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Stokes, G. M.

Publications and source records attributed to Stokes, G. M..

Identification of atmospheric C2H2 lines in the 3230-3340/cm region of high resolution solar absorption spectra recorded at the National Solar Observatory

A search has been conducted for the presence of absorption lines of atmospheric acetylene (C2H2), taking into account the 3230-3340/cm interval of 0.01/cm resolution solar absorption spectra recorded with the interferometer of the Solar Observatory on Kitt Peak. A total of 12 lines belonging to the strong nu-3 and nu-2 + nu-4 + nu-5 bands has been identified in this interval. This letter provides a report regarding the identification analysis of selected atmospheric C2H2 lines in a representative set of Kitt Peak solar spectra.

Rinsland, C. P.

Infrared measurements of atmospheric ethane (C2H6) from aircraft and ground-based solar absorption spectra in the 3000/cm region

A number of prominent Q-branches of the nu-7 band of C2H6 have been identified near 3000/cm in aircraft and ground-based infrared solar absorption spectra. The aircraft spectra provide the column amount above 12 km at various altitudes. The column amount is strongly correlated with tropopause height and can be described by a constant mixing ratio of 0.46 ppbv in the upper troposphere and a mixing ratio scale height of 3.9 km above the tropopause. The ground-based spectra yield a column of 9.0 x 10 to the 15th molecules/sq cm above 2.1 km; combining these results implies a tropospheric mixing ratio of approximately 0.63 ppbv.

Coffey, M. T.

Infrared Measurements of Atmospheric Ethane (C2H6) From Aircraft and Ground-Based Solar Absorption Spectra in the 3000/ cm Region

A number or prominent Q-branches or the upsilon(sub 7) band or C2H6 have been identified near 3000/ cm in aircraft and ground-based infrared solar absorption spectra. The aircraft spectra provide the column amount above 12 km at various altitudes. The column amount is strongly correlated with tropopause height and can be described by a constant mixing ratio of 0.46 ppbv in the upper troposphere and a mixing ratio scale height of 3.9 km above the tropopause. The, ground-based spectra yield a column of 9.0 x 10(exp 15) molecules/sq cm above 2.1 km; combining these results implies a tropospheric mixing ratio of approximately 0.63 ppbv.

Coffey, M. T.

Diurnal variations of atmospheric nitric oxide - Ground-based infrared spectroscopic measurements and their interpretation with time-dependent photochemical model calculations

Total vertical column amounts of NO have been derived from infrared solar absorption spectra recorded near sunrise and sunset with the 0.01 per cm resolution Fourier transform interferometer at the national Solar Observatory on Kitt peak (elevation 2095 m, latitude 31.9 degrees N) on February 23, 1981. The results show an increase in NO concentration in the morning, late afternoon values about 40 percent higher than in the morning, and a decrease in NO concentration prior to sunset. The measured diurnal changes in the total vertical column amount are compared with values obtained from time-dependent photochemical calculations.

Rinsland, C. P.

Ground-based infrared spectroscopic measurements of atmospheric hydrogen cyanide

A number of lines of the nu-3 band of hydrogen cyanide have been detected in solar absorption spectra recorded near sunrise and sunset at Kitt Peak National Observatory (elevation 2095 m) with a 0.01/cm resolution Fourier transform spectrometer. Analysis of two of the strongest and best isolated lines has led to a value of 2.73 x 10 to the 15th molecules/sq cm for the vertical column abundance of HCN above Kitt Peak. The accuracy of this value is estimated as + or - 25%. This result, combined with the stratospheric concentration of HCN derived by Coffey, Mankin, and Cicerone (1981), yields 166 parts per trillion by volume for the average mixing ratio of HCN between 2 and 12 km. This is the first determination of the HCN concentration in the nonurban troposphere.

Rinsland, C. P.

Mount St. Helens related aerosol properties from solar extinction measurements

A network of solar radiometers, operated on the North American Continent for an average of 2 years before the first major eruption of Mount St. Helens, Washington, continues to collect direct solar data through the eruptive phase of this volcano. The radiometers collect spectral data through 12 interference filters spanning the sensitivity of the photodiode used as detector. The data are collected every 5 minutes in seven filters and every 15 minutes in five additional filters. A variant of the classical Langley method has been used to measure the optical depth of the aerosols as a function of wavelength. The network, which is the nearest station, is located some 180 kilometers east of the volcano, well within range of noticeable effects during much of the minor as well as major activity. The wavelength dependence of the aerosol-optical depth before and after the 22 July 1980 major eruption, which was well characterized because of favorable meteorological conditions is discussed.

Michalsky, J. J.

Far-infrared observations of the Lagoon Nebula /M8/

Large-beam far-infrared photometry is used to estimate the dust temperature and mass, geometry, and energetics of the Lagoon Nebula (M8). Most of the data can be explained in terms of the visible star cluster, NGC 6530, heating a dense molecular cloud that lies behind it. The source M8E, however, may be heated internally, and appears to be a likely site of very recent star formation. The associated molecular cloud may be the location of future stellar formation activity as well.

Thronson, H. A., Jr.

Interstellar titanium

High-dispersion photoelectric scans of the interstellar 3384-A line of Ti II have been obtained for 68 stars. Column densities of Ti II are derived for the various individual kinematic components in the scans. These column densities, and those integrated over all components in the respective directions, are compared with corresponding results for Na I, Ca II, K I, H I, and H2. The column densities of titanium and hydrogen show directly that the depletion of titanium from the interstellar gas is large and variable. The abundance of titanium in the gas also varies strongly relative to the Na, K, and the grains responsible for reddening. In contrast, the titanium/calcium column-density ratio is relatively constant at about 4 times its solar value. Lower depletions are found in four out of five cases of absorption in the intercloud medium and toward each of two stars at high galactic z-distances. The column densities of Ca II and Ti II are used to estimate the electron densities in individual kinematic components. These electron densities are uncorrelated with the depletions of titanium, indicating that depletion is not a simple or unique function of local density.

Stokes, G. M.

Observations of interstellar titanium toward 47 stars

Results are presented from photoelectric scans of the interstellar 3384-A line of Ti II obtained at a resolution of 3.7 km/s for 47 stars. Although the depletion of titanium from the interstellar gas is large and highly variable, its ratio to the depletion of interstellar calcium is relatively constant; titanium is less depleted than calcium by a factor of about four. A method for determining approximate electron densities from the Ca II and Ti II column densities is applied to 51 interstellar clouds.

Stokes, G. M.