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Snyder, Lewis E.

Publications and source records attributed to Snyder, Lewis E..

Observational Results of a Multi-Telescope Campaign in Search of Interstellar Urea [(NH2)2CO]

In this paper, we present the results of an observational search for gas phase urea [(NH2)2CO] observed toward the Sgr B2(N-LMH) region. We show data covering urea transitions from ∼100 GHz to 250 GHz from five different observational facilities: the Berkeley-Illinois-Maryland-Association (BIMA) Array, the Combined Array for Research in Millimeter-wave Astronomy (CARMA), the NRAO 12 m telescope, the IRAM 30 m telescope, and the Swedish-ESO Submillimeter Telescope (SEST). The results show that the features ascribed to urea can be reproduced across the entire observed bandwidth and all facilities by best-fit column density, temperature, and source size parameters which vary by less than a factor of two between observations merely by adjusting for telescope-specific parameters. Interferometric observations show that the emission arising from these transitions is cospatial and compact, consistent with the derived source sizes and emission from a single species. Despite this evidence, the spectral complexity of both (NH2)2CO and of Sgr B2(N) makes the definitive identification of this molecule challenging. We present observational spectra, laboratory data, and models, and discuss our results in the context of a possible molecular detection of urea.

clouds - ISM↗

A Survey of Large Molecules toward the Protoplanetary Nebula CRL 61 8

We present the results of our survey toward the protoplanetary nebula CRL 618 for several large, highly saturated, oxygen bearing organic molecules of biological importance including acetaldehyde (CH3CHO), acetic acid (CH3OOH), dimethyl ether (CH3OCH3), ethanol (CH3CH2OH), formic acid (HCOOH) and methyl formate (HCOOCH3); large carbon chain molecules including methyl cyanide (CH3CN) , methylcyanoacetylene (CH3C3N), cyanoacetylene (HC3N), cyanodiacetylene (HC5N), and C6H; and finally smaller molecules including SO-34, SO2, O(C-34)S and MgNC. No biologically important organic molecules were detected. However, we report the first interferometric detections of CH3CN and vibrationally excited HC3N and HC5N toward this source. The temperature and distribution of CH3CN toward CRL 618 indicates it is formed in the outer envelope surrounding the UC HII region. Furthermore, the P-Cygni line profile and corresponding channel maps of vibrationally excited HC5N supports its distribution in the extended envelope expanding radially from the central star. The detection of vibrationally excited HC3N confirmed the temperature structure and column density of HC3N in the inner envelope found by Wyrowski and colleagues (2003). Finally, our observations clearly indicate that CRL 618 is a good source of large carbon chain species but is a very poor source to detect or produce organic species of biological importance.

Remijan, Anthony J.↗

Complex molecules in Sagittarius B2(N): The importance of grain chemistry

The complex molecules vinyl cyanide (CH2CHCN), methyl formate (HCOOCH3), and ethyl cyanide (CH3CH2CN) were observed in the Sgr B2 star-forming region with the BIMA millimeter wavelength array. A region with diameter less than 0.1 pc toward the Sgr B2(N) molecular core is found to be the major source of these molecules. Also, this source is coincident with continuum emission from dust and a center of H2O maser activity. Ultracompact (UC) H 11 regions are located within 0.1 pc. Strikingly, none of these molecules is detected toward Sgr B2(M), a core located 1 minute south of Sgr B2(N). The existence of complex molecules, a large mass of dust, high-velocity H2O masers, and UC H 11 regions strongly suggests that the Sgr B2(N) region has just begun to form stars, while the absence of strong dust emission and large molecules suggests Sgr B2(M) is more evolved. The detection of large molecules coincident with continuum emission from dust supports the idea found in current chemical models that grain chemistry is of crucial importance for the formation of these molecules.

Miao, Yanti↗

Three millimeter molecular line observations in Sagittarius B2. 1: Full synthesis mapping study of HNO, CCS, and HC(13)CCN

We present the first full synthesis maps of the small molecules HNO, CCS, and HC(13)CCN in Sgr B2. We have observed the 3.8 mm continuum, the HNO J(sub K(sub -1)K(sub 1)) = 1(sub O1)-0(sub OO), the CCS J(sub N) = 7(sub 6)-6(sub 5), and the HC(13)CCN J = 9-8 transitions in the core of the Sgr B2 molecular cloud, using the Berkeley Illinois Maryland Association (BIMA) millimeter array and the NRAO 12 m telescope. We have found that HNO exists in five major gas clumps in the Sgr B2 region, which we have labeled HNO(N), HNO(NW), HNO(E), HNO(M), and HNO(S). Of particular interest is HNO(M), a major molecular gas concentration approximately 15 sec west of Sgr B2(M) in a region of young star formation. HNO is found to be closely associated with the ionized gas and might be depleted around bright H II complexes. In general, the peak intensity of the HNO emission is found to be offset from the peak of the continuum emission. We found evidence for some chemical differentiation among the three species, HNO, CCS, and HC(13)CCN, but the abundance ratios are in fair agreement with theoretical models. Two unidentified lines, U81420 and U81518, were observed, and a previously unknown compact dust source was detected. Our HNO data indicate the presence of a rotating approximately (2.2-4.4) x 10(exp 3)solar mass gas envelope surrounding Sgr B2(N), a possible bipolar gas outflow in HNO(M), and possibly a large (approximately 4.2 x 10(exp 4)solar mass) extended rotating disk associated with HNO(S). In addition, the CCS and HC(13)CCN data approximately outline the extended component of Sgr B2 and clearly show that the southern continuum source Sgr B2(S) is actually a major molecular source as well. Consequently, the kinematics of the Sgr B2 molecular cloud is quite complex, but in moving from the northwest to south, the LSR velocity generally changes from 79 to 46 km/s.

Kuan, Yi-Jehng↗

Radar aperture synthesis observations of asteroids

We report of Goldstone-VLA, radar aperture-synthesis observations of the mainbelt asteroids 324 Bamberga and 7 Iris and the near-Earth asteroids 1991 EE and 4179 Toutatis. Simultaneous resolution of echoes in both angle and Doppler frequency provide new constraints on the mainbelt asteroids' pole directions: Bamberga's spin vector is within 40 deg of the south ecliptic pole, and the twofold ambiguity in Iris' pole direction (P. Magnusson, 1989) is resolved in favor of the ecliptic coordinates lambda = 15 deg, beta = +25 deg. For Bamberga, monostatic and bistatic radar echoes and VLA thermal-emission measurements, also reported here, are consistent with radiometric estimates of Bamberga's size and with the hypothesis that the asteroid is overlain by a regolith having a porosity of approximately 50%. Our near-Earth asteroid measurements required the development of new on-line VLA software that allows imaging of objects that are in the telescope's `near field.' This software has been successfully tested on Toutatis at a distance of 0.06 AU and will be essential for VLA observations of Earth-approaching comets.

De Pater, Imke↗

New 3 millimeter observations of interstellar HNO - Reinstating a discredited identification

HNO has been observed in six interstellar clouds via its 1(01)-0(00) transition at 3 mm wavelength. L134N, W33A, W51M, and DR 21 are new HNO sources. The excellent agreement between laboratory and astronomical rest frequency in L134N is important for establishing the correctness of the astronomical assignment of this line. With the exception of Ori A, every known NO source contains detectable HNO. The typical column density ratio N(tot)(NO)/N(tot)(HNO) appears to be 100-200, except for L134N (about 800) and DR 21(OH) (about 20). These new HNO results correct several misconceptions in the current literature.

Snyder, Lewis E.↗

Radar interferometric studies of comets

Our objectives are to use radio interferometry to study composition, velocity distribution, maser excitation, and plasma interactions of cometary gas. Two new cometary chemistry programs were started with radio interferometers: (1) the VLA used to search for HC3N emission from Comet Brorsen-Metcalf at 3.3 cm wavelength; and (2) the BIMA millimeter array used to observe Comet Austin in HCN.

Snyder, Lewis E.↗

Observations of formaldehyde and search for cyanoacetylene in Comet Brorsen-Metcalf (1989o)

The Very Large Array (VLA) was used in September 1989 to search Comet P/Brorsen-Metcalf (1989o) for the 1 sub 11-1 sub 10 transition of formaldehyde (H2CO) at 4,829.659 MHz and for the J equals 1-0, F equals 2-1 rotational transition of cyanoacetylene (HC3N) at 9098.3321 MHz. A new technique was used in reducing the data. Data blocks which were either 3x3 pixels, 5x5 pixels, or 9x9 pixels were examined for a signal from H2CO. Using this approach, different pixel clusters within the field of view can be sampled to optimize the coupling of the synthesized beam to the gas distribution. HC3N is of immediate interest as a cometary molecule because it may be a reservoir of carbon and a source of cometary CN. Our search for HC3N emission at 3.3 cm wavelength demonstrated that for this molecule the VLA can be expected to reach significant levels of sensitivity in many comets.

Snyder, Lewis E.↗

A review of radio interferometric imaging of comets

An overview of cometary observations carried out with the VLA which include OH imaging observations, studies of other molecules, and searches for continuum emission, is presented. Attention is focussed on the OH observations obtained of Comet Halley, a periodic comet, and Comet Wilson, a 'new' comet. The emission from Comet Halley is confined to a region a few times 10 exp 5 km. The emission from Comet Wilson exhibits sporadic blobs at large distances (about 10 exp 6 from the center), which vary abruptly in both position and velocity. It is suggested that for Comet Halley, collisional effects near the edge of the quenching region, which is coincidentally the approximate distance to the cometopause, may be important, and that for Comet Wilson, outgassing from cometesimals ejected from the nucleus may be significant. It is shown that asymmetric line profiles are more common than previously thought. H2CO detection experiments for comets Halley and Machholz are summarized.

De Pater, Imke↗

Observations of formaldehyde in Comet Machholtz (1988j)

Comet Machholtz's 1(11)-1(10) formaldehyde emission was detected with the VLA in September, 1988 at 6-cm wavelength; the small blueshift of -0.76 + or - 0.40 km/sec noted by these observations is consistent with an anisotropic outgassing of the cometary nucleus in the solar direction. The derived formaldehyde production rate for Comet Halley, which exhibits a similar emission line blueshift, was 1.5 x 10 to the 28th mol/sec, while for Comet Machholtz the production rate is about an order of magnitude higher, at 2 x 10 to the 29th mol/sec. The fading of Comet Machholtz after these observations is ascribed to its breakup.

Snyder, Lewis E.↗

Simultaneous imaging of optical CN lines and radio HCN lines in comet Austin

The parent molecule of cometary CN has been the subject of speculation for a long time. When HCN was detected at 3.4 mm in Comet Kohoutek, the problem seemed to be resolved, but much more detailed work on Comet Halley raised the quantitative question of whether HCN could be the only parent. Therefore, comparative CN/HCN studies are vital for understanding the origin of cometary CN. The striking observation of CN jets in Comet Halley raised another very interesting question about the origin of CN. Traditional theory permits only dust features to remain well defined far from the nucleus. The CN jets were interpreted as arising from submicron sized dust particles, perhaps CHON particles. An estimated 10 to 50 percent of the CN in the comet was in the jets in the Halley observations. Several hypotheses can be made: (1) some of the CN originates from the dust and has nothing to do with HCN; or, (2) at least some of the HCN is also produced from the dust in the coma rather than directly from the nucleus. (In the second hypothesis, whether CHN is or is not the parent of the CN associated with the dust would need to be established.) The extended scalelengths found for CO by Eberhardt et. al. (1987) and for H2CO by Snyder et. al. (1989) also support ideas like hypothesis (2). A third hypothesis should be mentioned; contrary to the usual theory, the gas flow does not become isotropic (Combi 1987). For all of the reasons mentioned, it is essential to make a detailed comparison of the spatial distributions of CN and HCN. Furthermore, because of the variability of cometary emissions, it is necessary to make measurements simultaneously.

Palmer, Patrick↗

VLA searches for formaldehyde and cyanoacetylene emission from comet P/Brorsen-Metcalf (1989o)

In Sep. 1989, Very Large Array (VLA) searches were conducted for both formaldehyde (H2CO) and cyanoacetylene (HC3N) emission from Comet P/Brorsen-Metcalf (1989o). In early July, this comet was outgassing strongly at a brighter than average preperihelion rate, and the hope was that it would continue to do so through perihelion. By observing the 1 sub 11 to 1 sub 10 transition of H2CO at 4,829.659 MHz (6 cm lambda) during the phase of maximum outgassing, it was expected that spectra would be collected with a high signal to noise ratio which would show the temporal behavior of formaldehyde relative to other molecules. During this same observation period, a search was also made for the J-1-0, F-2-1 rotational transition of cyanoacetylene at 9098.3321 MHz (3.3 cm lambda).

Snyder, Lewis E.↗

VLA observations of the OH emission from Comet Wilson (1986) - The value of high resolution in both spatial and velocity coordinates

In comparison with Comet Halley, the radio OH emission from Comet Wilson behaved very erratically, changing rapidly in position as well as in velocity, while the emission and brightness distribution from Comet Halley displayed apparent stability. A few months later, nearer perihelion, just the opposite behavior was observed at UV wavelengths. Another difference between the two comets is that the OH emission from Comet Halley seemed confined to a region a few times 100.000 km in size, while the emission from Comet Wilson showed up in sporadic blobs, with variable intensities and velocities, at distances as far as 10 to the 6th km from the nucleus. This behavior in Comet Wilson may be associated with the disintegration of the outer frosting associated with new comets and possibly with the fragmentation and ejection of cometesimals from the nucleus. As part of the data analysis, it is demonstrated that lengthening the integration time and lowering the velocity resolution affects the symmetry of the OH images and spectral-line profiles. As a consequence, asymmetric cometary OH line profiles may be more common than previously thought.

Palmer, Patrick↗

Radio detection of formaldehyde emission from Comet Halley

The J(K-1 K1) = -1(11) -10(10) transition of H2CO was detected in emission at 4829.659 MHz from Comet Halley. The H2CO emission line had a peak intensity of 2.66 + or - 0.78 mJy/beam with a small blueshift of -0.76 + or - 0.40 km/s, which is consistent with the anisotropic outgassing of the nucleus in the solar direction found for other cometary species. Data analysis suggests that cometary H2CO was produced from an extended source in the coma as well as directly from the nucleus and that it was not refrigerated as in interstellar dark nebulae. The derived H2CO production rate of 1.5 x 10 to the 28th molecules/s is obtained which is consistent with observational and theoretical findings.

Snyder, Lewis E.↗