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Solomon, S.

Publications and source records attributed to Solomon, S..

51 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Middle atmosphere composition revealed by satellite observations

A series of plots that describe the state of the stratosphere and to some degree, the mesosphere as revealed by satellite observations are shown. The pertinent instrument features, spatial and temporal coverage, and details of accuracy and precision for the experiments providing the data were described. The main features of zonal mean cross sections and polar stereographic projections were noted and intercomparisons were discussed where a parameter was measured by more than one experiment. The main purpose was to collect the available data in one place and provide enough inforamation on limitations or cautions about the data so that they could be used in model comparisons and science studies.

Russell, J. M., III↗
NASA NTRS1986

Evidence for nonlocal thermodynamic equilibrium in the nu3 mode of mesospheric ozone

Laboratory kinetic studies suggest that an appreciable fraction of the ozone produced by recombination of atomic oxygen is vibrationally excited in the nu3 mode. Further, laboratory data are available for the physical quenching of nu3, its radiative relaxation, and its radiative excitation by resonant absorption. It is shown that these chemical and physical processes are likely to result in substantial departures from local thermodynamic equilibrium for the nu3 mode of ozone in the mesosphere and therefore have important effects on infrared mesospheric ozone measurments by emission in the 9.6-micron band. Implications of these effects on data from the Limb Infrared Monitor of the Stratosphere (Remsberg et al, 1984), particularly their night/day ratio, are discussed.

Solomon, S.↗
NASA NTRS1986

Tracer transport by the diabatic circulation deduced from satellite observations

Nimbus-7 sensor data were used to track the diabatic circulation in the stratosphere to study the advective transport of CH4 and N2O as tracer species. Advective transport by the mean circulation was found to be a function of the temperature field and associated deviations from radiative equilibrium. A photochemical model was applied to account for the disappearance of the tracer species from the stratosphere. Comparisons between the SAMS data and modeling on the basis of the chemical loss rates of the tracers and the LIMS circulation data showed that the model predictions underestimated the resident abundances, although the global distributions and circulations exhibited a good match.

Solomon, S.↗
NASA NTRS1986

On the radiative balance of the stratosphere

The zonally averaged radiative balance of the stratosphere based on the measured temperature structure and gas concentrations available from the LIMS instrument is examined in detail. These data are extant for seven months (November 1978 to May 1979). The contribution to the net radiative balance due to the individual components of solar heating and longwave cooling is discussed. These components are further broken down by individual gas constituent to understand the role each gas plays in determining the total radiative heating/cooling. The deficiencies of employing a latitudinally and temporally independent Newtonian damping coefficient are also explored. In particular, the Newtonian damping time is shown to vary by a factor of two in both latitude and season. Net zonally averaged stratospheric radiative heating for the seven months of LIMS data are presented. These net heating rates are important in determining the role of advective transport of chemical constituents. An important feature that appears in the derived radiative heating is the existence of a region of net radiative cooling near the equatorial stratopause.

Kiehl, J. T.↗
NASA NTRS1986

Observations of the diurnal variation of nitrogen dioxide in the stratosphere

Observations of NO2 from the limb infrared monitor of the stratosphere (LIMS) experiment in high-latitude summer are presented. Appropriate selection of latitude and days during the month of May yields NO2 observations obtained during the afternoon and evening at solar zenith angles ranging from about 35-110 deg. These data show that the NO2 abundances in the stratosphere become strongly dependent on the solar zenith angle for angles exceeding about 80 deg. Model calculations and other observations suggest that from about 80-95 deg this dependence probably reflects variations in the propagation of the visible radiation that photodissociates NO2. The data obtained at zenith angles greater than about 95 deg provide clear evidence for the night decay of NO2 to form N2O5, and the observed decay rate is shown to be consistent with present theory.

Solomon, S.↗
NASA NTRS1986

On the atmospheric photochemistry of nitric acid

Measurements of the temporal and spatial variations in HNO3, particularly those from the Nimbus 7 limb IR monitor of the stratosphere (LIMS) satellite experiment, are compared to both a two-dimensional chemical/dynamical model and to chemistry/parcel trajectory analyses. Significant discrepancies are found between the observed and modeled variations in the winter season, especially in the polar night region. The study of the evolution of HNO3 suggests that an important source exists for this species in the high-latitude winter stratosphere that is not included in presently accepted photochemical schemes. Possible reactions to account for this discrepancy are explored.

Austin, J.↗
NASA NTRS1985

Transport processes and ozone perturbations

Current understanding of stratospheric transport in the meridional plane is reviewed, and the implications of that conceptual framework for the ozone response to chlorofluorocarbon increases are considered. The possibility of seasonal and latitudinal variations in that response is stressed. Calculations of the changes in ozone that may have occurred between the period before widespread chlorofluorocarbon usage and the present day, and the changes that would be expected to occur at steady state for 1980 chlorofluorocarbon production levels, are presented. Finally, some of the uncertainties in the adopted transport framework and its applicability to the evaluation of future perturbations are explored.

Solomon, S.↗
NASA NTRS1985

Effects of breaking gravity waves on the chemical composition of the mesosphere and lower thermosphere

Eddy diffusion and momentum forcing in the mesosphere and lower thermosphere arise principally from the effects of breaking gravity and waves. The propagation and dissipation of gravity waves depend strongly on season and latitude because of its relationship to the background zonal wind. These processes have significant effects on the transport of chemical species in that region, so that observations of variations in chemical constituents provide useful tracers for dynamical theory. A parameterization of gravity wave propagation and dissipation was incorporated in the coupled dynamical-chemical model to study these effects. Several easily observable airglow features of the mesosphere-thermosphere region are shown to provide sensitive indications of gravity wave influence. In particular, theoretical predictions of large seasonal and latitudinal variations in the atomic oxygen green line, the Meinal bands of excited OH, and the O3 densities inferred from O2 (delta supra 1 sub g) emission at altitudes from 75 to 90 km are shown to be in remarkably good agreement with observations. Implications of these sensitive chemical tracers for the dynamics of the mesosphere-lower thermosphere region and its relationship to gravity waves are discussed.

Solomon, S.↗
NASA NTRS1985

Model predictions of ozone changes

The predictions of several one-dimensional models were examined for a number of prescribed scenarios in steady-state or time-dependent approximations. A small number of two-dimensional steady-state calculations for a limited number of scenarios were compared with the results of one-dimensional models. The sensitivity of the calculated predictions to the values of input parameters were examined in order to assess recognized uncertainties in these predictions.

Johnston, H. S.↗
NASA NTRS1984

The variability of stratospheric and mesospheric NO2 in the polar winter night observed by LIMS

The LIMS experiment sounded the upper atmosphere from late October 1978 to late May 1979 and provided vertical profiles of atmospheric temperature, 03, H2O, HNO3, and NO2. Radiance averaging was used before retrieval to measure the altitude distribution of NO2 over the altitude range from the lower stratosphere into the mesosphere. Observations in the polar winter night region northward of about 70 deg N reveal NO2 levels near 175 ppbv at about 70 km, and they show a significant longitudinal variability (factor of 4 to 7). A definite temporal trend exists, showing a buildup of mesospheric and stratospheric NO2 during the polar night and a subsequent slowing of the increase of decline after sunlight returns, depending on altitude. The data represent the first experimental evidence that the thermosphere is an NO(x) source for the mesosphere and stratosphere.

Russell, M. J., III↗
NASA NTRS1981

The effect of particle precipitation events on the neutral and ion chemistry of the middle atmosphere. II - Odd hydrogen

A one dimensional time-dependent model of the neutral and ion chemistry of the middle atmosphere has been used to examine the production of odd hydrogen (H, OH, and HO2) during charged particle precipitation. At altitudes above about 65 km, odd hydrogen production depends on the ionization rate, and the atomic oxygen and water vapor densities. Odd hydrogen production is shown to exhibit diurnal and other time dependent variations during such an event at these altitudes, and the assumption that two odd hydrogen particles are always produced per ionization is reexamined.

Solomon, S.↗
NASA NTRS1981

LRIR observations of diurnal ozone variation in the mesosphere

The Limb Radiance Inversion Radiometer (LRIR) on the Nimbus 6 spacecraft obtained measurements of atmospheric infrared emission from which vertical profiles of temperature and ozone mixing ratio can be deduced. A three day sequence of data on either side of the evening terminator has been analyzed as a function of solar zenith angle (35 deg to 105 deg) and pressure level (2 mb to .1 mb). The response of the ozone field to solar flux extinction, temperature variability, and nighttime recombination are readily detected.

Anderson, G. P.↗
NASA NTRS1979

An economic analysis of five selected LANDSAT assisted information systems in Oregon

A comparative cost analysis was performed on five LANDSAT-based information systems. In all cases, the LANDSAT system was found to have cost advantages over its alternative. The information sets generated by LANDSAT and the alternative method are not identical but are comparable in terms of satisfying the needs of the sponsor. The information obtained from the LANDSAT system in some cases is said to lack precision and detail. On the other hand, it was found to be superior in terms of providing information on areas that are inaccessible and unobtainable through conventional means. There is therefore a trade-off between precision and detail, and considerations of costs. The projects examined were concerned with locating irrigation circles in Morrow County; monitoring tansy ragwort infestation; inventoring old growth Douglas fir near Spotted Owl habitats; inventoring vegetation and resources in all state-owned lands; and determining and use for Columbia River water policies.

Solomon, S.↗
NASA NTRS1979

Observational and theoretical evidence in support of a significant in-situ photochemical source of tropospheric ozone

The latitudinal and seasonal variation of ozone in the troposphere is discussed. Of particular interest is the asymmetrical behavior of this gas with respect to the two hemispheres. These asymmetries, when coupled with a diagnostic photochemical model of the troposphere, lends support to the view that ozone cannot be viewed as an inert tracer of stratospheric origin. In the calculations it is noted that it is likely that the budgets of carbon monoxide and tropospheric ozone may be quite dependent on each other and the calculations are discussed in light of the uncertainty which currently exists about representative global tropospheric background concentrations of the nitrogen oxides. In addition, the seasonal variation of excess (C-14)O2 (a stratospheric tracer) is examined and compared with the seasonal ozone variation during the same period of observations at the same location and altitudes. The distinct maxima for ozone found during the summer in the lower troposphere are not present for the (C-14)O2 data. This finding likewise suggests that photochemical processes taking place in the troposphere are an important source term for tropospheric ozone.

Fishman, J.↗