Redox-driven mineral and organic associations in Jezero Crater, Mars
Not provided.
Engineering topics
Publications and source records attributed to Schmidt, M..
Not provided.
Understanding the impact of actinide nanoparticle (NP) formation is important to assess radionuclide mobility in the environment. We combined surface X-ray diffraction (SXRD) and in situ AFM to investigate the previously reported unusual electrolyte effects on Th uptake on mica. At low [Th] (0.1 mM), interfacial structures show a broad Th electron density (~50 Å). A linear decrease of Th uptake with decreasing hydration enthalpy of the electrolyte cation (Li+, K+, NH4+, and Cs+) indicates a competitive effect between Th and the electrolyte cation. Na+ is a clear outlier from this trend. In situ AFM imaging confirms the results. Particles show a vertical size of ~1–2 nm and larger lateral dimensions of ~10–20 nm, which is typical for particles formed at interfaces (heterogeneous nucleation). At high [Th] = 1 and 3 mM, all investigated electrolytes (ACl, A = Li+, Na+, K+) show similar Th uptake, indicating a much smaller impact of electrolyte composition. The interfacial structures are dominated by a high Th loading at a distinct distance (~6.5 Å) from the surface. Therefore, the main retention mechanism at high [Th] is suggested to be the sorption of Th NPs aggregated from Th oligomers present in solution (homogeneous nucleation).
Surface Fermi arcs (SFAs), the unique open Fermi-surfaces (FSs) discovered recently in topological Weyl semimetals (TWSs), are unlike closed FSs in conventional materials and can give rise to many exotic phenomena, such as anomalous SFA-mediated quantum oscillations, chiral magnetic effects, three-dimensional quantum Hall effect, non-local voltage generation and anomalous electromagnetic wave transmission. Here, by using in-situ surface decoration, we demonstrate successful manipulation of the shape, size and even the connections of SFAs in a model TWS, NbAs, and observe their evolution that leads to an unusual topological Lifshitz transition not caused by the change of the carrier concentration. The phase transition teleports the SFAs between different parts of the surface Brillouin zone. Despite the dramatic surface evolution, the existence of SFAs is robust and each SFA remains tied to a pair of Weyl points of opposite chirality, as dictated by the bulk topology.
Direct reaction experiments exhibit a powerful tool to probe the structure of neutron-rich nuclei like beryllium-11. We use halo effective field theory to calculate the cross section of the deuteron-induced neutron transfer reaction 10 Be(d, p) 11 Be. The effective theory contains dynamical fields for the beryllium-10 core, the neutron, and the proton. In contrast, the deuteron and the beryllium-11 halo nucleus are generated dynamically from contact interactions using experimental and ab initio input. Breakup contributions are then included by construction. The reaction amplitude is constructed up to next-to-leading order in an expansion in the ratio of the length scales characterizing the core and the halo. The Coulomb repulsion between core and proton is treated perturbatively. Lastly, we compare our results to cross-section data and other calculations.
We introduce results from the Wendelstein Weak Lensing (WWL) pathfinder project, in which we have observed three intermediate-redshift Planck clusters of galaxies with the new 30 arcmin × 30 arcmin wide field imager at the 2 m Fraunhofer Telescope at Wendelstein Observatory. We investigate the presence of biases in our shear catalogues and estimate their impact on our weak lensing mass estimates. The overall calibration uncertainty depends on the cluster redshift and is below 8.1–16 per cent for z ≈ 0.27–0.77. It will decrease with improvements on the background sample selection and the multiplicative shear bias calibration. This work shows the first weak lensing mass estimates for PSZ1 G109.88+27.94 and PSZ1 G139.61+24.20, two Sunyaev-Zeldovich (SZ)-selected cluster candidates. Based on Wendelstein colours and SDSS (Sloan Digital Sky Survey) photometry, we find that the redshift of PSZ1 G109.88+27.94 has to be corrected to z ≈ 0.77. We investigate the influence of line-of-sight structures on the weak lensing mass estimates and find upper limits for two groups in each of the fields of PSZ1 G109.88+27.94 and PSZ1 G186.98+38.66. We compare our results to SZ and dynamical mass estimates from the literature, and in the case of PSZ1 G186.98+38.66 to previous weak lensing mass estimates. We conclude that our pathfinder project demonstrates that weak lensing cluster masses can be accurately measured with the 2 m Fraunhofer Telescope.
MSL Curiosity investigated the Windjana sandstone outcrop, in the Kimberley area of Gale Crater, and obtained mineralogical analyses with the CheMin XRD instrument. Windjana is remarkable in containing an abundance of potassium feldspar (and thus K in its bulk chemistry) combined with a low abundance of plagioclase (and low Na/K in its chemistry). The source of this enrichment in K is not clear, but has significant implications for the geology of Gale Crater and of Mars. The high K could be intrinsic to the sediment and imply that the sediment source area (Gale Crater rim) includes K-rich basalts and possibly more evolved rocks derived from alkaline magmas. Alternatively, the high K could be diagenetic and imply that the Gale Crater sediments were altered by K-rich aqueous fluids after deposition.
A significant portion of the soil of the Rocknest dune is crystalline and is consistent with derivation from unweathered basalt. Minerals and their compositions are identified by X-ray diffraction (XRD) data from the CheMin instrument on MSL Curiosity. Basalt minerals in the soil include plagioclase, olivine, low- and high-calcium pyroxenes, magnetite, ilmenite, and quartz. The only minerals unlikely to have formed in an unaltered basalt are hematite and anhydrite. The mineral proportions and compositions of the Rocknest soil are nearly identical to those of the Adirondack-class basalts of Gusev Crater, Mars, inferred from their bulk composition as analyzed by the MER Spirit rover.
The primary MER objectives have been successfully completed. The total integration time of all MB measurements exceeds the duration of the primary 90-sols-mission for Spirit's MB spectrometer, and approaches this value for Opportunity's MB spectrometer. Both MB spectrometers continue to accumulate valuable scientific data after three years of operation (data is available for download [13]) The identification of aqueous minerals such as goethite in Gusev crater and jarosite at Meridiani Planum by the MER Mossbauer spectrometers is strong evidence for past water activity at the two landing sites.
Home Plate is a layered plateau in Gusev crater on Mars. It is composed of clastic rocks of moderately altered alkali basalt composition, enriched in some highly volatile elements. A coarse-grained lower unit is overlain by a finer-grained upper unit. Textural observations indicate that the lower strata were emplaced in an explosive event, and geochemical considerations favor an explosive volcanic origin over an impact origin. The lower unit likely represents accumulation of pyroclastic materials, while the upper unit may represent eolian reworking of the same pyroclastic materials.
The meteorites Dho 225 and Dho 735 were recently found in Oman. Studies of their mineralogical and chemical composition suggest that these unusual meteorites are thermally metamorphosed CM2 chondrites [1,2,3]. Similar to Antarctic metamorphosed carbonaceous chondrites, the Dho 225 and Dho 735 are enriched in heavy oxygen compared to normal CMs [1,2]. However, IR studies indicating dehydration of matrix phyllosilicates are needed to confirm that the two new meteorites from Oman are thermally metamorphosed [4]. Synchrotron-based IR microspectroscopy is a new promising technique which allows the acquisition of IR spectra from extremely small samples. Here we demonstrate that this non-destructive technique is a useful tool to study hydration states of carbonaceous chondrites in situ. In addition, we acquired reflectance spectra of bulk powders of the Dho 225 and Dho 735 in the range of 0.3-50 microns.
In this paper we review the IGS network as it currently exists and its effectiveness in supporting the IGS suite of precise products.
The ROSAT Deep Survey includes a complete sample of 50 X-ray sources with fluxes in the 0.5 - 2 keV band larger than 5.5 x 10(exp -15)erg/sq cm/s in the Lockman field (Hasinger et al., Paper 1). We have obtained deep broad-band CCD images of the field and spectra of many optical objects near the positions of the X-ray sources. We define systematically the process leading to the optical identifications of the X-ray sources. For this purpose, we introduce five identification (ID) classes that characterize the process in each case. Among the 50 X-ray sources, we identify 39 AGNs, 3 groups of galaxies, 1 galaxy and 3 galactic stars. Four X-ray sources remain unidentified so far; two of these objects may have an unusually large ratio of X-ray to optical flux.
To bring together NASA's scientists and engineers and their counterparts in industry, other government agencies, and academia working in the Computational AeroSciences (CAS) field. This workshop is part of the technology transfer plan of the High Performance Computing and Communications Program (HPCCP). Specific objectives of this Workshop are to: (1) communicate the goals and objectives of HPCCP in the area of CAS; (2) promote and disseminate CAS technology within the appropriate technical communities, including NASA, industry, academia, and other government labs; (3) help promote synergy among CAS scientists; and (4) permit feedback from peer researchers in issues pacing the CAS field in general and the HPCCP CAS program in particular.
This paper presents the status of the long-term experiment using a hybrid GPS/acoustic system to determine strain rates across the Cascadia subduction zone.
The longest pointed observation (152 ksec) with the Rosat position sensitive proportional counter in the direction of the absolutely lowest neutral hydrogen column density is discussed. 26 shallower fields from the Rosat medium sensivity survey are analyzed. 1176 X-ray sources were detected in at least one Rosat energy band in these fields covering a total solid angle of 9.3 deg; 661 of these sources constitute a statistically complete sample detected in the hard band with 0.5 to 2 keV fluxes greater than 2.5 times 10 to the power of minus 15 erg/sq cm s. The faintest limiting flux of the survey is analyzed. Detailed simulations show that confusion effects and other selection biases are relatively small and can be corrected for in the sample. From an analysis in the Lockman field, a best fit slope of approximately 1.8 is found for the extrapolation of the differential X-ray counts below 2.5 times 10 to the power of minus 15 erg/sq cm s. On the basis of this analysis an upper limit of approximately 25% can be found for a truly diffuse background component in the Rosat hard band.
We report preliminary results from a program to identify optical counterparts of ROSAT sources in the North Ecliptic Pole (NEP) region. The most striking X-ray feature reported by Hasinger et al. (1991) is an extended low surface brightness region of X-ray emission. Within the two X-ray contours of highest count rate we find a cluster of galaxies at a redshift of 0.09 and an early-type galaxy at a redshift of 0.03. X-ray emission from these objects may provide an explanation for the observed X-ray morphology. We also find evidence that other X-ray sources in this region are coincident with clusters or groups of galaxies at redshifts between 0.08 and 0.09. The presence of at least five X-ray detected clusters or groups in this narrow redshift band within a 1.5 deg radius field seems to indicate the existence of a moderate redshift supercluster. The existence of these clusters will have major implications for the study of large-scale structure through X-ray surveys such as ROSAT.
Images of the gravitational lens 2237+0305 acquired in good seeing have resolved the system into at least five components within the central few arsec of the object: the galaxy nucleus and four point sources in a ringlike formation approximately centered on the galaxy. It is found that the four point sources are distinctly bluer than the galaxy, but that they do not have identical colors. The observed configuration is well reproduced by a simple model that assumes that the four objects are images of the quasar and that the lens is a constant mass-to-light ratio, elliptical, de Vaucouleurs bulge.
This paper presents optical photometry and spectroscopy of SN 1987D, a Type Ia supernova in the nearby galaxy UGC 7370, during the period immediately subsequent to its discovery. The distance modulus of the galaxy, independently determined by the redshift and the Tully-Fisher (1977) relation, is 32.3 + or - 1.0. The maximum brightness of SN 1987D was V about 13.2 and occurred on April 18, 1987, + or - 4 days; the absolute luminosity is about 0.6 mag brighter than the average for SNe Ia. The spectrum of SN 1987D is typical of SNe Ia, but the expansion velocity (9600 km/s) is considerably lower than average.