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Shiomi, T.

Publications and source records attributed to Shiomi, T..

Controlled thermal pre-treatment of ZMG232G10® for corrosion mitigation under simulated SOFC interconnect exposure conditions

The IT-SOFC candidate interconnect material ZMG232G10® was thermally pre-treated in air and in H 2 – 3% H 2 O to mitigate dual atmosphere corrosion. Bare and pre-treated steel samples were exposed to a dual atmosphere exposure condition (dry air/metal/4% H 2 – N 2 (bal.) + 3% H 2 O) for 500h at 600°C. Corrosion products and oxide morphology developed on the air-exposed surfaces were analyzed. Pre-treatments of the metal in oxidizing (air) and reducing (H 2 – 3% H 2 O) gas atmospheres provide improved passivation against dual atmosphere corrosion compared to bare steel. Further, the uniform and iron-free oxide scale developed during the pre-treatment of alloy in the low pO 2 H 2 – 3% H 2 O gas atmosphere provides an effective diffusion barrier against the outward transport of cations and oxidation of iron observed under dual atmosphere conditions.

36 MATERIALS SCIENCE↗

Corrosion of Chromia-Forming and Alumina-Forming Ferritic Stainless Steels under Dual Atmosphere Exposure Conditions

The surface morphology and chemistry of oxide scales formed on select chromia-forming and alumina-forming ferritic steels have been studied after exposure to a dual atmosphere of hydrogen and air. Localized Fe-rich oxide nodules with surface whiskers/platelets form at the onset of corrosion. The initiation and growth of localized nodules and breakdown of passivation are attributed to the presence of hydrogen, inclusion of iron oxide in the passivating scale, and subsequent growth of iron-rich oxide due to the establishment of redox (H 2 -H 2 O) atmosphere and modification of oxide defect chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Precise interferometric tracking of the DSCS II geosynchronous orbiter

A demonstration of the precise tracking of a geosynchronous orbiter by radio metric techniques based on very-long-baseline interferometry (VLBI) has been jointly conducted by the Jet Propulsion Laboratory and Japan's Radio Research Laboratory. Simultaneous observations of a U.S. Air Force communications satellite from tracking stations in California, Australia, and Japan have determined the satellite's position with an accuracy of a few meters. Accuracy claims are based on formal statistics, which include the effects of errors in non-estimated parameters and which are supported by a chi-squared of less than one, and on the consistency of orbit solutions from disjoint data sets. A study made to assess the impact of shorter baselines and reduced data noise concludes that with a properly designed system, similar accuracy could be obtained for either a satellite viewed from stations located within the continental U.S. or for a satellite viewed from stations within Japanese territory.

Border, J. S.↗