Engineering topics
Publications and source records attributed to Stump, E. C., Jr..
After a review of some of the literature to point out limitations in fluoroether synthesis, current work is discussed that is designed to alleviate deficiencies in obtaining high molecular weights, and projections on some of the challenges for future work in this area are given. Several mechanisms are diagrammed. The work of Dr. Price is emphasized.
The reaction perfluorinated hydroxyl terminated polyether with diisocyanate to form polyurethane is discussed. Data are given on the resin's oxidation stability, chemical resistance, and low temperature flexibility.
New polyurethanes containing a high degree of fluorine atoms are reported. The presence of the fluorine atoms in the polyurethane resins provides material having good thermal stability and chemical resistance. These polyurethanes are derived from a new hydroxy-terminated perfluoro polyether. The hydroxy terminated material is reacted with a diisocyanate to produce the polyurethanes. The polyurethanes can be used to form seals, coatings, potting material, hoses and the like.
Chemical synthesis of hydroxy terminated perfluoro ethers as intermediates for highly fluorinated polyurethane resins
Fluorinated prepolymers are used to generate highly fluorinated polymers which possess most of the desirable properties of polytetrafluoroethylene, such as nonflammability and high corrosion resistance, while retaining good low temperature flexibility.
New polyurethanes, formed from a reaction of a prepolymer diol and a perfluorinated diisocyanate, are nonflammable and possess high corrosion resistance and good low temperature flexibility. Polymer hardness increases rapidly with increasing ratio of diisocaynate to diol, but its glass transition temperature is not adversely affected.
Hydroxy-terminated perfluoroethers and polyurethane resins derived from ethers have outstanding chemical resistance and good thermal properties. They can be used as potting compounds, coatings, and seals. The hydroxy-terminated ethers serve as intermediates in the synthesis of highly fluorinated elastomers and adhesives.