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Sullivan, C. W.

Publications and source records attributed to Sullivan, C. W..

Bromoalkane production by Antarctic ice algae

Ice microalgae, collected from the underside of annual sea ice in McMurdo Sound, Antarctica, were found to contain and release to seawater a number of brominated hydrocarbons. These included bromoform, dibromomethane, mixed bromochloromethanes, and methyl bromide. Atmospheric measurements in the McMurdo Sound vicinity revealed the presence of bromoform and methyl bromide in the lower atmosphere, with lowest concentrations inland, further indicating that biogenic activity in the Sound is a source of organic bromine gases to the Antarctic atmosphere. This may have important implications for boundary layer chemistry in Antarctica. In the Arctic, the presence of bromoform has been linked to loss of surface ozone in the spring. We report here preliminary evidence for similar surface ozone loss at McMurdo Station.

Sturges, W. T.↗

Coastal zone color scanner pigment concentrations in the southern ocean and relationships to geophysical surface features

Climatological data on the distribution of surface pigment fields in the entire southern ocean over a seasonal cycle are examined. The occurrence of intense phytoplankton blooms during austral summer months and during other seasons in different regions is identified and analyzed. The highest pigment concentrations are observed at high latitudes and over regions with water depths usually less than 600 m. Basin-scale pigment distribution shows a slightly asymmetric pattern of enhanced pigment concentrations about Antarctica, with enhanced concentrations extending to lower latitudes in the Atlantic and Indian sectors than in the Pacific sector. A general increase in pigment concentrations is evident from the low latitudes toward the Antarctic circumpolar region. Spatial relationships between pigment and archived geophysical data reveal significant correlation between pigment distributions and both bathymetry and wind stress, while general hemispheric scale patterns of pigment distributions are most coherent with the geostrophic flow of the Antarctic Circumpolar Current.

Comiso, J. C.↗

Particulate organic matter delta C-13 variations across the Drake Passage

Particulate organic matter (POM) was sampled during two cruise transects across the Drake Passage during March 1986 to investigate the unusual C-13 depletion in high-latitude Southern Ocean plankton. This POM delta C-13 transition from -23.2 o/oo at 53.3 deg S to values as low as -30.3 o/oo at above 62 deg S does not track previously reported abrupt changes in water chemistry and plankton species composition associated with the Polar Front Zone. The north-south isotopic trend is not accompanied by significant changes in POM carbon or nitrogen concentrations, or in POM C/N. Differences in plankton standing crop or biochemistry (e.g. lipid content) do not appear responsible for the isotopic trends observed. The latitudinal change in POM delta C-13 is highly correlated with water temperature and with the calculated concentration of CO2 (aq) at equilibrium with atmospheric CO2. These observations are consistent with the hypothesis that CO2 (aq) significantly influences POM delta C-13 in ocean surface waters.

Rau, G. H.↗

Satellite ocean color studies of Antarctic ice edges in summer and autumn

Large areas of elevated phytoplanton pigment concentration were observed using CZCS satellite data in the Weddell Sea marginal ice zone and adjacent regions during the austral summer-autumn transition. Pigment values higher in the south than in the north indicate that, besides the irradiance, there are other factors controlling spatial distributions of the phytoplankton pigment concentrations at this time. Low pigment concentrations (as in observations near the Greenwich meridian) may result from turbulent oceanic and atmospheric forcings during the early stage of sea ice development. The data indicate that the phytoplankton blooms are not only characteristic of the spring/summer period, but also extend into the austral autumn and may contribute significantly to regional productivity.

Comiso, J. C.↗

Phytoplankton standing crops within an Antarctic ice edge assessed by satellite remote sensing

The dynamic interactions between the pack-ice recession and the occurrence of ice blooms of phytoplankton in waters of the marginal ice zone within an Antarctic ice edge were investigated using CZCS and SMMR imageries from the Nimbus 7 satellite (September 16-December 17, 1983), together with in situ measurements of pigments and sea ice concentration carried out from November 7 to December 2. A substantial amount of spatial variability in pigment concentration was observed to occur along the ice edge in the Weddell Sea. The relationships among light, ice distribution, and vertical stability and their effects on observed spatial variations in phytoplankton biomass are discussed. The results of this investigation suggest that the retreat of ice provides an input of significant volumes of meltwater which creates vertical stability for a period necessary to permit growth and accumulation of phytoplankton.

Sullivan, C. W.↗

Satellite microwave and in situ observations of the Weddell Sea ice cover and its marginal ice zone

The radiative and physical characteristics of the Weddell Sea ice cover and its marginal ice zone are analyzed using multichannel satellite passive microwave data and ship and helicopter observations obtained during the 1983 Antarctic Marine Ecosystem Research. Winter and spring brightness temperatures are examined; spatial variability in the brightness temperatures of consolidated ice in winter and spring cyclic increases and decrease in brightness temperatures of consolidated ice with an amplitude of 50 K at 37 GHz and 20 K at 18 GHz are observed. The roles of variations in air temperature and surface characteristics in the variability of spring brightness temperatures are investigated. Ice concentrations are derived using the frequency and polarization techniques, and the data are compared with the helicopter and ship observations. Temporal changes in the ice margin structure and the mass balance of fresh water and of biological features of the marginal ice zone are studied.

Comiso, J. C.↗