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Stewart, S. T.

Publications and source records attributed to Stewart, S. T..

The Principal Hugoniot of Iron-Bearing Olivine to 1465 GPa

Shock compression experiments on natural compositions are imperative to accurately model planetary accretion and the interior dynamics of planets. Combining shock compression experiments from the Sandia Z Machine and the OMEGA EP laser facility with density functional theory-based molecular dynamics calculations, we report the first pressure-density-temperature (P-ρ-T) relationship of natural iron (Fe)-bearing olivine ((Mg 0.91 Fe 0.09 ) 2 SiO 4 ) on the principal Hugoniot between 166 and 1,465 GPa. Additionally, we report the first reflectivities of natural olivine liquid in this pressure range. Compared to the magnesium-endmember forsterite (Mg 2 SiO 4 ), the presence of Fe in typical mantle abundance (~9 wt% FeO) alters the U S -u P relation of olivine. Furthermore, the shock temperature and reflectivity of olivine are indistinguishable from forsterite where experimental conditions overlap. Both forsterite and olivine increase in reflectivity (and hence optical conductivity) with increasing temperature, with a maximum reflectivity of ~31% at shock velocities greater than 22 km/s (~800 GPa).

58 GEOSCIENCES↗

Temperature and Density on the Forsterite Liquid‐Vapor Phase Boundary

Abstract The physical processes during planet formation span a large range of pressures and temperatures. Giant impacts, such as the one that formed the Moon, achieve peak pressures of 100s of GPa. The peak shock states generate sufficient entropy such that subsequent decompression to low pressures intersects the liquid‐vapor phase boundary. The entire shock‐and‐release thermodynamic path must be calculated accurately in order to predict the post‐impact structures of planetary bodies. Forsterite (Mg 2 SiO 4 ) is a commonly used mineral to represent the mantles of differentiated bodies in hydrocode models of planetary collisions. Here, we performed shock experiments on the Sandia Z Machine to obtain the density and temperature of the liquid branch of the liquid‐vapor phase boundary of forsterite. This work is combined with previous work constraining pressure, density, temperature, and entropy of the forsterite principal Hugoniot. We find that the vapor curves in previous forsterite equation of state models used in giant impacts vary substantially from our experimental results, and we compare our results to a recently updated equation of state. We have also found that due to under‐predicted entropy production on the principal Hugoniot and elevated temperatures of the liquid vapor phase boundary of these past models, past impact studies may have underestimated vapor production. Furthermore, our results provide experimental support to the idea that giant impacts can transform much of the mantles of rocky planets into supercritical fluids.

58 GEOSCIENCES↗

Silicate Melting and Vaporization During Rocky Planet Formation

Collisions that induce melting and vaporization can have a substantial effect on the thermal and geochemical evolution of planets. However, the thermodynamics of major minerals are not well known at the extreme conditions attained during planet formation.We obtained new data at the Sandia Z Machine and use published thermodynamic data for the major mineral forsterite (Mg 2 SiO 4 ) to calculate the specific entropy in the liquid region of the principal Hugoniot.We use our calculated specific entropy of shocked forsterite, and revised entropies for shocked silica, to determine the critical impact velocities for melting or vaporization upon decompression from the shocked state to 1 bar and the triple points, which are near the pressures of the solar nebula.We also demonstrate the importance of the initial temperature on the criteria for vaporization. Applying these results to N-body simulations of terrestrial planet formation, we find that up to 20% to 40% of the total system mass is processed through collisions with velocities that exceed the criteria for incipient vaporization at the triple point. Vaporizing collisions between small bodies are an important component of terrestrial planet formation.

58 GEOSCIENCES↗

Shock Demagnetization of Pyrrhotite

Maps of the remanent magnetic field of Mars show demagnetized zones within and around giant impact basins. It is likely that vast regions of the Martian crust were demagnetized due to a shock-induced phase change or magnetic transition of magnetic minerals in the crust. This hypothesis is supported by the fact that around the Hellas and Argyre basins, the edges of the unmagnetized zones roughly correspond with peak shock pressure contour lines of a few GPa. Although pyrrhotite is not a major carrier of magnetization in the Earth s crust, it is a common phase in Martian meteorites and may be an important carrier in the Martian crust. Understanding the effects of shock waves on magnetic minerals is critical for determining the origin of the demagnetized zones in impact basins and possibly for identifying the major magnetic carrier phases. Here we present the results of the first controlled shock demagnetization measurements on pyrrhotite. Previous experiments: Shock demagnetization

Louzada, K. L.↗

Impact Crater Geometries Provide Evidence for Ice-rich Layers at Low Latitudes on Mars

The impact cratering record documents the history of resurfacing events on Mars. The morphology and distribution of layered (rampart) ejecta blankets provide insights into the presence of volatiles in the upper crust [1-4]. The physical properties of the crust and history of water have been revealed through recent quantitative studies of the geometry of Martian craters [5-91. Here, we present the results from a study focused on impact craters in Utopia Planitia and the Elysium Mons province to infer the history and properties of resurfacing episodes.

Black, B. A.↗

Martian Surface Properties: Inferences from Resolved Differences in Crater Geometries

Impact craters are a natural probe of planetary sub-surfaces, both from the excavated material and from crater geometries, which are sensitive to material properties of the target. One of the most intriguing aspects of Martian craters is the morphology of the ejecta blankets. All fresh and many older Martian craters larger than a few km are surrounded by ejecta blankets which appear fluidized, with morphologies believed to form by entrainment of liquid water. In addition to the ejecta morphology, quantitative information about the subsurface composition may be derived from geometrical measurements, e.g., rim uplift height and ejecta blanket volumes. In order to use craters to derive subsurface composition or test rampart morphology formation hypotheses, accurate measurements with quantified error estimates are required. We have developed and tested a toolkit for measurements of crater geometry using the MOLA altimetry data. Here, we present the results from geometry measurements on fresh craters in Lunae Planum and Utopia Planitia.

Valiant, G. J.↗