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Storey, John

Publications and source records attributed to Storey, John.

Potential Impact of Flexible CHP on the Future Electric Grid in California

This presentation summarizes results from the “Modeling the Impact of Flexible CHP on the Future Electric Grid In California” report (doi:10.2172/1649545). The analysis estimated the value of flexible CHP to the gird in a somewhat decarbonized grid in California. The analysis found that advanced, flexible CHP can more than double capacity with a 6 year payback period, save site owners up to $760 million, reduce CA-ISOs operating cost by over $700 million, and eliminate hours of grid stress in CA-ISO.

CHP↗

Performance of direct injected propane and gasoline in a high stroke-to-bore ratio SI engine: Pathways to diesel efficiency parity with ultra low soot

This work explores pathways to achieve diesel-like, high-efficiency combustion with stoichiometric 3-way catalyst compatible combustion in a single-cylinder spark ignition (SI) research engine. A unique high stroke-to-bore engine design (1.5:1) with cooled exhaust gas recirculation (EGR) and high compression ratio ( r c ) was used to improve engine efficiency by up to 30% compared with a production turbocharged gasoline direct injection spark ignition engine. Engine experiments were conducted with both 91 RON E10 gasoline and liquified petroleum gas (LPG) (i.e. autogas) and were compared to legacy gasoline data on the production engine. Geometric compression ratio ( r c ) of 13.3:1 was used for both fuels with additional experiments at 16.8:1 for LPG only. Measurements of exhaust soot particle size and number concentrations were made with both fuels. Significant reduction in soot particles across the whole particle size range were achieved with LPG due to the elimination of in-cylinder liquid films. The effects of EGR, late intake valve closing (IVC) and fuel characteristics were investigated through their effects on efficiency, combustion stability and soot production. Results of 47% gross thermal efficiency, and 45% net thermal efficiency at stoichiometric engine operation, at up to 17 bar IMEP and 2000 r/min with 16.8:1 r c were achieved with LPG. Estimated brake efficiency values were compared to a contemporary medium duty diesel engine illustrating the benefits of the chosen path for achieving diesel efficiency parity.

33 ADVANCED PROPULSION SYSTEMS↗

Modeling the Impact of Flexible CHP on the Future Electric Grid In California

Combined heat and power (CHP) systems provide electricity and process heat at more than 4,400 industrial and commercial facilities across the United States. Typically fueled with natural gas, a CHP system combines a prime mover (such as a reciprocating engine) with a generator and heat recovery equipment, allowing operation at very high efficiencies (65–85%). Traditionally, CHP systems have been configured to serve local electrical and thermal loads at the sites where they are deployed. Units are sized to ensure a high capacity factor for the equipment, and the electricity generated tends to be used on site. CHP units in the United States already generate over 12% of the nation’s electricity. However, CHP’s potential benefits could be much greater if power generated could be used beyond the site, because the analysis was performed under the assumption that sites could use all the thermal output. Analysis of a few key sectors confirmed that this assumption is valid (for more information, see Appendix E). Those benefits could include improved grid reliability and resilience, as well as lower-cost options for providing energy and other grid services. The potential benefits also align well with grid modernization objectives, as shown in Combined heat and power (CHP) systems provide electricity and process heat at more than 4,400 industrial and commercial facilities across the United States., and greater electrification of loads, driven by carbon reduction priorities.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Performance of a Printed Bimetallic (Stainless Steel and Bronze) Engine Head Operating under Stoichiometric and Lean Spark Ignited (SI) Combustion of Natural Gas

Additive manufacturing was used to fabricate a head for an automotive-scale single-cylinder engine operating on natural gas. The head was consisted of a bimetallic composition of stainless steel and bronze. The engine performance using the bimetallic head was compared against the stock cast iron head. The heads were tested at two speeds (1200 and 1800 rpm), two brake mean effective pressures (6 and 10 bar), and two equivalence ratios (0.7 and 1.0). The bimetallic head showed good durability over the test and produced equivalent efficiencies, exhaust temperatures, and heat rejection to the coolant to the stock head. Higher combustion temperatures and advanced combustion phasing resulted from use with the bimetallic head. The implication is that with optimization of the valve timing, an efficiency benefit may be realized with the bimetallic head.

42 ENGINEERING↗

Detection of Polar Compounds Condensed on Particulate Matter Using Capillary Electrophoresis-Mass Spectrometry

A new analytical method to aid in the understanding of the organic carbon (OC) phase of particulate matter (PM) from advanced compression ignition (ACI) operating modes, is presented. The presence of NO2 and unburned fuel aromatics in ACI emissions, and the low exhaust temperatures that result from this low temperature combustion strategy, provide the right conditions for the formation of carboxylic acids and nitroaromatic compounds. These polar compounds contribute to OC in the PM and are not typically measured using nonpolar solvent extraction methods such as the soluble organic fraction (SOF) method. The new extraction and detection method employs capillary electrophoresis with electrospray ionization mass spectrometry (CE-ESI MS) and was specifically developed to determine polar organic compounds in the ACI PM emissions. The new method identified both nitrophenols and aromatic carboxylic acids in the ACI PM. The ACI air-fuel stratification mode and NOx emissions were found to correlate with the presence and amount of the individual polar species identified.

Lewis Sr, Samuel↗

Characterization of Particulate Matter Emissions from Heavy-Duty Partially Premixed Compression Ignition with Gasoline-Range Fuels

In this study, the compression ratio of a commercial 15L heavy-duty diesel engine was lowered and a split injection strategy was developed to promote partially premixed compression ignition (PPCI) combustion. Various low reactivity gasoline-range fuels were compared with ultra-low-sulfur diesel fuel (ULSD) for steady-state engine performance and emissions. Specially, particulate matter (PM) emissions were examined for their mass, size and number concentrations, and further characterized by organic/elemental carbon analysis, chemical speciation and thermogravimetric analysis. As more fuel-efficient PPCI combustion was promoted, a slight reduction in fuel consumption was observed for all gasoline-range fuels, which also had higher heating values than ULSD. Since mixing-controlled combustion dominated the latter part of the combustion process, hydrocarbon (HC) and carbon monoxide (CO) emissions were only slightly increased with the gasoline-range fuels. In contrast, soot emissions were significantly reduced with the gasoline-range fuels, including a ~70% reduction in micro soot sensor measurements and a >50% reduction in smoke meter measurements. All gasoline-range fuel PM samples were also found to contain higher amount of volatile species and organic carbon fractions compared to ULSD PM samples as measured by thermogravimetric and EC-OC analyses. Various partially oxidized HC species and nitrophenolic compounds were also detected by TDP-GC-MS and CE-MS techniques, which implied that more pronounced PPCI combustion occurred with the gasoline-range fuels. As a whole similar PM oxidation behavior was observed despite the differences in reactivity and chemical properties of the fuels, even though there may be some significant impacts under certain operating conditions.

33 ADVANCED PROPULSION SYSTEMS↗

Characterization of GDI PM during Vehicle Start-Stop Operation

As the fuel economy regulations increase in stringency, many manufacturers are implementing start-stop operation to enhance vehicle fuel economy. During start-stop operation, the engine shuts off when the vehicle is stationary for more than a few seconds. When the brake is released by the driver, the engine restarts. Depending on traffic conditions, start-stop operation can result in fuel savings from a few percent to close to 10%. Gasoline direct injection (GDI) engines are also increasingly available on light-duty vehicles. While GDI engines offer fuel economy advantages over port fuel injected (PFI) engines, they also tend to have higher PM emissions, particularly during start-up transients. Thus, there is interest in evaluating the effect of start-stop operation on PM emissions. In this study, a 2.5L GDI vehicle was operated over the FTP75 drive cycle. Runs containing cold starts (FTP-75 cycle Phases 1 & 2) and multiple runs containing hot starts (FTP-75 cycle Phases 3 & 4) were performed each day. Note that the FTP-75 Phases 3 & 4 are identical to Phases 1 & 2 except that the engine is warmed up. Three fuels were evaluated: an 87 AKI gasoline (E0), a 21% splash blend of ethanol and the 87 AKI gasoline (E21), and a 12% splash blend of iso-butanol and the 87 AKI gasoline (iBu12). PM mass, transient particle number concentration and size distribution, and soot mass concentration were evaluated for both start-stop operation and no start-stop operation on each fuel. Three Phase 1 & 2 cycles and as many as 27 Phase 3 & 4 cycles were performed for each fuel-mode combination. Composite FTP mass emissions for E0 and iBu12 showed increased total PM emissions with start-stop operation, but E21 showed no difference. Statistical analysis of the effects of start-stop on PM number and soot emissions showed different trends for different fuels. For example, when E0 is used with start-stop operation, the particle number decreased but the soot mass tended to increase. The results of this study have implications for hybrid vehicle operation as well because the internal combustion engine in hybrid vehicles must stop and re-start during normal operation.

Storey, John↗

Co-Optimization of Fuels & Engines: Efficiency Merit Function for Spark-Ignition Engines; Revisions and Improvements Based on FY16-17 Research

Early in fiscal year 2016 (FY16), a fuel efficiency 'merit function' was developed to provide a simple tool to evaluate the potential thermal efficiency benefits of various fuels when multiple fuel properties or performance metrics are changing simultaneously. It has also proven to be useful for evaluating various fuel candidates and provides a useful framework for capturing and summarizing results from multiple projects within the Co-Optima Fuel Properties and Advanced Engine Development research portfolios. The objective of this report is to collect pertinent research results from FY16 and the first half of FY17, and to integrate them into an improved merit function.

33 ADVANCED PROPULSION SYSTEMS↗

U.S. Department of Energy Fuels & Lubricants Project on Lubricant Technology - Innovation, Discovery, Design, and Engineering (Final Report)

In 2016, the Vehicle Technologies Office (VTO) of the Department of Energy (DOE) issued a solicitation for the AOP Lab Call research in FY2017 on a number of topics related to vehicles. Topic 6A of the Lab Call focused on research related to advanced lubricants: '...(in) support of the lubricants program goal to, by 2020, demonstrate novel formulations for powertrain and driveline lubricants, compatible with new and legacy vehicles, to achieve at least a 4 percent real-world fuel economy improvement.' Argonne National Laboratory (ANL) in collaboration with Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) was awarded a 3-year multilab project on 'Lubricant Technology - Innovation, Discovery, Design, and Engineering.' Research on the project began in FY2017 at the three laboratories with industry participation; however, in FY2018, the project was terminated due to budgetary constraints. The following is the final report for the project and highlights progress made during the first year of research. The report is divided into sections that highlight the following: goals, objectives, milestones and deliverables; project highlights; outreach - publications, conferences, and reports; milestones accomplished; research progress.

30 DIRECT ENERGY CONVERSION↗

Fuel economy and emissions testing of an RCCI series hybrid vehicle

In the current work, a series hybrid vehicle has been constructed that utilises a dual-fuel, reactivity controlled compression ignition (RCCI) engine. Full vehicle testing was conducted on chassis dynamometers over the US Environmental Protection Agency Federal Test Procedure, Highway Fuel Economy Test and US06 using RCCI combustion with commercially available gasoline and ultra-low sulphur diesel. Fuel economy and emissions data were recorded over the specified test cycles. Testing revealed that engine-out emissions were similar to steady-state dynamometer engine testing. However, tailpipe-out emissions saw a reduction of HC and CO during the HWFET of 98.5%. Fuel economy was lower than expected due to the higher drivetrain losses of the series hybrid drivetrain. Finally, simulated changes to the drivetrain showed that it may be possible to increase fuel economy significantly, while meeting EPA emissions standards.

33 ADVANCED PROPULSION SYSTEMS↗

On-Board Particulate Filter Failure Prevention and Failure Diagnostics Using Radio Frequency Sensing

The increasing use of diesel and gasoline particulate filters requires advanced on-board diagnostics (OBD) to prevent and detect filter failures and malfunctions. Early detection of upstream (engine-out) malfunctions is paramount to preventing irreversible damage to downstream aftertreatment system components. Such early detection can mitigate the failure of the particulate filter resulting in the escape of emissions exceeding permissible limits and extend the component life. However, despite best efforts at early detection and filter failure prevention, the OBD system must also be able to detect filter failures when they occur. In this paper, radio frequency (RF) sensors were used to directly monitor the particulate filter state of health for both gasoline particulate filter (GPF) and diesel particulate filter (DPF) applications. The testing included controlled engine dynamometer evaluations, which characterized soot slip from various filter failure modes, as well as on-road fleet vehicle tests. The results show a high sensitivity to detect conditions resulting in soot leakage from the particulate filter, as well as potential for direct detection of structural failures including internal cracks and melted regions within the filter media itself. Finally and furthermore, the measurements demonstrate, for the first time, the capability to employ a direct and continuous monitor of particulate filter diagnostics to both prevent and detect potential failure conditions in the field.

42 ENGINEERING↗

Characterization of Hydrocarbon Emissions from Gasoline Direct-Injection Compression Ignition Engine Operating on a Higher Reactivity Gasoline Fuel

Low temperature combustion engine technologies are being investigated for high efficiency and low emissions. However, such engine technologies often produce higher engine-out hydrocarbon (HC) and carbon monoxide (CO) emissions, and their operating range is limited by the fuel properties. In this study, two different fuels, a US market gasoline containing 10% ethanol (RON 92 E10) and a higher reactivity gasoline (RON 80 E0), were compared on a Delphi’s second generation Gasoline Direct-Injection Compression Ignition (Gen 2.0 GDCI) multi-cylinder engine. The engine was evaluated at three operating points ranging from a light load condition (800 rpm/2 bar IMEP g ) to medium load conditions (1500 rpm/6 bar and 2000 rpm/10 bar IMEP g ). The engine was equipped with two oxidation catalysts, between which was located the exhaust gas recirculation (EGR) inlet. Samples were taken at engine-out, between the catalysts, and at tailpipe locations. In addition, part of the raw exhaust was diluted and sampled for HC speciation. Canisters and sorbent membranes were used to collect volatile HCs and semi-volatile HCs, respectively. Di-nitrophenyl hydrazine (DNPH) cartridges were also used for collecting oxygenated species. Results showed overall lower HC emissions with the RON 80 E0 fuel compared to the RON 92 E10 fuel. For both fuels, the percentage of aromatic HCs was higher in the exhaust than in the fuels themselves. High engine-out aldehyde and ketone emissions were observed for both fuels. The reported HC speciation information can be useful for the development of a robust emission control system.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Detailed characterization of particulate matter emitted by lean-burn gasoline direct injection engine

This study presents detailed characterization of the chemical and physical properties of PM emitted by a 2.0L BMW lean-burn turbocharged GDI engine operated under a number of combustion strategies that include lean homogeneous, lean stratified, stoichiometric, and fuel rich conditions. We characterized PM number concentrations, size distributions, and the size, mass, compositions, and effective density of fractal and compact individual exhaust particles. For the fractal particles, these measurements yielded fractal dimension, average diameter of primary spherules, and number of spherules, void fraction, and dynamic shape factors as function of particle size. Overall, the PM properties were shown to vary significantly with engine operation condition. Lean stratified operation yielded the most diesel-like size distribution and the largest PM number and mass concentrations, with nearly all particles being fractal agglomerates composed of elemental carbon with small amounts of ash and organics. In contrast, stoichiometric operation yielded a larger fraction of ash particles, especially at low speed and low load. Three distinct forms of ash particles were observed, with their fractions strongly dependent on engine operating conditions: sub-50 nm ash particles, abundant at low speed and low load, ash-containing fractal particles, and large compact ash particles that significantly contribute to PM mass loadings

Environmental Molecular Sciences Laboratory↗

Advanced Collaborative Emissions Study (ACES)

The objective of the Advanced Collaborative Emissions Study (ACES) was to determine before widespread commercial deployment whether or not the new, energy-efficient, heavy duty diesel engines (2007 and 2010 EPA Emissions Standards Compliant) may generate anticipated toxic emissions that could adversely affect the environment and human health. ACES was planned to take place in three phases. In Phase 1, extensive emissions characterization of four production-intent prototype engine and control systems designed to meet 2007 standards for nitrogen oxides (NOx) and particulate matter (PM) was conducted at an existing emissions characterization facility: Southwest Research Institute (SwRI). One of the tested engines was selected (at random, after careful comparison of results) for health testing in Phase 3. In Phase 2, extensive emission characterization of three production-intent prototype engine and control systems meeting the 2010 standards (including more advanced NOx controls to meet the more stringent 2010 NOx standards) was conducted at the same test facility. In Phase 3, one engine/aftertreatment system selected from Phase 1 was further characterized during health effects studies (at an existing inhalation toxicology laboratory: Lovelace Respiratory Research Institute, [LRRI]) to form the basis of the ACES safety assessment. The Department of Energy (DOE) award provided funding for emissions characterization in Phases 1 and 2 as well as exposure characterization in Phase 3. The main health analyses in Phase 3 were funded separately and are not reported here.

54 ENVIRONMENTAL SCIENCES↗