Falsifiability Test for Classical Nucleation Theory
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Beneduce, Camilla (ORCID:0000000171472062)↗
Engineering topics
Sciortino, Francesco
Publications and source records attributed to Sciortino, Francesco.
Inverse design of a pyrochlore lattice of DNA origami through model-driven experiments
Sophisticated statistical mechanics approaches and human intuition have demonstrated the possibility of self-assembling complex lattices or finite-size constructs. However, attempts so far have mostly only been successful in silico and often fail in experiment because of unpredicted traps associated with kinetic slowing down (gelation, glass transition) and competing ordered structures. Theoretical predictions also face the difficulty of encoding the desired interparticle interaction potential with the experimentally available nano- and micrometer-sized particles. To overcome these issues, we combine SAT assembly (a patchy-particle interaction design algorithm based on constrained optimization) with coarse-grained simulations of DNA nanotechnology to experimentally realize trap-free self-assembly pathways. In this paper, we use this approach to assemble a pyrochlore three-dimensional lattice, coveted for its promise in the construction of optical metamaterials, and characterize it with small-angle x-ray scattering and scanning electron microscopy visualization.
77 NANOSCIENCE AND NANOTECHNOLOGY↗
Soft matter roadmap
Soft materials are usually defined as materials made of mesoscopic entities, often self-organised, sensitive to thermal fluctuations and to weak perturbations. Archetypal examples are colloids, polymers, amphiphiles, liquid crystals, foams. The importance of soft materials in everyday commodity products, as well as in technological applications, is enormous, and controlling or improving their properties is the focus of many efforts. From a fundamental perspective, the possibility of manipulating soft material properties, by tuning interactions between constituents and by applying external perturbations, gives rise to an almost unlimited variety in physical properties. Together with the relative ease to observe and characterise them, this renders soft matter systems powerful model systems to investigate statistical physics phenomena, many of them relevant as well to hard condensed matter systems. Understanding the emerging properties from mesoscale constituents still poses enormous challenges, which have stimulated a wealth of new experimental approaches, including the synthesis of new systems with, e.g. tailored self-assembling properties, or novel experimental techniques in imaging, scattering or rheology. Theoretical and numerical methods, and coarse-grained models, have become central to predict physical properties of soft materials, while computational approaches that also use machine learning tools are playing a progressively major role in many investigations. This Roadmap intends to give a broad overview of recent and possible future activities in the field of soft materials, with experts covering various developments and challenges in material synthesis and characterisation, instrumental, simulation and theoretical methods as well as general concepts.
36 MATERIALS SCIENCE↗
Experimental inference of neutral and impurity transport in Alcator C-Mod using high-resolution x-ray and ultra-violet spectra
We present experimental inferences of cross-field impurity transport coefficients for AlcatorC-Mod plasmas without edge-localized modes, leveraging a novel forward model for the entire Ca Kα spectrum, including satellite lines within the spectral range, to compare to high-resolution x-ray imaging crystal spectroscopy (XICS). These measurements are complemented by extreme ultra-violet (EUV) spectroscopy that constrains transport closer to the edge. Using new atomic data sets for both XICS and EUV analysis has enabled consideration of line ratios across both spectral ranges and has increased the accuracy of inferred transport coefficients. Inclusion of charge exchange between edge thermal neutrals and impurities is shown to be extremely important in C-Mod pedestals. Atomic D neutral densities from experimental D Lyα measurements at the midplane are compared to SOLPS-ITER simulations, finding good agreement. Bayesian inferences of impurity transport coefficients are presented for L-, EDA H-, and I-mode discharges, making use of the Aurora package for forward modeling and combining our spectroscopic constraints. Experimentally inferred diffusion profiles are found to match turbulent transport models at midradius within uncertainties, using both quasilinear gyro-fluid TGLF SAT-1 and nonlinear ion-scale gyrokinetic CGYRO simulations. Furthermore, significant discrepancies in convection are observed in some cases, suggesting difficulties in predictions of flat or hollow impurity profiles.
neutrals↗
Diverted Negative Triangularity plasmas on DIII–D: The benefit of high confinement without the liability of an edge pedestal
Diverted discharges at negative triangularity on the DIII-D tokamak sustain normalized confinement and pressure levels typical of standard H-mode scenarios (H 98y,2 ≅1, β N ≅3) without developing an edge pressure pedestal, despite the auxiliary power far exceeding the L → H power threshold expected from conventional scaling laws. The power degradation of confinement is substantially weaker than the ITER-89P scaling, resulting in a confinement factor that improves with increasing auxiliary power. Furthermore, the absence of the edge pedestal is beneficial in several aspects, such as eliminating the need for active mitigation or suppression of edge localized modes, low impurity retention and a reconstructed scrape-off layer heat flux width at the mid-plane that exceeds the ITPA multi-machine scaling law by up to 50%. Together with technological advantages granted by placing the divertor at larger radii, plasmas at Negative Triangularity without an edge pedestal feature both core confinement and power handling characteristics that are potentially suitable for operation in future fusion reactors.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Combinatorial-Entropy-Driven Aggregation in DNA-Grafted Nanoparticles
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99 GENERAL AND MISCELLANEOUS↗
Design study of a combined interferometer and polarimeter for a high-field, compact tokamak
This article is the first design study of a combined interferometer and polarimeter on a compact, high-field, high-density, net-energy tokamak. Recent advances in superconducting technology have made possible designs for compact, high magnetic field fusion power plants, such as ARC [Sorbom et al., Fusion Eng. Des. 100, 378 (2015)], and experiments, such as SPARC [Greenwald et al., PSFC Report No. RR-18-2 (2018)]. These new designs create both challenges and opportunities for plasma diagnostics. The diagnostic proposed in this work, called InterPol, takes advantage of unique opportunities provided by high magnetic field and density to measure both line-averaged density and poloidal magnetic field with a single set of CO 2 and quantum cascade lasers. These measurements will be used for fast density feedback control, constraint of density and safety factor profiles, and density fluctuation measurements. Synthetic diagnostic testing using a model machine geometry, called MQ1 (Mission Q ≥ 1), and profiles simulated with Tokamak Simulation Code indicate that InterPol will be able to measure steady state density and poloidal magnetic field, as well as fluctuations caused by toroidal Alfven eigenmodes and other phenomena on a high-field compact tokamak.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Bayesian Spectral Moment Estimation and Uncertainty Quantification
We present a Bayesian spectral fitting method developed for spectroscopic data analysis, particularly (but not solely) in the context of fusion energy research. The presented techniques are particularly valuable to estimating moments and corresponding uncertainties whenever the spectra result from line-integrated measurements in nonuniform plasmas, for which the approximation of atomic line shapes being ideal Gaussians gives poor estimates. We decompose multiple, potentially overlapping spectral lines into a sum of Gauss-Hermite polynomials, whose properties allow efficient truncation and uncertainty quantification, often with only three free parameters per atomic emission line. Tests with both synthetic and experimental data demonstrate the effectiveness and robustness where more standard nonlinear fitting routines may experience difficulties. A parallelized version of our implementation is publicly released under an open source license.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗