Modular dimerization of organic radicals for stable and dense flow battery catholyte
Not provided.
Energy & Fuels↗
Engineering topics
Sullivan, Patrick
Publications and source records attributed to Sullivan, Patrick.
Towards Automated and High-Throughput Quantitative Sizing and Isotopic Analysis of Nanoparticles via Single Particle-ICP-TOF-MS
The work described herein assesses the ability to characterize gold nanoparticles (Au NPs) of 50 and 100 nm, as well as 60 nm silver shelled gold core nanospheres (Au/Ag NPs), for their mass, respective size, and isotopic composition in an automated and unattended fashion. Here, an innovative autosampler was employed to mix and transport the blanks, standards, and samples into a high-efficiency single particle (SP) introduction system for subsequent analysis by inductively coupled plasma–time of flight–mass spectrometry (ICP-TOF-MS). Optimized NP transport efficiency into the ICP-TOF-MS was determined to be >80%. This combination, SP-ICP-TOF-MS, allowed for high-throughput sample analysis. Specifically, 50 total samples (including blanks/standards) were analyzed over 8 h, to provide an accurate characterization of the NPs. This methodology was implemented over the course of 5 days to assess its long-term reproducibility. Impressively, the in-run and day-to-day variation of sample transport is assessed to be 3.54 and 9.52% relative standard deviation (%RSD), respectively. The determination of Au NP size and concentration was of <5% relative difference from the certified values over these time periods. Isotopic characterization of the 107 Ag/ 109 Ag particles (n = 132,630) over the course of the measurements was determined to be 1.0788 ± 0.0030 with high accuracy (0.23% relative difference) when compared to the multi-collector–ICP-MS determination.
36 MATERIALS SCIENCE↗
AmeriFlux US-KPL Lily Lake Fen
This is the AmeriFlux version of the carbon flux data for the site US-KPL Lily Lake Fen. Site Description - fen
Sullivan, Patrick↗
Ultrasonic Jet Bat Deterrent System Advancement
General Electric Renewable Energy (GE) and the Department of Energy (DOE) worked to develop a project with an objective to increase confidence in acoustic ultrasonic bat deterrent technologies in wind turbines, by mitigating stakeholder investment risks that currently hinder the adoption of deterrent technologies. Many wind turbine sites utilize a bat conservation plan that curtail wind turbines and stop energy production. Curtailment is a known bat impact mitigation solution that has an history of environmental regulatory acceptance. To help support a solution that allows for simultaneous bat conservation and energy production with regulatory acceptance of acoustic bat deterrents, GE proposed a study to compare four treatments: control (no curtailment or deterrent), deterrent only, deterrent plus curtailment, and curtailment only. The concept was to provide a direct comparison of bat deterrent and curtailment effectiveness within the same wind farm and bat migration season. This comparison was intended to advocate for the adoption of bat deterrents with a large-scale field study by addressing customer concerns on regulatory acceptance of deterrents. The study was to be hosted at a forested habitat site during a bat migration season, by Stony Creek Energy, LLC (SCE), the owner of the Orangeville Wind Farm (OWF) in the state of New York. Included was a behavioral study plan with two turbines to monitor bat flight paths with thermal imaging cameras.
17 WIND ENERGY↗