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Schaeffer, O. A.

Publications and source records attributed to Schaeffer, O. A..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Total nitrogen content of deep sea basalts

An estimate of the total nitrogen content of the earth's mantle, aimed at furnishing a further constraint for earth atmosphere origin and evolution models, was attempted through thermal neutron activation analysis via N-14(n,p)C-14 for the case of deep sea basalt glasses from the East Pacific Rise, the Mid-Atlantic Rift, and the Juan de Fuca Ridge. The increased nitrogen abundance of matrix material from the same samples as the glasses may be due to the incorporation of chemically-bound nitrogen from sea water, rather than dissolved molecular nitrogen. A discussion is presented of factors affecting observed basalt nitrogen content and its interpretation in terms of mantle nitrogen abundance. A 2 ppm N lower limit is estimated for the mantle.

Norris, T. L.↗
NASA NTRS1982

An estimate of atmospheric contamination of Allende coarse-grained inclusion 3529Z

Studies conducted by Zaikowski and Schaeffer (1979) have shown that minerals can take up rare gases when exposed to the atmosphere. Herzog et al. (1980) have conducted a laser microprobe study of coarse-grained Ca-Al-rich inclusions from the Allende meteorite. The amount of Ar-40 found in the Allende minerals is less than the equilibrium amount found for a synthetic serpentine by Zaikowski and Schaeffer. The present investigation has the objective to obtain a better estimate for the absorption of atmospheric argon by the minerals in Allende. Ar-38 was used as a tracer to investigate the diffusion of argon into a coarse-grained Ca-Al-rich inclusion from Allende. On the basis of the results obtained in the current investigation, it is believed that atmospheric contamination is not the cause for the extra argon and the above 4.55 G.y. ages in the case of the considered Allende inclusion.

Warasila, R.↗
NASA NTRS1980

Ar-39/Ar-40 systematics of Allende inclusions

A laser microprobe was used to measure the Ar isotopic contents of individual mineral grains in four neutron-irradiated Allende samples: two coarse-grained Ca-Al-rich inclusions; one fine-grained Ca-Al-rich inclusion; and one sample with matrix and miscellaneous chondrules. The following K-Ar ages (G.y.) were obtained after degassing low Ar retentive sites by preheating the samples for one hour at 675 C: matrix, 3.5 + or - 0.2; three miscellaneous chondrules, 4.4 + or - 0.1, 4.0 + or - 0.1, and 4.4 + or - 0.1; and the fine-grained inclusion, 4.5 + or - 0.2. The minerals in the coarse-grained Ca-Al-rich inclusions have ubiquitous chlorine, less than 10 ppm K and apparent ages ranging upwards from 4.6 G.y. to well over 10 G.y. Possible explanations for these apparent ages are atmospheric contamination, the decay of K-40 prior to the formation of the solar system, and the trapping of radiogenic Ar-40 lost by the matrix.

Herzog, G. F.↗
NASA NTRS1979

Solubility of noble gases in serpentine - Implications for meteoritic noble gas abundances

An investigation of the solubilities of the noble gases from synthesis and solubility studies of the sheet silicate mineral serpentine in carbonaceous chondrites is presented. Hydrothermal synthesis and exchange experiments were made at 340C and 1 kbar with noble gas partial pressures from 2 times 10 to the -8th power to 0.1 atm. The measured distribution coefficients for noble gases are not sufficiently high to account for the trapped noble gases in carbonaceous chondrites by exchange in solar nebula if meteoritic minerals have comparable distribution coefficients. Also, serpentine gains and loses noble gases to approach equilibrium values with the terrestrial atmosphere, indicating that this exposure may have influenced the noble gas abundances in phyllosilicate minerals of these chondrites. The dispersion of K-Ar ages of carbonaceous chondrites could be the result of phyllosilicates approaching equilibrium solubility of atmospheric Ar-40.

Zaikowski, A.↗
NASA NTRS1979

Consortium breccia 73255 - Laser /Ar-39/-/Ar-40/ dating of aphanite samples

Laser (Ar-39)-(Ar-40) studies of clasts and groundmass in breccia 73255 are presented. They show a variety of ages indicating that some materials lost argon from sites that outgas at low temperature, while other materials have retained argon generated before the breccia-forming event. The estimate for the time of the breccia-forming event from thermal release studies is compared to the upper limit of the event from the laser studies; this work also shows that ages in excess of 4.0 G.y. determined on rocks containing devitrified maskelynite clasts probably have no chronological significance.

Eichhorn, G.↗
NASA NTRS1978

Meteoritic evidence for the Maunder minimum in solar activity

Concentrations of argon-39 produced by cosmic rays in the metal in 30 meteorites are remarkably similar, but they are slightly higher than expected for the present solar-cycle-averaged flux of cosmic rays. This supports the idea suggested by Eddy (1976) that there were prolonged minima in solar activity before 1715 which caused the deVries maximum in carbon-14 in earth's atmosphere by reducing the amount of cosmic-ray modulation in interplanetary space. The observations are easily consistent with 180 years of 'sunspot minimum' modulation during the Maunder and Spoerer minima, and possibly with virtually no solar modulation at all during that time. This would indicate that the solar wind then contained very little magnetic turbulence or whatever it is in the solar wind that causes the modulation of galactic cosmic rays.

Forman, M. A.↗
NASA NTRS1978

Feldspathic granulite 79215 - Limitations on T-fo2 conditions and time of metamorphism

Feldspathic granulite 79215, an annealed polymict breccia which has a bulk composition between anorthositic gabbro and gabbroic anorthosite, contains numerous oxide complexes in the matrix. An Ar-39-Ar-40 stepwise heating experiment gives a well-defined plateau corresponding to an age of 4.03 + or - 0.02 AE. The polmict character of this breccia and the variability of the complexes suggest that they formed as a consequence of reactions between spinel-rich clasts and matrix under the high-T low-P conditions of an ejecta blanket. The duration of annealing is estimated to have been less than 10 million yr; the absence of a KREEP component may indicate an inhomogeneous distribution of this component at the lunar surface at 4.0 AE.

Mcgee, J. J.↗
NASA NTRS1978

Laser /39/Ar-/40/Ar dating of two clasts from consortium breccia 73215

A laser Ar-39-Ar-40 study of the components of an ANT-suite anorthositic gabbro and a black aphanite from a consortium breccia is reported. A wide range of K-Ar ages is found for the plagioclase in the anorthositic gabbro; at the centers of the largest grains is material showing the greatest age (older than 4.11 billion years) while the youngest material (3.81-3.88 billion years) is found near the grain margins. Partial outgassing of the clasts upon incorporation into the breccia could account for the age patterns. The black aphanite clast appears to be cogenetic with the aphanite that forms the breccia matrix. The time of crystallization of a lunar granite has also been measured by the laser technique.

Eichhorn, G.↗
NASA NTRS1978

Ar-39-Ar-40 and petrologic study of Luna 24 samples 24077,13 and 24077,63

The ferrogabbro 24077,13, with pyroxene and plagioclase major and minor element chemical ranges comparable to the dominant ferrogabbro component in the Luna 24 core, has a Ar-39-Ar-40 temperature release age of 3.33 plus or minus 0.21 billion years. The metaferrobasalt 24077,63 is very fine-grained with a texture and mineralogy consistent with contact metamorphism between superimposed basalt flows or within a single flow. The Ar-39-Ar-40 plateau age of 24077,63 is 3.26 plus or minus 0.4 billion years. The basalt flows in Mare Crisium are about the same age as those of Mare Imbrium and younger than those of Mare Tranquillitatis and Mare Serenitatis.

Schaeffer, O. A.↗
NASA NTRS1977

Laser Ar-39-Ar-40 study of Apollo 17 basalts

Three Apollo 17 basalts were studied by the laser Ar-39-Ar-40 method. The 70215 basalt has a normal well-behaved Ar-39-Ar-40 release pattern; the 70017 basalt has a disturbed release pattern which indicates a limited intermediate maximum age followed by a broad low-age region; and the 75035 basalt has a pattern initially similar to 70017 that is followed by a high-temperature maximum age. The laser study shows that all mineral systems in 70215 have small and uniform temperature losses, while the laser-determined ages for 70017 and 75035 are, apparently, primarily controlled by the minerals containing mesostasis inclusions. It is possible that the drop in ages observed by the conventional Ar-39-Ar-40 method was due not only to recoil of Ar-39 during neutron irradiation but also to gas loss from some minerals. It is suggested that the plagioclases are the best minerals to use for a reliable age.

Schaeffer, O. A.↗
NASA NTRS1977

/Ar-39/-/Ar-40/ ages of lunar rocks

The (Ar-39)-(Ar-40) ages for 21 lunar samples from Apollo 14, 15, 16, and 17 are presented. The cosmic-ray exposure ages, Ca, and K contents are also measured. Mare basalt 15075, a slowly cooled pyroxene-phyric basalt, has a (Ar-39)-(Ar-40) plateau age of 3.45 + or - 0.2 billion years. This is one of the oldest mare basalts found at Apollo 15. 65777, a recrystallized noritic breccia, has a plateau age of 3.72 + or - 0.02 billion years, relatively young for a highland rock. This rock is probably related to a cratering event over 200 m.y. post Imbrium. Similarly breccia 68516 was formed 150 m.y. post Imbrium. Histograms for the (Ar-39)-(Ar-40) plateau ages strongly suggest that the peak in ages at Apollo 14, 16, and 17 of about 4 billion years is caused by the dominance of Imbrium ejecta at these landing sites.

Schaeffer, G. A.↗
NASA NTRS1977

Laser probe /Ar-39/-/Ar-40/ dating of materials from consortium breccia 73215

The unique capacity of the laser-probe (Ar-39)-(Ar-40) method to determine ages of constituents in a rock sample which are only of the order of 100 microns apart has been applied to measure ages of the different constituents of consortium breccia 73215. Evidence is given that the age of the melt-derived ground mass, 4.01 + or - 0.05 billion years, has no chronological significance. Instead, the best estimate for the age of the breccia-forming event, about 3.90 billion years, comes from the study of two clasts only a few hundred micrometers in size. The interpretation of this age as the age of the breccia-forming event is also supported by the studies of other consortium members and suggests a reinterpretation of the ages of most of the other Apollo 17 highland breccias.

Mueller, H. W.↗
NASA NTRS1976

The duration of volcanism in Mare Serenitatis

The crystallization ages of a suite of Apollo 17 basalts from four different stations have been measured using the Ar-39 to Ar-40 stepwise heating technique. The rocks analyzed include all principal petrographic types found at Apollo 17 landing site. A correlation between the ages and the petrographic type exists; plagioclase-poikilitic ilmenite basalts are youngest and olivine porphyritic ilmenite basalts are the oldest. The duration of volcanism in Mare Serenitatis is about 200 million years, the same as observed for Mare Imbrium, and less than observed for Mare Tranquillitatis, 400 million years. A relationship between duration of volcanism and gravity anomalies is noted. The cosmic ray exposure ages (in millions of years) for various locations range as: station 4, 58-315; station 5, 85-440; station 6, 110; station 8, 90-160.

Schaeffer, O. A.↗
NASA NTRS1976

Ages of highland rocks - The chronology of lunar basin formation revisited

The Ar-39-Ar-40 age studies are presented for thirteen Apollo 16 and 17 highland rocks. The plateau ages range from 3.63 to 4.23 G.y. for ten of the samples which give plateaus. For three of the samples, a Ar-39-Ar-40 age is not obtainable because there is no plateau in the temperature release patterns. The ages of all Ar-39-Ar-40 lunar highland rocks are summarized in histograms for Apollo 16 and 17. The histograms show a preponderance of ages in the 3.95 plus or minus 0.05 G.y. interval with a fair number of ages well in excess of 4.0 G.y. up to 4.3 G.y. The ages of the highland rocks indicate a more or less continuous bombardment of the lunar surface during the first 600 m.y. with the major ring basins being formed randomly during this period and not all in a relatively short interval at 3.9-4.0 G.y. ago.

Schaeffer, O. A.↗
NASA NTRS1975

Lunar evolution - The first 600 million years

From a stepwise-heating experiment on neutron-irradiated samples of whole rock and a plagioclase separate, an Ar-40/Ar-39 age of 4.26 plus or minus 0.02 G.y. was determined for the Apollo 17 troctolite 76535. This rock is believed to have formed as a result of very slow cooling at a depth of 10 to 40 km, and hence furnishes direct evidence that the moon was chemically zoned before 4.26 G.y. The age of the rock is associated with the Serenitatis Basin forming event. The formation of the Serenitatis Basin is then deduced to have occurred 4.26 plus or minus 0.02 G.y. ago, about 300 m.y. before the Imbrium event. It appears that the major basin forming era on the near side of the moon lasted longer than 300 m.y. The grouping of many lunar rock ages at 3.9 to 4.0 G.y. is most likely due to the fact that the Imbrium ejecta predominates all highland landing sites.

Husain, L.↗
NASA NTRS1974

Chronology of lunar basin formation

The lunar anorthositic rocks 60025,86 and 60015,22 give Ar-40/Ar-39 ages of about 4.19 and 3.50 b.y., respectively. Two coarse fine anorthositic rock fragments 78503,7,1 and 72503,8,12 have ages of 4.13 and 3.96 b.y., respectively. The rock 60025 is the first large lunar rock with an age well in excess of 4.0 b.y. Evidence for the conclusion that the cratering events reset the radiometric ages is discussed. The chronology of the lunar basin forming events is deduced from the ages of the lunar highland impact breccias. Using the ages of lunar breccias, we have deduced a chronology for the last five lunar basin forming events. It is concluded that the 'lunar cataclysm' is the Imbrium event.

Schaeffer, O. A.↗