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Stephanie L Vivod

Publications and source records attributed to Stephanie L Vivod.

Diamond-Loaded Polyimide Aerogel Scattering Filters and Their Applications in Astrophysical and Planetary Science Observations

Infrared-blocking, aerogel-based scattering filters have a broad range of potential applications in astrophysics and planetary science instruments in the far-infrared, sub-millimeter, and microwave regimes. This paper demonstrates the ability of conductively-loaded, polyimide aerogel filters to meet the mechanical and science instrument requirements for several experiments, including the Cosmology Large Angular Scale Surveyor (CLASS), the Experiment for Cryogenic Large-Aperture Intensity Mapping (EXCLAIM), and the Sub-millimeter Solar Observation Lunar Volatiles Experiment (SSOLVE). Thermal multi-physics simulations of the filters predict their performance when integrated into a cryogenic receiver. Prototype filters have survived cryogenic cycling to 4 K with no degradation in mechanical properties. Measurement of total hemispherical reflectance and transmittance, as well as cryogenic tests of the aerogel filters in a full receiver context, allow estimates of the integrated infrared emissivity of the filters. Knowledge of the emissivity will help instrument designers incorporate the filters into future experiments in planetary science, astrophysics, and cosmology.

Kyle R Helson↗

Characterization of Aerogel Scattering Filters for Astronomical Telescopes

We have developed a suite of novel infrared-blocking filters made by embedding scattering particles in a polymer aerogel substrate. Our developments allow us to tune the spectral performance of the filters based on both the composition of the base aerogel material and the properties of the scattering particles. Our filters are targeted for use in a variety of applications, from ground-based CMB experiments to planetary science probes. We summarize the formulations we have fabricated and tested to date, including several polyimide base aerogel formulations incorporating a range of size distributions of diamond scattering particles. We also describe the spectral characterization techniques used to measure the filters’ optical properties, including the development o fa mm-wave Fourier transform spectrometer testbed.

aerogel, filter, blocking, scattering, Fourier Tra↗

Meta-aerogels: Auxetic Shape-memory Polyurethane Aerogels

Shape-memory poly(isocyanurate-urethane) (PIR-PUR) aerogels are low-density monolithic nanoporous solids that remember and return to their permanent shape through a heating actuation step. Herein, through structural design at the macro scale, the shape-memory response is augmented with an auxetic effect manifested by a negative Poisson’s ratio of approximately -0.8 at 15% compressive strain. Thus, auxetic shape-memory PIR-PUR monoliths experience volume contraction upon compression at a temperature above the glass transition temperature of the base polymer (Tg ~ 30 °C), and they can be stowed indefinitely in that temporary shape by cooling below Tg. By heating back above Tg, the compressed/shrunk form expands back to their original shape/size. This technology is relevant to a broad range of industries spanning the commercial, aeronautical, and aerospace sectors. The materials are referred to as meta-aerogels and their potential applications include minimally invasive medical devices, soft robotics, and in situations where volume is at a premium, as for example for storage of deployable space structures and planetary habitats during transport to the point of service.

Sadeq Malakooti↗

Auxetic Thermo-Responsive Shape-Memory Polyurethane Aerogels

Shape memory polymer aerogels are stimuli-responsive aerogel materials that incorporate polymer aerogel characteristics such as flexibility at low density, and high porosity with shape-changing capabilities upon exposure to external stimuli. By designing the structure of these materials at meso- to macroscale, their shape memory response can be efficiently engineered to show an auxetic response such as a negative Poisson’s ratio, leading to an active and tunable metamaterial. We present a material technology based on a shape memory polyurethane aerogel derived from aliphatic triisocyanate and triethylene glycol, which demonstrates and remembers an auxetic shape change through a thermomechanical cycle first below, and then back again above the glass transition temperature of the polyurethane. Our auxetic shape memory polyurethane aerogels exhibit a significant auxetic response with a negative Poisson’s ratio of approximately -0.8 at 15% compressive strain. This technology is expected to impact multiple areas of interest in relation to commercial, aeronautic, and aerospace industries. Potential applications include minimally invasive medical technologies, soft robotics, and self-deployable structures and habitats. Structure-property relationships of the auxetic shape memory polymer aerogels will be discussed.

Sadeq Malakooti↗

Careers at NASA: A Universe of Options

A brief look at the journey to become a Research Chemical Engineer for NASA; highlighting the education requirements and hiring process, the main aspects of the position, and the myriad of employment options within the organization.

Stephanie L Vivod↗

Novel Infrared-blocking Aerogel Scattering Filters and Their Applications in Astrophysical and Planetary Science Observations

Infrared-blocking scattering aerogel filters have a broad range of potential applications in astrophysics and planetary science observations in the far-infrared, sub-millimeter, and microwave regimes. Successful dielectric modeling of aerogel filters allowed the fabrication of samples to meet the mechanical and science instrument requirements for several experiments, including the Sub-millimeter Solar Observation Lunar Volatiles Experiment (SSOLVE), the Cosmology Large Angular Scale Surveyor (CLASS), and the Experiment for Cryogenic Large-Aperture Intensity Mapping (EXCLAIM). Thermal multi-physics simulations of the filters predict their performance when integrated into a cryogenic receiver. Prototype filters have survived cryogenic cycling to 4 K with no degradation in mechanical properties.

Kyle R Helson↗

Polymer Aerogels for Lunar Applications and Beyond

As the Space Community endeavors to reach new heights of human exploration, materials for extreme environment are at the forefront of research. One class of materials of particular focus are polymer aerogels; lightweight solids with nanoscale pore size, high internal surface area, and extremely high porosities. These interesting properties allow aerogels to act as superior thermal insulators, IR scattering filters, sensor platforms, and vibro-acoustic mitigating materials. Polymer aerogels also have the potential to combat issues found in lunar environments such as dust and radiation mitigation.

polymer↗

Commercially-viable Hydrogen Aircraft for Reduction of Greenhouse Emissions

NASA assembled a cross-organizational multidisciplinary “radical” project team combining a diverse set of skills including aircraft architecture modelling and optimization, advanced material science, and engineering of high performance cryogenic, thermal management and fuel cell systems components and subsystems to tackle the challenging problem of development of commercially viable mid-size aircraft that would radically transform air transportation. Our team is developing an integrated conceptual and experimental methodology to realize a medium-range hydrogen aircraft design based on fuel cells, hydrogen burning engines, advanced power management and distribution, cryogenic hydrogen storage systems, and novel thermal management systems combined with an integrated aircraft concept of operations both during the flight and at the airports. The resulting analyses suggested the aircraft architecture options, sizes and layouts for the propulsion subsystem and cryogenic liquid hydrogen (LH2) tankage to verify the weight-scaling relationships for a medium-range aircraft carrying 100-200 passengers flying 1000 - 5000 km. Hydrogen - based distributed electric propulsion and cryogenic systems were further analysed, and more detailed study identified systems goals for a viable overall system weight for missions of various lengths. The developed aircraft architecture is being optimized by total specific energy density, specific power, size and mission profiles.

aircraft architecture↗

Cryogenic Fuel Aviation – Challenges and Opportunities

NASA aeronautics goals include pioneering new technology to increase efficiency and reduce emissions from air travel. The feasibility of using of on-board cryogenic fuels systems in combination with fuel cells, high efficiency engines, and electric motors for high efficiency commercial transport aircraft is being examined at NASA in collaborations with external partners. Growing emphasis on next generation air transportation resulted in the development of strategic investigations into cryogenic fuels aviation, including roadmaps for maturing new technologies, needs to improve testing and manufacturing capabilities, and the requirements for establishing regulatory and certification standards. A NASA cross-organizational multidisciplinary project team is exploring new aircraft architectures, enabling materials, and the engineering challenges associated with cryogenic fuels for aircraft. The engineering challenges include high performance cryogenic, thermal management, and power/propulsion components and subsystems to tackle the challenging problem of development of commercially viable aircraft that would radically transform air transportation.

liquid natural gas↗

Expanding the Horizons of Polymer Aerogels

As the Space Community endeavors to reach new heights of human exploration, materials for extreme environments are at the forefront of research. One class of materials of particular focus are polymer aerogels; lightweight solids with nanoscale pore size, high internal surface area, and extremely high porosities. These interesting properties allow aerogels to act as superior thermal insulators, IR scattering filters, sensor platforms, and vibro-acoustic mitigating materials. Polymer aerogels also have the potential to combat issues found in lunar environments such as dust and radiation mitigation. Herein, past and present research, synthesis, and applications of polymer aerogels will be discussed.

Stephanie L Vivod↗