Engineering topics

Schmitt, Bernard

Publications and source records attributed to Schmitt, Bernard.

6 records

NASA NTRS1999

Water Ice on Triton

We report the spectroscopic detection of H2O ice on Triton, evidenced by the broad absorptions in the near infrared at 1.55 and 2.04 micron. The detection on Triton confirms earlier preliminary studies (D. P. Cruikshank, R. H. Brown, and R. N. Clark, Icarus 58, 293-305, 1984). The spectra support the contention that H2O ice on Triton is in a crystalline (cubic or hexagonal) phase. Our spectra (1.87-2.5 micron) taken over an interval of nearly 3.5 years do not show any significant changes that might relate to reports of changes in Triton's spectral reflectance (B. Buratti, M. D. Hicks, and R. L. Newburn, Jr., Nature 397, 219, 1999), or in Triton's volatile inventory (J. L. Elliot et al., Nature 393, 765-767, 1998).

Cruikshank, Dale P.↗

NASA NTRS1993

Ices on the surface of Triton

The near-infrared spectrum of Triton reveals ices of nitrogen, methane, carbon monoxide, and carbon dioxide, of which nitrogen is the dominant component. Carbon dioxide ice may be spatially segregated from the other more volatile ices, covering about 10 percent of Triton's surface. The absence of ices of other hydrocarbons and nitriles challenges existing models of methane and nitrogen photochemistry on Triton.

Cruikshank, Dale P.↗

NASA NTRS1993

Surface ices and the atmospheric composition of Pluto

Observations of the 1.4- to 2.4-micrometer spectrum of Pluto reveal absorptions of carbon monoxide and nitrogen ices and confirm the presence of solid methane. Frozen nitrogen is more abundant than the other two ices by a factor of about 50; gaseous nitrogen must therefore be the major atmospheric constituent. The absence of carbon dioxide absorptions is one of several differences between the spectra of Pluto and Triton in this region. Both worlds carry information about the composition of the solar nebula and the processes by which icy planetesimals formed.

Owen, Tobias C.↗

NASA NTRS1989

New insights in the photochemistry of grain mantles: The identification of the 4.62 and 6.87 micron bands

The mid-IR spectral region of molecular clouds is known to show the fingerprints of molecules frozen in the icy mantles of the interstellar grains. To study the complex chemical and physical interactions on the ice mantles accreted on grains in molecular clouds numerous UV irradiation and diffusion experiments were performed. The irradiation of binary ices was studied. Using isotopic labelling on NH3/CO and NH3/O2 ices numerous compounds were identified, of which OCN(-), NO2(-), NO3(-), and NH4(+) ions reveal a new type of chemical reactions. It appeared that these compounds were formed by proton transfer reactions induced by the interaction between an acid (HNCO, HNO2, HNO3) and a base (NH3) through a hydrogen bond. This mechanism was confirmed by a study of photolyzed diluted argon mixtures. The main astrophysically relevant data from the overall study are presented. The 4.62 micron band in W33A can be reproduced with NH3/CO containing irradiated ices and was identified with OCN(-). The 6.87 micron band in W33A and other photostellar objects is reproduced with NH3/O2 containing ices and is identified with NH4(+).

Grim, Ruud↗

NASA NTRS1989

Diffusion and infrared properties of molecules in ice mantles

Within dense molecular clouds the formation of frozen icy mantles on interstellar dust grains is thought to be the result of various growth conditions. The molecules, which make up the ice mantles are probably completely mixed. To study the physical properties of such ice mixtures the experiments were performed on the evaporation processes and on the spectroscopic properties of CO, CO2, and CH4 in water rich ices. The decrease in concentration of volatile molecules in ice samples deposited at 10 K and subsequently heated is found to occur essentially in two steps. The first one, corresponding to an evaporation of part of the volatile molecules, starts at about 25 K for CO, 32 K for CH4, and 70 K for CO2. During the crystallization of H2O ice at temperatures greater than 120 K a second evaporation occurs leading to the complete disappearance of the volatile molecules in the solid phase. The main astrophysical implications of the diffusion and spectroscopic behaviors are presented. The possible effects of a heating source on the fraction of volatile molecules, such as CO trapped in grain mantles, are discussed.

Schmitt, Bernard↗

NASA NTRS1989

Ions in grain mantles - A new explanation for the 6.86 micron absorption in W33A

The 6.86-micron absorption in W33A has been investigated using the results of laboratory experiments simulating the photochemistry of interstellar grain mantles. The 5-8-micron IR spectrum, and particularly the 6.86-micron absorption, of W33A can be reproduced with ultraviolet irradiated water-rich ices. The 5-8-micron spectrum of W33A exhibits effects which are interpreted as due to dust material heated to different temperatures along the line of sight. Photolyzed dust mantles with a temperature less than 100 K provide the 6.0-micron absorption, while dust mantles heated to more than 100 K are the main contributors to the 6.86-micron absorption feature. Different photolysis and heating scenarios, as well as line of sight effects, are required to account for the 5-8-micron spectra of other protostellar objects.

Grim, Ruud J. A.↗