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Sarah J. Snyder

Publications and source records attributed to Sarah J. Snyder.

XSP Methane Sensors Test and Evaluation Project “M-Step”

Methane sensor technology is employed in industry sectors from oil and gas to agriculture, landfills, and monitoring of natural emissions. The US oil and gas sector is extensive in scale, critical to fulfilling US energy needs, and deals with commodities presenting enormous challenges for personnel safety and the environment. Thus, it is imperative that they have accurate and responsive sensors to detect hazardous gases such as methane. US space launch systems will increasingly also use liquefied methane and liquefied natural gas (LNG), which is mostly methane, in quantities large and small, as main and auxiliary propulsion and power. Some of these systems will be reusable, which adds the unique challenge of processing a vehicle that has residual commodities and has returned to its launch site to be readied for its next launch. The methane sensors test and evaluation project (M-STEP) began within the context of a reusable launch system, the Defense Advanced Research Projects Agency (DARPA) Experimental Spaceplane (XSP) program, which would have employed a high-pressure gaseous methane and gaseous oxygen reaction control system. Although the XSP partnership between Boeing and DARPA was terminated by Boeing in early 2020, DARPA and KSC have continued to collaborate in the area of gas sensors with the hydrogen sensor test and evaluation project (H-STEP) and with M-STEP. The NASA Launch Services program (LSP) invested in M-STEP in FY 2021 “to evaluate and understand the state-of-the-art in methane gas sensors”. M-STEP and the LSP effort was complementary, pushing in the same direction to understand US launch system stakeholder needs and approaches, requirements internal (NASA) and external, and commercially available or forthcoming methane sensing technologies, practices, and approaches. In addition, M-STEP (as with H-STEP) enhances KSC capabilities and understanding of these technologies, informing agency investments and further research in these areas.

Tracy L. Gibson↗

Using Electrostatic Principles to Separate Out Nutrients from ECLSS Wastewater Brines

This project will study the use electrostatics to perform electrostatic separation and recovery of Environmental Control and Life Support Systems (ECLSS) waste brines. Currently we have no way to perform nutrient recovery on ECLSS waste brines. This process can give us a competing way to separate sodium from potassium to allow tandem production of acids, bases, and plant fertilizers to run upstream operations and hydroponic systems respectively (when combined with electrodialysis). If we can recover valuable chemicals from brine, then this will decrease resupply from earth, which will allow tremendous (multiple kilograms a day up-mass reduction) cost savings. In addition, using electrostatics for regolith enrichment allow much reduced mining costs for metal production on celestial bodies and allow a smaller mining footprint.

Michael D. Hogue↗

Wastewater Brine Purification and Recovery through Electrodialysis Ion Exchange

Reutilizing resources onboard the International Space Station (ISS) and for future deep space missions are critical for mission longevity and sustainability. Wastewater brine produced from water recovery systems contain chemical species that could be processed into a potential fertilizer for future plant systems. This can be achieved through a process called electrodialysis ion exchange. Wastewater containing inorganic salt components are fed through a series of ion exchange membranes to produce fertilizer (a phosphate rich stream), electrolysis-grade water, and other useful commodities. Electrodialysis cells consisting of anion and cation exchange membranes, monovalent anion exchange membranes, and bipolar membranes were utilized to achieve selective ion exchange. The use of the electrodialysis cells were effective for both water extraction and ion separation. Ions successfully diffused across their respective membranes into the concentrate, acid, and base streams. This resulted in pure water, a phosphate rich stream, and a separate anion/hydrogen and cation/hydroxide stream. However, sulfate and some phosphate ions were able to diffuse through the monovalent anion exchange membrane into the acid stream. This resulted in predominantly phosphate ions remaining in the concentrate. Optimization of the process was accomplished by altering flowrates of each stream and initial volumes, adjusting the power input and resulting current through each cell, and varying the starting parameters by splitting the inorganic waste input into the diluate and the concentrate. As expected, increasing the flowrate and the power input to each cell reduced the overall time of the process. However, mission constraints may require a longer duration process in order to reduce the power consumption. Further analysis will be required to determine the power input necessary to achieve ion diffusion effectively and in a timely manner.

Ion Exchange Membranes↗