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Sill, G. T.

Publications and source records attributed to Sill, G. T..

Design study of an entry probe spectro-reflectometer

A wind tunnel was built to simulate the rapid movement of an entry probe through the Jupiter atmosphere. Wind speeds range from 1 to 50 meters per second in a closed system. Wind velocity and temperature probes as well as a cryogenically cooled cold finger can be placed in the 6 inch diameter viewing section. The initial testing of the wind tunnel involved running sectional profiles through the observation port of air currents of 0.1 to 3.0 atmosphere. The velocity profile was very uniform throughout the cross section of the experimental port, with the exception of the wall effects. The deposition of cooled volatiles using the wind tunnel was not performed. However, measurements of the deposition of H2O ice on a cryogenically cooled thickness modulator were made under ambient conditions, namely room temperature and pressure. In the Frost Depositon Test Facility, ice deposition was measured at thicknesses of about a half millimeter and frost was produced whose thickness reflectivity could easily be measured by reflectance spectroscopy.

Sill, G. T.↗

The clouds of Venus - Sulfuric acid by the lead chamber process

The Pioneer Venus atmospheric probe provided new data on the clouds of Venus. A model consistent with this data involves SO2 being oxidized to H2SO4 by NO(x) in the presence of H2O. NO(x) also forms nitrosylsulfuric acid (NOHSO4) dissolved in the H2SO4 droplets. This acid solution, along with SO2 and perhaps NO2, can explain the UV and visible reflection spectrum of Venus. In the middle and lower clouds, NOHSO4 forms solid particles.

Sill, G. T.↗

The infrared spectral properties of frozen volatiles

Since Whipple's dirty snowball model of comet nuclei, it has been generally accepted that volatile ices help to explain cometary phenomena. The infrared spectral properties of many substances that are potential candidates for frozen volatiles in the solar system are being pursued; indeed some of these frozen materials have been found in the solar system: H2O, CO2, and SO2. A review of laboratory spectra in the range 1 to 20 microns of H2O, CO2, SO2, CH4, NH3, H2S, CO, NH4HS and NH3.H2O is presented. Both reflection spectra of thick frosts and transmission spectra of thin films are shown, and their main characteristics are described. Hydrates, clathrates, and composite spectra are discussed. When it is possible to observe the nuclei of comets at close range, it may be possible to identify frozen volatiles by their infrared spectra.

Fink, U.↗

Composition of the surfaces of the Galilean satellites

Sulfur chemistry on Io and the surface chemistry of the icy Galilean satellites are discussed in terms of laboratory chemical findings and spectral investigations. Gaseous, liquid, and solid allotropes of sulfur are described and related to spectral data for Io. Compounds of sulfur identified on Io's surface are given and possible mechanisms for their formation are evalutated. Laboratory studies of water frost, ice, and mixtures with other minerals are discussed and their relevance in interpreting infrared spectra of the icy Galilean satellites and the apparent solid water absorption band profiles is shown.

Sill, G. T.↗

Ice clathrate as a possible source of the atmospheres of the terrestrial planets

The presence and compositions of atmospheres on the terrestrial planets do not follow directly from condensation models which would have earth accreting near 500 K. No single mechanism yet proposed adequately accounts for the abundances of noble gases and carbon and nitrogen in the atmospheres. We show that the composition of clathrates forming at low temperatures in cold regions of the nebula can be predicted. Addition of about 1 ppm clathrate material to the earth can explain observed abundances of Ar, Kr, and Xe. Condensation and adsorption processes occurring at 400-500 K are necessary to explain the observed abundances of Ne, H2O, C, and N. Possible sources of clathrates could be cometary bodies formed in the outer solar system.

Sill, G. T.↗

The composition of the ultraviolet dark markings on Venus

The ultraviolet dark clouds are an ephemeral phenomenon in the Venus atmosphere, apparently just near the limit of stability. The UV dark material is moderately abundant, perhaps 10%, since the contrasts between light and dark material are some 20%. The material should absorb light between 3000-4000 A, and ideally should also have visible absorptions in the blue, as the overall spectral albedo of Venus indicates. Such a material is bromine dissolved in hydrobromic acid. Solar radiation near 2500 A is sufficient to partially photolyze HBr into Br2. HBr in the Venus atmosphere is inferred to have a mixing ratio of 0.0001 versus CO2. With a water vapor mixing ratio of 0.001, droplets of hydrobromic acid are possible. These droplets would eventually evaporate in the drier upper atmosphere. The refractive index of these hydrobromic acid droplets of 52% (by weight) composition is 1.46, within the limits set by polarization studies of Venus.

Sill, G. T.↗

Reflection spectra of solids of planetary interest

The spectra of solids are reproduced which might be found on the surfaces of planetary bodies or as solid condensates in the upper planetary atmosphere. Among these are spectra of various iron compounds of interest in the study of the clouds of Venus. Other spectra are included of various sulfides, some at low temperature, relevant to the planet Jupiter. Meteorite and coal abstracts are also included, to illustrate dark carbon compounds.

Sill, G. T.↗

Reflection spectra of solids of planetary interest

This paper reproduces the spectra of solids which might be found on the surfaces of planetary bodies or as solid condensates in the upper planetary atmosphere. Among these are spectra of various iron compounds of interest in the study of the clouds of Venus. Other spectra (some at low temperature) are included for various sulfides relevant to the planet Jupiter. Meteorite and coal spectra are also included to illustrate dark carbon compounds.

Sill, G. T.↗

Sulfuric Acid in the Venus Clouds

The visible and ultraviolet transmission features of a thin layer of elemental bromine and hydrobromic acid dissolved in sulfuric acid somewhat resemble the Venus spectrum, up to 14 microns. The chemical process postulated for forming sulfuric acid involves the oxidation of sulfur and its compounds to sulfuric acid through the agency of elemental bromine, produced by the photolytic decomposition of hydrogen bromide.

Sill, G. T.↗

Sulfuric acid in the Venus clouds.

The extremely dry nature of the Venus upper atmosphere appears to demand the presence of an efficient desiccating agent as the chief constituent of the clouds of Venus. On the basis of polarization measures it is to be expected that this substance is present as spherical droplets, 1 to 2 microns in diameter, with a refractive index n of 1.46 plus or minus 0.02 at 3500A in the observed region of the atmosphere, with T about equal to 235 K. This substance must have ultraviolet, visible, and infrared reflection properties not inconsistent with the observed spectrum of Venus. Sulfuric acid, of about 86% by weight composition, roughly fulfills the first of these properties. The visible and ultraviolet transmission features of a thin layer of elemental bromine and hydrobromic acid dissolved in sulfuric acid somewhat resemble the Venus spectrum, up to 14 microns. The chemical process postulated for forming sulfuric acid involves the oxidation of sulfur and its compounds to sulfuric acid through the agency of elemental bromine produced by the photolytic decomposition of hydrogen bromide.

Sill, G. T.↗