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Seals, R. K., Jr.

Publications and source records attributed to Seals, R. K., Jr..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Upper Atmosphere Data Program (UADP)

Rapid, effective access to the increasing volume of information on stratospheric trace gases, both from measurements and model calculations, is important in advancing our knowledge of the Earth's atmosphere. The data have their origins in a variety of sources, ranging from satellite experiments and 2-D model predictions to individual balloon measurements, and are found in a variety of locations and formats. This task focuses on development and operation of an electronic data base for such trace gas data. The objectives are to provide effective access to these diverse data sets; to foster electronic data access, manipulation, and display; and to support periodic assessment and intercomparison activities.

Seals, R. K., Jr.↗
NASA NTRS1983

Stratospheric temperature profile from balloon-borne measurements of the 10.4-micron band of CO2

The technique of nonlinear least squares spectral curve fitting has been used to derive the stratospheric vertical temperature profile from balloon-borne measurements of the 10.4 micron band of CO2. The spectral data were obtained at sunset with the approximately 0.02 per cm resolution University of Denver interferometer system from a float altitude of 33.5 km near Alamogordo, New Mexico, on 23 March 1981. The r.m.s. deviation between the retrieved temperature profile and correlative radiosonde measurements is 2.2 K.

Rinsland, C. P.↗
NASA NTRS1982

Stratospheric N2O mixing ratio profile from high-resolution balloon-borne solar absorption spectra and laboratory spectra near 1880/cm

A nonlinear least-squares fitting procedure is used to derive the stratospheric N2O mixing ratio profile from balloon-borne solar absorption spectra and laboratory spectra near 1880/cm. The atmospheric spectra analyzed here were recorded during sunset from a float altitude of 33 km with the University of Denver's 0.02/cm resolution interferometer near Alamogordo, N.M. (33 deg N) on Oct. 10, 1979. The laboratory data are used to determine the N2O line intensities. The measurements suggest an N2O mixing ratio of 264 ppbv near 15 km, decreasing to 155 ppbv near 28 km.

Rinsland, C. P.↗
NASA NTRS1982

Stratospheric measurements of collision-induced absorption by molecular oxygen

High-resolution stratospheric solar absorption spectra recorded at sunset with a balloon-borne interferometer, from an altitude of 33 km, are used in a study of collision-induced absorption by the fundamental vibration-rotation band of O2, whose continuum has been identified in the 1400-1700/cm region in spectra obtained at tangent altitudes below 22 km. It is found that transmittance measurements in intervals free of atmospheric line absorption agree with values calculated with the O2 absorption coefficients of Timofeyev and Tonkov (1978), and that the measurements indicate a 20% upper limit for the uncertainty of the available O2 absorption coefficients at lower stratospheric temperatures, on the order of 220 K.

Rinsland, C. P.↗
NASA NTRS1977

Ozone monitoring with an infrared heterodyne radiometer

Measurements of the total burden and of the concentration-versus-altitude profiles of ozone have been made with a ground-based heterodyne radiometer at Pasadena, California. The measurements were made in the 9.5-micron wavelength region, where a strong ozone infrared absorption band exists. The radiometer measured solar absorption at selected wavelengths with a spectral resolution of 0.001 reciprocal centimeter, equivalent to the half-width of an ozone absorption line at the 10-millibar altitude level. A carbon dioxide laser served as the local oscillator. This technique can be used to gather important data on both tropospheric and stratospheric ozone, which are not readily accessible with other remote-sensing techniques.

Menzies, R. T.↗
NASA NTRS1976

Remote sensing of atmospheric pollutant gases using an infrared heterodyne spectrometer

Remote sensing of the concentration and vertical distribution of atmospheric gases using an infrared heterodyne spectrometer (IHS) has been investigated, and a dual (C-13)(O-16)2 laser multichannel IHS has been developed. Analyses of nadir thermal-radiance measurements from an aircraft at 10-km altitude and of solar absorption measurements from the ground indicate that initial applications of the IHS to tropospheric measurements of NH3 and O3 are feasible with measurement precisions ranging from 0.5 to 2 ppb and 20 to 30 ppb, respectively. These analyses have included effects of potential retrieval-error sources and have resulted in specifications of measurement modes, optimum signature lines, required system parameters, and expected sensitivities. Preliminary instrument performance data are presented.

Seals, R. K., Jr.↗
NASA NTRS1975

Measurements of NH3 absorption coefficients with a C-13/O-16/2 laser

Measurements of NH3 absorption coefficients are presented for several transitions of a C-13(O-16)2 laser for small concentrations of NH3(p less than 1 torr) for absorption lines broadened to 1 atm with N2. NH3 absorption coefficients were determined for laser transitions R(8)(920.2194 wavelengths/cm) to R(28)(933.8808 wavelengths/cm) of the 00 1 - (10 0,02 0)I band. The strongest absorption coefficient K = 36.09 + or - 1.43 per (atm-cm) was measured for the R(18) transition for the NH3 line, aQ(6,6), and is larger than has been found in any previous measurements with a CO2 laser. The dependence of K on total pressure was also obtained for select transitions, and the frequency separation between the R(18) laser transition and the neighboring NH3 line aQ(6,6) was determined to be 550 + or - 50 MHz. These results are significant for long path absorption monitoring of NH3 with CO2 lasers since the path length can be reduced by approximately 40% and for heterodyne detection of NH3 since the relative position of the laser transition to the NH3 absorption line is well within the bandpass of Hg-Cd-Te photomixers.

Allario, F.↗
NASA NTRS1973

Analysis of laser differential absorption remote sensing using diffuse reflection from the earth

A computer model analysis of an infrared laser differential absorption remote sensing technique (DARS) is presented. An infrared laser source operating at two or more wavelengths and a heterodyne detection system are considered to be mounted on either an aircraft or satellite platform to monitor the differential absorption between the laser source and the earth surface. The capability of this technique for measuring gas concentrations in the lower 5 kilometers of the atmosphere is emphasized. Numerical results are presented simulating measurements of vertical burdens of CO, NO, CH4, CO2, and O3. These results indicate that measurements of expected concentrations of these gases can be made with greater than 80% accuracy using realistic laser powers and system parameters.

Seals, R. K., Jr.↗
NASA NTRS1972

Atmospheric windows for HF laser radiation between 2.7 and 3.2 microns.

A high resolution computer model study of the atmospheric transmittance in the 2.7 to 3.2 micron region of the spectrum is described, whose purpose was to identify atmospheric windows for the HF laser wavelengths available in this region. Three HF lines corresponding to the transitions P(12), 1 to 0, P(6), 3 to 2, and P(4), 5 to 4 are identified as having transmittances of 0.70 or greater over a 1-km sea level path.

Seals, R. K., Jr.↗