Flux Synthesis of Alkaline-Earth Lanthanide Borates as Potential Nuclear Waste Forms
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Engineering topics
Publications and source records attributed to Smith, Mark.
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This document summarizes the progress of VTO Technology Integration projects supported during the fiscal year 2023. VTO's Technology Integration Program supports a broad technology portfolio that includes alternative fuels, energy efficient mobility systems and technologies, and other efficient advanced technologies that can reduce transportation energy costs for businesses and consumers. The program provides objective, unbiased data and real-world lessons learned to inform future research needs and support local decision making. It also includes projects to disseminate data, information, and insight, as well as online tools and technology assistance to cities and regions working to implement alternative fuels and energy efficient mobility technologies and systems.
For presentation at the AICHE Fall 2023 National Meeting, Orlando, FL, November 5-10, 2023.
Provided here are a final thermal conductivity test report, a drilling log, and a heat rejection log from Carbondale, CO. Also attached is a report made before drilling, which contains predictions on the hydrogeologic conditions of the drill site. The forty-eight (48.9) hour in-situ thermal conductivity test was performed on the 28th through the 30th, of November 2023. The test was performed at the borehole drilled on November 16th through the 20th, at the 3rd Street Center at 520 S. 3rd, Street in Carbondale, Colorado. Testing was done with a certified Ewbank portable test unit.
VTO's Technology Integration Program supports a broad technology portfolio that includes alternative fuels, energy efficient mobility systems and technologies, and other efficient advanced technologies that can reduce transportation energy costs for businesses and consumers. The program provides objective, unbiased data and real-world lessons learned to inform future research needs and support local decision making. It also includes projects to disseminate data, information, and insight, as well as online tools and technology assistance to cities and regions working to implement alternative fuels and energy efficient mobility technologies and systems.
For presentation at the International Microwave Power Institute Annual Symposium, Denver, CO, June 27-30, 2023.
Presentation at the International Microwave Power Institute Annual Symposium, Denver, CO, June 27-30, 2023.
Causal discovery algorithms construct hypothesized causal graphs that depict causal dependencies among variables in observational data. While powerful, the accuracy of these algorithms is highly sensitive to the underlying dynamics of the system in ways that have not been fully characterized in the literature. In this report, we benchmark the PCMCI causal discovery algorithm in its application to gridded spatiotemporal systems. Effectively computing grid-level causal graphs on large grids will enable analysis of the causal impacts of transient and mobile spatial phenomena in large systems, such as the Earth’s climate. We evaluate the performance of PCMCI with a set of structural causal models, using simulated spatial vector autoregressive processes in one- and two-dimensions. We develop computational and analytical tools for characterizing these processes and their associated causal graphs. Our findings suggest that direct application of PCMCI is not suitable for the analysis of dynamical spatiotemporal gridded systems, such as climatological data, without significant preprocessing and downscaling of the data. PCMCI requires unrealistic sample sizes to achieve acceptable performance on even modestly sized problems and suffers from a notable curse of dimensionality. This work suggests that, even under generous structural assumptions, significant additional algorithmic improvements are needed before causal discovery algorithms can be reliably applied to grid-level outputs of earth system models.
Co-gasification of waste plastic and corn stover into hydrogen is an effective way of reducing hydrogen cost and carbon footprint. However, current gasification technologies are energy intensive and cannot accommodate flexible feedstock. Microwave gasification offers several advantages including higher H 2 yield and enhanced selectivity to syngas over tars. Herein this work presents parametric optimization study of microwave co-gasification of mixed plastics and corn stover for hydrogen-rich syngas. High hydrogen yields of 30.5 mmol H2 /g feed at 700 °C were obtained using a microwave reactor, as opposed to 0.9 mmolH 2 /g feed at 700-950 °C with conventional heating. Hydrogen yields are >98% of the theoretical extractable hydrogen from feedstock. Microwaves enhanced plastic and corn stover synergy and reduced tar yields. H-poor carbon formation resulting from the dehydrogenation of tar and coke, and light olefins decomposition, triggered by the external microwave electric fields, allowed further cracking of intermediate hydrocarbons to produce additional H 2 .
Here, recent progress in the design and manufacturing development of in-vessel diagnostic components by the U.S. ITER team is reported. Design and manufacturing choices are driven by engineering challenges stemming from ITER’s burning plasma mission, which entails levels of plasma neutron emission, pulse lengths, and size scales well beyond the existing database. Challenges include port access limitations, neutron irradiation and activation risks, nuclear heating of components, complex interfaces, remote handling compatibility, and constraints on component and processing materials. Responses to these challenges are presented using examples from the low field side reflectometer, toroidal interferometer polarimeter, and electron cyclotron emission diagnostics. Relevance of the experience from ITER diagnostics engineering to the design of future integrated fusion facilities based on burning plasmas is addressed.
VTO's Technology Integration Program supports a broad technology portfolio that includes alternative fuels, energy efficient mobility systems and technologies, and other efficient advanced technologies that can reduce transportation energy costs for businesses and consumers. The program provides objective, unbiased data and real-world lessons learned to inform future research needs and support local decision making. It also includes projects to disseminate data, information, and insight, as well as online tools and technology assistance to cities and regions working to implement alternative fuels and energy efficient mobility technologies and systems.
56th Annual Microwave Power Symposium (IMPI 56), Savannah, GA, June 14-16, 2022
A keynote presentation delivered at 26th Canadian Catalysis Symposium virtually on microwave work at NETL.
The vacuum in the National Spherical Torus Experiment Upgrade (NSTX-U) is in the range of 2.66x10⁻⁶ Pa (2x 10⁻⁸ torr). To enhance vacuum seals and lower gas permeation in the NSTX-U and therefore ensuring operation safety and quality, the machine core vacuum seal design has been upgraded using double elastomeric seals and pumped interspaces (guard channels). In NSTX-U machine core, there are six major vacuum seals, including upper and lower vacuum vessel main flanges, upper and lower bellows flanges, and two in the ceramic isolation ring assembly that are mounted to the upper vacuum vessel main flange. The elastomeric seals are commercially available and customized fluorocarbon (Viton) O-rings. To ensure appropriate O-ring compression ratios for the vacuum seal, the O-ring grooves are customized with appropriate tolerances considering specific situations for each seal. In this upgrade, the vacuum in each interspace is designed to reach 13.33 Pa (0.1 torr), thus the overall pressure difference crossing each double O-ring seal is expected to be reduced by at least three orders of magnitude, and accordingly the overall rates of leakage and permeation will be lowered by three orders of magnitude. The corresponding pump-down times for each seal, at room temperature, are estimated at about 60 s. Additionally, the vacuum pumped interspaces will be able to function as a real-time leak monitor.
Here, effects of gasifier conditions (microwave or conventional) on the gasification characteristics of four different types of coal are evaluated by analysis of gaseous species generated during pyrolysis and gasification reactions. Four different coal samples are tested: a lignite (Mississippi), a low-ash subbituminous (Wyodak), a high-ash subbituminous (Usibelli), and a low volatile bituminous (Pocahontas #3). Gas composition, overall yields, carbon conversion efficiency, and cold gas efficiency are evaluated to compare gasification reactivity of the different coal types under microwave and conventional heating. During microwave pyrolysis (Ar atmosphere), greater selectivity of syngas species (H2 + CO) and greater overall non-condensable gas yields are observed, compared to conventional pyrolysis for all coals tested. The high yield of syngas during microwave pyrolysis is attributed to primary pyrolysis gases subsequently gasifying the char of the same sample to produce greater amounts of H2 and CO. During microwave gasification (CO2 atmosphere), selective heating and formation of hotspots within the coal enable the reverse Boudouard reaction to occur at a low bulk gasification temperature of 700 °C, which is less favorable under thermal gasification at this temperature. Yields of syngas are much higher under microwave gasification of all coals. Carbon conversion is found to have a linear correlation with volatile matter of the parent coal. Carbon conversion and cold gas efficiency are highest for coals gasified under microwave irradiation, and gasification reactivity of the four coals was determined to be dependent on the coal type.
Conference Research Paper Presentation
38th Annual International Pittsburgh Coal Conference, Virtual, September 20-23, 2021