Magnetically Doped Molybdenum Disulfide Layers for Enhanced Carbon Dioxide Capture
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Materials Science↗
Engineering topics
Shuster, Seth
Publications and source records attributed to Shuster, Seth.
Partial oxidation of methane to methanol on boron nitride at near critical acetonitrile
Abstract Direct catalytic conversion of methane to methanol with O 2 has been a fundamental challenge in unlocking abundant natural gas supplies. Metal-free methane conversion with 17% methanol yield based on the limiting reagent O 2 at 275 °C was achieved with near supercritical acetonitrile in the presence of boron nitride. Reaction temperature, catalyst loading, dwell time, methane–oxygen molar ratio, and solvent-oxygen molar ratios were identified as critical factors controlling methane activation and the methanol yield. Extension of the study to ethane (C2) showed moderate yields of methanol (3.6%) and ethanol (4.5%).
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