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Squyres, Steven W.

Publications and source records attributed to Squyres, Steven W..

At least 19 records

Distinct Igneous APXS Rock Compositions on Mars from Pathfinder, MER and MSL

The alpha particle x-ray spectrometer (APXS) on all four Mars Rovers returned geochemical data from about 1000 rocks and soils along the combined traverses of over 50 kilometers. Here we discuss rocks likely of igneous origin, which might represent source materials for the soils and sediments identified along the traverses. Adirondack-type basalts, abundant in the plains of Gusev Crater, are primitive, olivine bearing basalts. They resemble in composition the basaltic soils encountered at all landing sites, except the ubiquitous elevated S, Cl and Zn in soils. They have been postulated to represent closely the average Martian crust composition. The recently identified new Martian meteorite Black Beauty has similar overall geochemical composition, very distinct from the earlier established SNC meteorites. The rim of the Noachian crater Endeavour, predating the sulfate-bearing Burns formation at Meridiani Planum, also resembles closely the composition of Adirondack basalts. At Gale Crater, the MSL Curiosity rover identified a felsic rock type exemplified by the mugearitic float rock JakeM, which is widespread along the traverse at Gale. While a surprise at that time, possibly related more evolved, alkaline rocks had been previously identified on Mars. Spirit encountered the Wishstone rocks in the Columbia Hills with approx. 6% Na2O+K2O, 15 % Al2O3 and low 12% FeO. Pathfinder rocks with elevated K and Na and >50% SiO2 were postulated to be andesitic. Recently Opportunity encountered the rock JeanBaptisteCharbonneau with >15% Al2O3, >50% SiO2 and approx. 10% FeO. A common characteristic all these rocks is the very low abundance of Cr, Ni and Zn, and an Fe/Mn ratio of about 50, indicating an unaltered Fe mineralogy. Beside these likely igneous rock types, which occurred always in several rocks, a few unique rocks were encountered, e.g. Bounce Rock, a pyroxene-bearing ejecta rock fragment resembling the Shergottite EETA 79001B meteorite. The APXS data can be used to relate the findings of all 4 landing sites, constrain the water to rock ratio of sediments or imply source rock provenance. Beyond that the capability to quantify important volatile elements like P, S, Cl, and Br have provided new insights into the chemistry and the environment present during the formation of the sediments.

Gellert, Ralf

Sulfur-bearing Phases Detected by Evolved Gas Analysis of the Rocknest Aeolian Deposit, Gale Crater, Mars

The Sample Analysis at Mars (SAM) instrument suite detected SO2, H2S, OCS, and CS2 from ~450 to 800degC during evolved gas analysis (EGA) of materials from the Rocknest aeolian deposit in Gale Crater, Mars. This was the first detection of evolved sulfur species from a Martian surface sample during in situ EGA. SO2 (~3-22 μmol) is consistent with the thermal decomposition of Fe sulfates or Ca sulfites, or evolution/desorption from sulfur-bearing amorphous phases. Reactions between reduced sulfur phases such as sulfides and evolved O2 or H2O in the SAM oven are another candidate SO2 source. H2S (~41-109 nmol) is consistent with interactions of H2O, H2 and/or HCl with reduced sulfur phases and/or SO2 in the SAM oven. OCS (~1-5nmol) and CS2 (~0.2-1 nmol) are likely derived from reactions between carbon-bearing compounds and reduced sulfur. Sulfates and sulfites indicate some aqueous interactions, although not necessarily at the Rocknest site; Fe sulfates imply interaction with acid solutions whereas Ca sulfites can form from acidic to near-neutral solutions. Sulfides in the Rocknest materials suggest input from materials originally deposited in a reducing environment or from detrital sulfides from an igneous source. The presence of sulfides also suggests that the materials have not been extensively altered by oxidative aqueous weathering. The possibility of both reduced and oxidized sulfur compounds in the deposit indicates a nonequilibrium assemblage. Understanding the sulfur mineralogy in Rocknest materials, which exhibit chemical similarities to basaltic fines analyzed elsewhere on Mars, can provide insight in to the origin and alteration history of Martian surface materials.

Gale Crater

Discovery of Carbonate-Rich Outcrops in the Gusev Crater Columbia Hills by the MER Rover Spirit

The chemical composition, global abundance, distribution, and formation pathways of carbonates are central to understanding aqueous processes, climate, and habitability of early Mars. The Mars Exploration Rover (MER) Spirit analyzed a series of olivine-rich outcrops while descending from the summit region of Husband Hill into the Inner Basin of the Columbia Hills of Gusev Crater to the eastern edge of the El Dorado ripple field in late 2005. Reanalysis of Spirit s mineralogical data from the Moessbauer Spectrometer (MB) and the Miniature Thermal Emission Spectrometer (Mini-TES) and chemical data from the Alpha Particle X-Ray Spectrometer (APXS) in 2010, coupled with new laboratory data for carbonate-bearing samples, lead to identification of carbonate in one of the outcrops (Comanche) [Morris, R.V., et al., Science, 329, 421-424]. The carbonate is rich in magnesium and iron (Mc62Sd25Cc11Rh2, assuming all Ca and Mn is associated with the carbonate) and is a major component of the Comanche outcrops (16 to 34 wt.%). The mineralogical, chemical, and abundance data are constrained in multiple, mutually consistent ways by the MER analyses. For example, a low-Ca carbonate is required by the MB and APXS data and is consistent with Mini-TES data. Three spectral features attributable to fundamental infrared vibrational modes of low-Ca carbonate are present in the Mini-TES spectra of Comanche outcrops. The average composition of Comanche carbonate approximates the average composition of the carbonate globules in Martian meteorite ALH 84001. Analogy with ALH 84001, terrestrial, and synthetic carbonate globules suggests that Comanche carbonate precipitated from aqueous solutions under hydrothermal conditions at near neutral pH in association with volcanic activity during the Noachian era. Comanche outcrop morphology suggests they are remnants of a larger carbonate-bearing formation that evolved in ultramafic rock and then preferentially eroded by a combination of aeolian abrasion and chemical decomposition by exposure to acid-sulfate vapors/solutions. The high carbonate concentration in the Comanche outcrops supports climate models involving a CO2 greenhouse gas on a wet and warm early Mars and subsequent sequestering of at least part of that atmosphere in carbonate minerals.

Morris, Richard V.

The Rocks of the Columbia Hills

The Mars Exploration Rover Spirit has identified five distinct rock types in the Columbia Hills of Gusev crater. Clovis Class rock is a poorly-sorted clastic rock that has undergone substantial aqueous alteration. We interpret it to be aqueously-altered ejecta deposits formed by impacts into basaltic materials. Wishstone Class rock is also a poorly-sorted clastic rock that has a distinctive chemical composition that is high in Ti and P and low in Cr. Wishstone Class rock may be pyroclastic in origin. Peace Class rock is a sedimentary material composed of ultramafic sand grains cemented by significant quantities of Mg- and Ca-sulfates. Peace Class rock may have formed when water briefly saturated the ultramafic sands, and evaporated to allow precipitation of the sulfates. Watchtower Class rocks are similar chemically to Wishstone Class rocks, and have undergone widely varying degrees of near-isochemical aqueous alteration. They may also be ejecta deposits, formed by impacts into Wishstone-rich materials and altered by small amounts of water. Backstay Class rocks are basalt/trachybasalt lavas that were emplaced in the Columbia Hills after the other rock classes were, either as impact ejecta or by localized volcanic activity. The geologic record preserved in the rocks of the Columbia Hills reveals a period very early in martian history in which volcanic materials were widespread, impact was a dominant process, and water was commonly present.

Squyres, Steven W.

An integrated view of the chemistry and mineralogy of Martian soils.

The mineralogical and elemental compositions of the martian soil are indicators of chemical and physical weathering processes. Using data from the Mars Exploration Rovers, we show that bright dust deposits on opposite sides of the planet are part of a global unit and not dominated by the composition of local rocks. Dark soil deposits at both sites have similar basaltic mineralogies, and could reflect either a global component or the general similarity in the compositions of the rocks from which they were derived. Increased levels of bromine are consistent with mobilization of soluble salts by thin films of liquid water, but the presence of olivine in analysed soil samples indicates that the extent of aqueous alteration of soils has been limited. Nickel abundances are enhanced at the immediate surface and indicate that the upper few millimetres of soil could contain up to one per cent meteoritic material.

Zipfel, Jutta

First Atmospheric Science Results from the Mars Exploration Rovers Mini-TES

Thermal infrared spectra of the martian atmosphere taken by the Miniature Thermal Emission Spectrometer (Mini-TES) were used to determine the atmospheric temperatures in the planetary boundary layer and the column-integrated optical depth of aerosols. Mini-TES observations show the diurnal variation of the martian boundary layer thermal structure, including a near-surface superadiabatic layer during the afternoon and an inversion layer at night. Upward-looking Mini-TES observations show warm and cool parcels of air moving through the Mini-TES field of view on a time scale of 30 seconds. The retrieved dust optical depth shows a downward trend at both sites.

Mars

Mars Mineralogy by Microbeam Raman Spectrometry

The Mars Microbeam Raman Spectrometer, under development at Washington University and the Jet Propulsion Laboratory, can identify oxide, sulfide, and oxyanion minerals, bound water and OH, and organic and graphitic carbon in Mars rocks and soils in situ. Additional information is contained in the original extended abstract.

Haskin, Larry A.

A LiF silicon sandwich counter to measure water content of planetary surfaces

The neutron counter proposed here has a long history and was commercially available in a somewhat different form. This counter would be suitable for a rover or lander since it requires a rather long measuring time for each placement. It consists of two silicon wafer charged-particle counters with a layer of Li-6F deposited on the inner surface of one. The neutron detecting reaction is Li-6(n,H-3)He-4 in which the alpha particle and the triton are emitted from the Li-6 deposit back to back. If one of the detectors sees the alpha particle, the other will see the triton. This allows one to use a coincidence technique that virtually eliminates all background. The signals from each detector can be added together so that the total energy of the reaction, Q=4.6 MeV and the kinetic energy of the neutron, can be recorded.

Drake, D. M.

Viscoelastic Relaxation of Topographic Highs on Venus to Produce Coronae

Coronae on Venus are believed to result from the gravitationally driven relaxation of topography that was originally raised by mantle diapirs. We examine this relaxation using a viscoelastic finite element code, and show that an initially plateau shaped load will evolve to the characteristic corona topography of central raised bowl, annular rim, and surrounding moat. Stresses induced by the relaxation are consistent with the development of concentric extensional fracturing common on the outer margins of corona moats. However, relaxation is not expected to produce the concentric faulting often observed on the annular rim. The relaxation timescale is shorter than the diapir cooling timescale, so loss of thermal support controls the rate at which topography is reduced. The final corona shape is supported by buoyancy and flexural stresses and will persist through geologic time. Development of lower, flatter central bowls and narrower and more pronounced annular rims and moats enhanced by thicker crusts, higher thermal gradients, and crustal thinning over the diapir.

Janes, Daniel M.

Radially fractured domes: A comparison of Venus and the Earth

Radially fractured domes are large, tectonic and topographic features discovered on the surface of Venus by the Magellan spacecraft. They are thought to be due to uplift over mantle diapirism, and to date are known to occur only on Venus. Since Venus and the Earth are grossly similar in size, composition and structure, we seek to understand why these features have not been seen on the Earth. We model the uplift and fracturing over a mantle diapir as functions of lithospheric thickness and diapir size and depth. We find that lithospheres of the same thickness on the Earth and Venus should respond similarly to the same sized diapir, and that radially fractured domes should form most readily in thin oceanic lithospheres on Earth if diapiric activity is similar on the two planets. However, our current knowledge of the Earth's oceanic floors is insufficient to confirm or deny the presence of radially fractured domes. We compute the expected dimensions for these features on the Earth and suggest a search for them to determine whether mantle diapirism operates similarly on the Earth and Venus.

Janes, Daniel M.

The spatial distribution of coronae and related features on Venus

Coronae are large quasi-circular geologica features that are common on Venus. They appear to be the surface tectonic and volcanic expressions of mantle diapirs that have impinged on the underside of the venusian lithosphere. We have investigated the spatial distribution of 335 coronae and related features identified in Magellan radar data. It is more clustered than a Poisson distribution, with a statistical certainty of more than 99%. It is dominated by a single large cluster centered near the equator at about 245 deg longitude. The features are preferentially found at elevation and geoid values close to the planetary mean, with a paucity at both the highest and lowest levels of topgraphy and geoid. Some coronae appear aligned in quasi-linear chains. We attribute the clustering of coronae and related features to preferential formation of these features above regions of broad-scale mantle upwelling, and suggest that a major mantle upwelling underlies the one large cluster. We suggest that coronae are rare at the lowest elevations because these may be regions of mantle downwelling. The shortage of coronae at the highest elevations may result both from obscuration by other intense tectonism there and from suppression there of their formation by an unusually thick crust. Corona chains may be produced by enhanced passive mantle uplift below failed or incipient rifts.

Squyres, Steven W.

Plains tectonism on Venus: The deformation belts of Lavinia Planitia

High-resolution radar images from the Magellan spacecraft have revealed the first details of the morphology of the Lavinia Planitia region of Venus. A number of geologic units can be distinguished, including volcanic plains units with a range of ages. Transecting these plains over much of the Lavinia region are two types of generally orthogonal features that we interpret to be compressional wrinkle ridges and extensional grooves. The dominant tectonic features of Lavinia are broad elevated belts of intense deformation that transect the plains with complex geometry. They are many tens to a few hundred kilometers wide, as much as 1000 km long, and elevated hundreds of meters above the surrounding plains. Two classes of deformation belts are seen in the Lavinia region. 'Ridge belts' are composed of parallel ridges, each a few hundred meters in elevation, that we interpret to be folds. Typical fold spacings are 5-10 km. 'Fracture belts' are dominated instead by intense faulting, with faults in some instances paired to form narrow grabens. There is also some evidence for modest amounts of horizontal shear distributed across both ridge and fracture belts. Crosscutting relationships among the belts show there to be a range in belt ages. In western Lavinia, in particular, many ridge and fracture belts appear to bear a relationship to the much smaller wrinkle ridges and grooves on the surrounding plains: ridge morphology tends to dominate belts that lie more nearly parallel to local plains wrinkle ridges, and fracture morphology tends to dominate belts that lie more nearly parallel to local plains grooves. We use simple models to explore the formation of ridge and fracture belts. We show that convective motions in the mantle can couple to the crust to cause horizontal stresses of a magnitude sufficient to induce the formation of deformation belts like those observed in Lavinia. We also use the small-scale wavelengths of deformation observed within individual ridge belts to place an approximate lower limit on the venusian thermal gradient in the Lavinia region at the time of deformation.

Squyres, Steven W.

The topography of impact craters in 'softened' terrain on Mars

The technique of photoclinometry is applied here to Viking orbiter images of Mars in order to derive topographic profiles across Martian craters on both softened and unsoftened terrain. The results demonstrate that craters on the two kinds of terrain are in fact topographically distinct. Both simple and complex softened craters are characterized by more convex-upward crater walls than are unsoftened craters, and both simple and complex softened craters have rounder crater rims. Softened complex craters have modestly smaller crater depths than unsoftened complex craters. Both the rim heights and bowl depths are reduced, with the rim heights reduced more. Softened simple craters have much smaller crater depths than unsoftened simple craters. Both the rim heights and bowl depths are reduced, with the bowl depths reduced more.

Jankowski, David G.

Geophysical models for the formation and evolution of coronae on Venus

The proposition that Venusian coronae form over sites of mantle upwelling and are modified by subsequent gravitational relaxation is examined using two geophysical models to determine whether and under what conditions these mechanisms can produce the topography and tectonics exhibited by coronae in the Magellan altimetry data and radar images. It is shown that mantle diapirism can produce the domical topography of novae, which may be coronae in the earliest stage of formation. The model stresses induced at the surface by a mantle diapir imply the formation of radially oriented extensional fracturing as observed in novae. The novae dimensions indicate that the diapirs responsible for them are smaller than about 100 km in radius and that the elastic lithosphere is less than 32 km thick. A flattened diapir at the top of the mantle is modeled and shown to result in plateaulike uplift. The volume of the flattened model diapir is similar to that of the spherical diapirs derived for novae.

Janes, Daniel M.

Effects of material mixing on planetary gamma ray spectroscopy

The effect of mixing of rocks and soil on the gamma-ray signal emitted by Martian surface was investigated with special consideration given to the effect of the geometry of mixing. It is shown that, under certain circumstances, this scale can have a significant effect on the gamma-ray spectrum observed. The techniques that can be used to address this problem are discussed, showing that, using these techniques, rock compositions can be inferred from the signal produced by a rock-soil mixtures of unknown rock concentration and mixing geometry.

Squyres, Steven W.

Venus tectonics - An overview of Magellan observations

Magellan observations of the tectonic characteristics of highland regions on Venus are discussed with reference to competing theories for highland formation and evolution. Complex rigid terrain, or tessera, and the extent to which these elevated blocks of intensely deformed crust may be genetically related to highlands are then considered. Further, the tectonics of plains and lowland regions are examined, including deformation belts and coronae, and possible relations between such features and mantle dynamics. Implications of these observations for the global tectonics of Venus are discussed.

Solomon, Sean C.

Global distribution and characteristics of coronae and related features on Venus - Implications for origin and relation to mantle processes

The increased coverage and resolution of Magellan images and altimetry data have resulted in significant new identifications of coronae and coronalike features and more detailed information on corona morphology, topography, and distribution. The distribution of coronae and coronalike features in Magellan data are assessed in the light of the proposed hotspot origin of these features. The basic characteristics of coronae are then compared with other possible hotspot features on Venus (e.g., major volcanic shields and domelike highlands) in a first-order assessment of the implications of mantle plume-related features on Venus for interior convective processes.

Stofan, Ellen R.

Plains tectonism on Venus - The deformation belts of Lavinia Planitia

The belts of the Lavinia Planitia region of Venus are discussed in detail with reference to high-resolution radar images from the Magellan spacecraft. Two types of deformation belts are identified: ridge belts and fracture belts. Ridge belts are composed of parallel ridges, each a few hundred meters in elevation, that are interpreted as folds. Typical fold spacings are 5-10 km. Fracture belts are dominated by intense faulting, with faults in some instances paired to form narrow grabens. The formation of ridge and fracture belts is explored using simple models.

Squyres, Steven W.