Engineering topics

Stewart, G. R.

Publications and source records attributed to Stewart, G. R..

14 records

DOE OSTI2024

Effect of low-temperature compression on superconductivity and crystal structure in strontium metal

The superconducting and structural properties of elemental strontium metal were investigated under pressures up to 60 GPa while maintaining cryogenic conditions during pressure application. Applying pressure at low temperatures reveals differences in superconducting and structural phases compared to previous reports obtained at room temperatures. Notably, the superconducting critical temperature exhibits a twofold increase under compression after cryogenic cooling within the pressure range of 35–42 GPa, compared to cryogenic cooling after room-temperature compression. Subsequently, the transition width becomes significantly sharper above 42 GPa. Low-temperature x-ray diffraction measurements under pressure reveal that this change corresponds to the Sr-III to Sr-IV transition, with no evidence of any metastable structure. Furthermore, the monoclinic Sr-IV structure was observed to remain stable to much higher pressures—at least up to 60 GPa, without the appearance of the incommensurate Sr-V phase present at room temperature. As a result, this implies that thermal activation energy plays an important role in overcoming the presence of a kinetic barrier to the Sr-V phase at room temperature.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2023

Niobium substitution suppresses the superconducting critical temperature of pressurized MoB 2

A recent study has demonstrated that MoB 2 , transforming to the same structure as MgB 2 (P 6 /mmm), superconducts at temperatures above 30 K near 100 GPa [C. Pei et al., Natl. Sci. Rev. 10, nwad034 (2023)], and Nb substitution in MoB 2 stabilizes the P6/mmm structure down to ambient pressure [A. C. Hire et al., Phys. Rev. B 106, 174515 (2022)]. Here, the current work explores the high-pressure superconducting behavior of Nb-substituted MoB 2 (Nb 0.25 Mo 0.75 B 2 ). High-pressure x-ray diffraction measurements show that the sample remains in the ambient pressure P6/mmm structure to at least 160 GPa. Electrical resistivity measurements demonstrate that from an ambient pressure T c of 8K (confirmed by specific heat to be a bulk effect), the critical temperature is suppressed to 4 K at 50 GPa, before gradually rising to 5.5 K at 170 GPa. The critical temperature at high pressure is thus significantly lower than that found in MoB 2 under pressure (30 K), revealing that Nb substitution results in a strong suppression of the superconducting critical temperature. Our calculations indeed find a reduced electron-phonon coupling in Nb 0.25 Mo 0.75 B 2 , but do not account fully for the observed suppression, which may also arise from inhomogeneity and enhanced spin fluctuations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2022

Creating superconductivity in WB 2 through pressure-induced metastable planar defects

High-pressure electrical resistivity measurements reveal that the mechanical deformation of ultra-hard WB 2 during compression induces superconductivity above 50 GPa with a maximum superconducting critical temperature, T c of 17 K at 91 GPa. Upon further compression up to 187 GPa, the T c gradually decreases. Theoretical calculations show that electron-phonon mediated superconductivity originates from the formation of metastable stacking faults and twin boundaries that exhibit a local structure resembling MgB 2 (hP3, space group 191, prototype AlB 2 ). Synchrotron x-ray diffraction measurements up to 145 GPa show that the ambient pressure hP12 structure (space group 194, prototype WB 2 ) continues to persist to this pressure, consistent with the formation of the planar defects above 50 GPa. The abrupt appearance of superconductivity under pressure does not coincide with a structural transition but instead with the formation and percolation of mechanically-induced stacking faults and twin boundaries. The results identify an alternate route for designing superconducting materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2022

Comparison of response of superconductivity to impurity concentration in UBe 13 and LuBe 13

Uhlirova et al. reported superconductivity in LuBe 13 and assigned it tentatively to be BCS-type, with specific heat measurements down to 0.45 K showing the partial onset of a bulk transition. In order to check LuBe13 for unconventional behavior, as well as to further characterize the unconventional superconductivity in UBe 13 , we have prepared and characterized down to 0.40 K three arc-melted samples each of MBe 13 , M = Lu, U, using three different purities (99.999%, 99.96%, and 99.8%) of Be but with the same high purity M (Lu or U) for all three. The measurements down to 0.40 K allow the detection of the maximum in the specific heat in all three LuBe 13 samples. The resulting superconducting properties strongly depend on impurity level in UBe 13 (40% decrease in ΔC/T c , 15% decrease in T c mid ) while the three LuBe 13 samples exhibit significantly smaller changes (10% and 5% respectively) with purity. The comparison of properties at the first two levels of purity (99.999% vs 99.96%) is even more disparate: 12% decrease in T c mid in UBe 13 vs no change in LuBe 13 . Furthermore, these results are consistent with previous results that argue for unconventional superconductivity in UBe 13 and are consistent with Uhlirova et al.‘s assignment of LuBe 13 as a conventional, BCS superconductor. More generally, this example of comparing superconducting properties vs-controlled gradations in impurity levels with two compositionally and structurally “matched” superconducting compounds (one conventional and one of to-be-determined coupling behavior) offers a new method for determining unconventional behavior.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2022

The 2021 room-temperature superconductivity roadmap

Designing materials with advanced functionalities is the main focus of contemporary solid-state physics and chemistry. Research efforts worldwide are funneled into a few high-end goals, one of the oldest, and most fascinating of which is the search for an ambient temperature superconductor (A-SC). The reason is clear: superconductivity at ambient conditions implies being able to handle, measure and access a single, coherent, macroscopic quantum mechanical state without the limitations associated with cryogenics and pressurization. This would not only open exciting avenues for fundamental research, but also pave the road for a wide range of technological applications, affecting strategic areas such as energy conservation and climate change. In this roadmap we have collected contributions from many of the main actors working on superconductivity, and asked them to share their personal viewpoint on the field. The hope is that this article will serve not only as an instantaneous picture of the status of research, but also as a true roadmap defining the main long-term theoretical and experimental challenges that lie ahead. Interestingly, although the current research in superconductor design is dominated by conventional (phonon-mediated) superconductors, there seems to be a widespread consensus that achieving A-SC may require different pairing mechanisms.

"Toward hot superconductivity"↗

DOE OSTI2022

Machine learning of superconducting critical temperature from Eliashberg theory

Abstract The Eliashberg theory of superconductivity accounts for the fundamental physics of conventional superconductors, including the retardation of the interaction and the Coulomb pseudopotential, to predict the critical temperature T c . McMillan, Allen, and Dynes derived approximate closed-form expressions for the critical temperature within this theory, which depends on the electron–phonon spectral function α 2 F ( ω ). Here we show that modern machine-learning techniques can substantially improve these formulae, accounting for more general shapes of the α 2 F function. Using symbolic regression and the SISSO framework, together with a database of artificially generated α 2 F functions and numerical solutions of the Eliashberg equations, we derive a formula for T c that performs as well as Allen–Dynes for low- T c superconductors and substantially better for higher- T c ones. This corrects the systematic underestimation of T c while reproducing the physical constraints originally outlined by Allen and Dynes. This equation should replace the Allen–Dynes formula for the prediction of higher-temperature superconductors.

36 MATERIALS SCIENCE↗

NASA NTRS1998

Three-Dimensional Hydrodynamic Simulations of the Postimpact Proto-Earth

Astrophysical fluid configurations are susceptible to a variety of nonaxisymmetric instabilities under the combined effects of rotation, self-gravity, and thermal pressure. When strong enough, they can induce rapid transport of mass and angular momentum. Our own previous studies of nonaxisymmetric instabilities in model protostars and protostellar disks show that significant transport can occur on orbital timescales and that material can be ejected to large distances. In this contribution, we present three-dimensional simulations of the circumterrestrial debris belt that may have resulted from a giant impact. Our three-dimensional hydrodynamics code with self-gravity and artificial viscosity is fully second-order in space and time; the equations of hydrodynamics and the Poisson equation are solved on an Eulerian cylindrical grid. In the preliminary calculations presented here, we use a simplified EOS where the central proto-Earth is treated as an n = 1/2 polytropic fluid, surrounded by a more compressible, rapidly rotating, fluid disk that represents silicate vapor. Our initial disk parameters are generated from the endstate data of recent smoothed particle hydrodynamics giant-impact calculations. Ultimately, we wish to detennine under what conditions nonaxisymmetric instabilities grow in the postimpact disk and whether they facilitate the transport of material outside the proto-Earth's Roche Limit, leading to the formation of the Moon. In future work, we hope to include a more realistic EOS and the consequences of heating, cooling, and phase transitions.

Pickett, B. K.↗

NASA NTRS1987

Formation of giant molecular clouds in global spiral structures: The role of orbital dynamics and cloud-cloud collisions

The different roles played by orbital dynamics and dissipative cloud-cloud collisions in the formation of giant molecular clouds (GMCs) in a global spiral structure are investigated. The interstellar medium (ISM) is simulated by a system of particles, representing clouds, which orbit in a spiral-perturbed, galactic gravitational field. The overall magnitude and width of the global cloud density distribution in spiral arms is very similar in the collisional and collisionless simulations. The results suggest that the assumed number density and size distribution of clouds and the details of individual cloud-cloud collisions have relatively little effect on these features. Dissipative cloud-cloud collisions play an important steadying role for the cloud system's global spiral structure. Dissipative cloud-cloud collisions also damp the relative velocity dispersion of clouds in massive associations and thereby aid in the effective assembling of GMC-like complexes.

Roberts, W. W., Jr.↗

NASA NTRS1987

Hamiltonian theory of nonlinear waves in planetary rings

The derivation of a Hamiltonian field theory for nonlinear density waves in Saturn's rings is discussed. Starting with a Hamiltonian for a discrete system of gravitating streamlines, an averaged Hamiltonian is obtained by successive applications of Lie transforms. The transformation may be carried out to any desired order in q, where q is the nonlinearity parameter defined in the work of Shu, et al (1985) and Borderies et al (1985). Subsequent application of the Wentzel-Kramer-Brillouin Method approximation yields an asymptotic field Hamiltonian. Both the nonlinear dispersion relation and the wave action transport equation are easily derived from the corresponding Lagrangian by the standard variational principle.

Stewart, G. R.↗

NASA NTRS1987

Collisional dynamics of perturbed particle disks in the solar system

Investigations of the collisional evolution of particulate disks subject to the gravitational perturbation of a more massive particle orbiting within the disk are underway. Both numerical N-body simulations using a novel collision algorithm and analytical kinetic theory are being employed to extend our understanding of perturbed disks in planetary rings and during the formation of the solar system. Particular problems proposed for investigation are: (1) The development and testing of general criteria for a small moonlet to clear a gap and produce observable morphological features in planetary rings; (2) The development of detailed models of collisional damping of the wavy edges observed on the Encke division of Saturn's A ring; and (3) The determination of the extent of runaway growth of the few largest planetesimals during the early stages of planetary accretion.

Roberts, W. W.↗

NASA NTRS1985

Preparing a health care delivery system for Space Station

NASA's Space Station is viewed as the beginning of man's permanent presence in space. This paper presents the guidelines being developed by NASA's medical community in preparing a quality, permanent health care delivery system for Space Station. The guidelines will be driven by unique Space Station requirements such as mission duration, crew size, orbit altitude and inclination, EVA frequency and rescue capability. The approach will emphasize developing a health care system that is modular and flexible. It will also incorporate NASA's requirements for growth capability, commonality, maintainability, and advanced technology development. Goals include preventing unnecessary rescue attempts, as well as maintaining the health and safety of the crew. Proper planning will determine the levels of prevention, diagnosis, and treatment necessary to achieve these goals.

Logan, J. S.↗

NASA NTRS1985

The collisional dynamics of particulate disks

It is shown that the use of the Krook equation greatly simplifies the discussion of the collisional dynamics of particulate disks. Collisions are assumed to be inelastic from the outset. A simple heuristic argument is used to compute the effective collision rate in a disk of spherical particles with a power-law distribution of sizes. For Saturn's rings, the effective collision rate for momentum transport is substantially lower than that conventionally estimated on the basis of an observed optical depth at visual wavelengths. The closure of the vertically integrated set of moment equations without discarding the third-order moments at the outset is discussed, allowing for the possibility of a bent disk. In the limit that the collision frequency is much larger than the orbit frequency, the usual Navier-Stokes equations of viscous hydrodynamics for a thin disk are recovered with an explicit expression for the shear viscosity. The method is generalized to include the effects of gravitational scattering.

Shu, F. H.↗

NASA NTRS1984

Collision-induced transport processes in planetary rings

The physics of collision-dominated particle disks around planets is analyzed from both the analytical and numerical point of view. The existence of Saturn's ringlet structure is analyzed in terms of a radial instability induced by viscous diffusion. The detailed model described is based on the assumption of uniform particle size. Modifications caused by finite particle size, gravitational effects, and a distribution of particle sizes are discussed.

Stewart, G. R.↗

NASA NTRS1980

A gravitational kinetic theory for planetesimals

An analytical theory is developed for the velocity evolution of nonaccreting planetesimal populations, based on the Boltzmann and Fokker-Planck equations. Adapting Shkarofsky's calculation of plasma viscosities, the rate of increase in random velocities due to gravitational encounters between planetesimals of equal mass is found to be one-third to one-half Safronov's result. Comparison with Wetherill's numerical experiments suggests that the Fokker-Planck equation underestimates the effectiveness of encounters and that Safronov's value is approximately correct. For populations of nonuniform sizes, the Fokker-Planck equation indicates an efficient redistribution of energy from the largest bodies to the smaller ones. By conserving angular momentum, the rate of radial spreading of orbits is also derived.

Stewart, G. R.↗