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Sarrao, J. L.

Publications and source records attributed to Sarrao, J. L..

Magnetic properties of Ce x Y 1-x Pt compared to Ce x La 1-x Pt ones

In this paper, we have investigated the magnetic properties of the Ce x Y 1-x Pt Kondo ferromagnetic alloy system in the temperature range from 1.8 K to 320 K. The results of these investigations can be summarized as follows: dc-susceptibility can be described by the Curie-Weiss law at higher temperatures down to about 100 K, but also at low temperatures above the ferromagnetic phase transition. At higher temperatures, the extracted Curie-Weiss parameter, θ p , is negative and at low temperature θ C is positive. The extracted effective magnetic moment above 100 K increases with the Ce content up to almost the theoretical value of the isolated Ce 3+ ion, μ = 2.54 μ B , for CePt. This suggests an increase of the hybridization with decreasing Ce content, or said equivalently, it means that the increase of the Kondo interaction diminishes effective magnetic moment. These observations confirm the main conclusions inferred from an earlier transport properties investigation of this alloy system. The corresponding θ C differs within 1 K from the Curie temperature, T C , which is determined by the resistivity measurements. The most intriguing result of the investigation of Ce x Y 1-x Pt is the linear concentration dependence of T C vs. x and, moreover, it is the same as in Ce x La 1-x Pt although in the former system the hybridization diminishes considerably the effective magnetic moment per Ce ion, while in the latter system, hybridization is minor and independent of x. Finally, we offer the explanations of these intriguing experimental results.

36 MATERIALS SCIENCE↗

Transport properties of the Ce x Y 1-x Pt alloy system: Unusual concenration dependence of the Curie temperature

Here, in order to study Kondo ferromagnetism of CePt, we have investigated the transport properties, resistivity and thermopower, of the Ce x Y 1-x Pt alloy system from 2 K to 320 K. The extracted magnetic contribution to the total resistivity cannot be scaled to the concentration and is much higher than in the Ce x La 1-x Pt alloy system. The maximum of the magnetic contribution of the resistivity moves to lower temperatures with decreasing the Ce content while the temperature of the minimum of the thermopower does not change with concentration. These two facts seem to be in contradiction. Usually one assumes that these extrema represent the Kondo temperature. To the contrary, we show that the Kondo temperature increases with decreasing Ce content. The most intriguing observation in this alloy system is the linear relationship between the Curie temperature and the concentration of the Ce ions and, moreover, that it is the same as in Ce x La 1-x Pt. Lastly, this fact is in contradiction with the conventional picture of small moment Kondo magnetism.

36 MATERIALS SCIENCE↗

Unusual diffusive effects on the ESR of Nd 3+ ions in the tunable topologically nontrivial semimetal YBiPt

Electron spin resonance (ESR) of diluted Nd 3+ ions in the topologically nontrivial semimetallic (TNSM) YBiPt compound is reported. The cubic YBiPt compound is a non-centrosymmetric half Heusler material which crystallizes in the F43m space group. The low temperature Nd 3+ ESR spectra showed a g-value of 2.66(4) corresponding to a ${{\Gamma}_{6}}$ cubic crystal field Kramers' doublet ground state. Remarkably, the observed metallic and diffusive (Dysonian) Nd 3+ lineshape presented an unusual dependence with grain size, microwave power, Nd 3+ concentration and temperature. Furthermore, the spin dynamic of the localized Nd 3+ ions in YBiPt was found to be characteristic of a phonon-bottleneck regime. It is claimed that, in this regime for YBiPt, phonons are responsible for mediating the diffusion of the microwave energy absorbed at resonance by the Nd 3+ ions to the thermal bath throughout the skin depth ($\delta \simeq 15$ μm). We argue that this is only possible because of the existence of highly mobile conduction electrons inside the skin depth of YBiPt that are strongly coupled to the phonons by spin–orbit coupling. Thus, our unexpected ESR results point to a coexistence of metallic and insulating behaviors within the skin depth of YBiPt. This scenario is discussed in the light of the TNSM properties of this compound.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗