trace elements on Titan, in order to monitor the evolution of the chemical growth. Both the gas- and solid phase products resulting from the plasma-induced chemistry can be monitored and analyzed using a combination of complementary in situ and ex situ diagnostics. A recent mass spectrometry[1] study of the gas phase has demonstrated that the THS is a unique tool to probe the first and intermediate steps of Titan's atmospheric chemistry at Titan-like temperature. In particular, the mass spectra obtained in a N2-CH4-C2H2-C6H6 mixture are relevant for comparison to Cassini's CAPS-IBS instrument. The results of a complementary study of the solid phase are consistent with the chemical growth evolution observed in the gas phase. Grains and aggregates form in the gas phase and can be jet deposited on various substrates for ex situ analysis. Scanning Electron Microscopy images show that more complex mixtures produce larger aggregates. A mass spectrometry analysis of the solid phase has detected the presence of aminoacetonitrile, a precursor of glycine, in the THS aerosols. X-ray Absorption Near Edge Structure (XANES) measurements also show the presence of imine and nitrile functional groups, showing evidence of nitrogen chemistry. These complementary studies show the high potential of THS to better understand Titan's chemistry and the origin of aerosol formation.

Laboratory↗
NASA NTRS2015

Laser Induced Fluorescence Spectroscopy of Neutral and Ionized Polycyclic Aromatic Hydrocarbons in the Cosmic Simulation Chamber

Polycyclic aromatic hydrocarbon (PAH) molecules are considered the best carriers to account for the ubiquitous infrared emission bands. PAHs have also been proposed as candidates to explain the diffuse interstellar bands (DIBs), a series of absorption features seen on the interstellar extinction curve and are plausible carriers for the extended red emission (ERE), a photoluminescent process associated with a wide variety of interstellar environments. Extensive efforts have been devoted over the past two decades to characterize the physical and chemical properties of PAH molecules and ions in space. Absorption spectra of PAH molecules and ions trapped in solid matrices have been compared to the DIBs. Absorption spectra of several cold, isolated gas-phase PAHs have also been measured under experimental conditions that mimic the interstellar conditions. The purpose of this study is to provide a new dimension to the existing spectroscopic database of neutral and single ionized PAHs that is largely based on absorption spectra by adding emission spectroscopy data. The measurements are based on the laser induced fluorescence (LIF) technique and are performed with the Pulsed Discharge Nozzle (PDN) of the COSmIC laboratory facility at NASA Ames laboratory. The PDN generates a plasma in a free supersonic jet expansion to simulate the physical and the chemical conditions in interstellar environments. We focus, here, on the fluorescence spectra of large neutral PAHs and their cations where there is a lack of fluorescence spectroscopy data. The astronomical implications of the data (e.g., ERE) are examined.

Laboratory↗
NASA NTRS2015

Laboratory Studies of Cosmic Dust with NASA Ames' COSmIC Facility – Applications to Interstellar and Planetary Issues

I will present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in deciphering the diffuse interstellar bands (DIBs) and in monitoring in the laboratory the formation of solid dust grains from their gas-phase molecular precursors in environments as varied as stellarcircumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed as well as the implications of these studies for current and upcoming space missions.

COSmIC↗
NASA NTRS2014

The Formation of Solid Particles from their Gas-Phase Molecular Precursors in Cosmic Environments with NASA Ames' COSmIC Facility

We present and discuss the unique characteristics and capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for Cosmic Simulation Chamber and is dedicated to the study of molecules and ions under the low temperature and high vacuum conditions that are required to simulate interstellar, circumstellar and planetary physical environments in space. COSmIC integrates a variety of state-of-the-art instruments that allow forming, processing and monitoring simulated space conditions for planetary, circumstellar and interstellar materials in the laboratory. COSmIC is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a free jet supersonic expansion coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a Cavity Ring Down Spectroscopy (CRDS) system for photonic detection and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent, unique, laboratory astrophysics results that were obtained using the capabilities of COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid gains from their gas-phase molecular precursors in environments as varied as stellar/circumstellar outflow and planetary atmospheres. Plans for future, next generation, laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics will also be addressed as well as the implications of these studies for current and upcoming space missions.

COSmIC↗