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Summers, Michael E.

Publications and source records attributed to Summers, Michael E..

Sulfur Dioxide and the Production of Sulfuric Acid on Present-Day and Early Mars: Implications for the Lack of Detected Carbonates on the Surface

In the early history of Mars, volcanic activity associated with the formation of the Tharsis ridge produced a very large amount of atmospheric SO2--on the order of a bar of atmospheric SO2. In the present-day atmosphere of Mars, the lifetime of SO2 is relatively short with a lifetime of less than a day. The short lifetime of SO2 in the present Mars atmosphere makes the production of significant levels of H2SO4 very difficult since the SO2 may be destroyed by various chemical and photochemical processes before the SO2 can be converted to H2SO4. However, photochemical calculations performed and described here, indicate that enhanced atmospheric levels of CO2 in the early atmosphere of Mars resulted in a significantly enhanced atmospheric lifetime for SO2 up to several years. With a significantly enhanced atmospheric lifetime, SO2 could readily form large amounts of H2SO4, which precipitated out of the atmosphere in the form of droplets. The precipitated H2SO4 then reacted with potential surface carbonates, destroying the carbonates and resulting in the abundant and widespread distribution of sulfates on the surface of Mars as detected by recent Mars missions.

Levine, Joel S.↗

Upper limit on Titan's atmospheric argon abundance

An analysis is conducted on the Voyager 1 UV Spectrometer solar-occultation data and a Titan flyby spectrum of the north polar region dayglow, in order to infer the tropopausal Ar mixing ratio's upper limit as a function of the CH4 mixing ratio, f(CH4). The mole-fraction upper limit of tropopausal Ar mixing ratio ranges from 0.01 to 0.1 at f(CH4) of 0.026 to as low as 0.08 at f(CH4) of 0.05. Since the best fits to the solar occultation data require f(CH4) of more than 0.26, the Ar mixing ratio must be lower than 0.1.

Strobel, Darrell F.↗

Titan's upper atmosphere - Structure and ultraviolet emissions

An analysis is conducted of the composition and thermal structure of Titan's upper atmosphere, and the relative importance of airglow-excitation processes, on the basis of Voyager 1 UV spectrometer data for solar occultation and airglow. Attention is also given to the Smith et al. (1982) optical depth profiles for the evening terminator, entrance occultation, and asymptotic temperature. A magnetospheric power input figure is obtained that is 25 times smaller than the initial estimate by Strobel and Shemansky (1982).

Strobel, Darrell F.↗

On the thermal structure of Triton's thermosphere

The analysis of the Voyager 2 Ultraviolet Spectrometer solar occultation data obtained at Triton is consistent with a spherically symmetric, isothermal thermosphere above 400 km at T(infinity) = 96 K. A detailed calculation of energy loss processes in a pure N2 atmosphere indicates that solar heating, with calculated T(infinity) = 70 K, is insufficient to account for the inferred T(infinity) = 96 K. The magnetosphere must deposit twice as much power as the sun to heat the thermosphere to 96 K and generate the observed N2 tangential column densities above 450 km. The thermal escape of H and N atoms and the downward diffusion of N atoms to recombine below 130 km results in local ionospheric heating efficiency of 24 percent. An upper limit on the tropopause CO mixing ratio of 2 x 10 exp -4 is inferred in the absence of aerosol heating to balance its efficient cooling by LTE rotational line emission.

Stevens, Michael H.↗

Triton's atmosphere - A source of N and H for Neptune's magnetosphere

Mass loading of the Neptunian magnetosphere occurs primarily by thermal escape of H, H2, and N from Triton's upper atmosphere. The global escape rate of hydrogen is about 7 x 10 exp 25/s, determined by the global average methane photolysis rate, whereas the escape rate of nitrogen for the present preferred model is about 3.4 x 10 exp 25/s, and is controlled by the global and orbital average energy deposition rate due to precipitating magnetospheric electrons. The escape rate of H(+) and N(+) is less than 4 percent of the neutral escape rate and implies that mass loading of the Neptunian magnetosphere is not localized to Triton's corona. The ratio of hydrogen to nitrogen escape rates for the present preferred model is about 2:1, comparable to the H(+)/N(+) abundance ratio inferred for Neptune's magnetosphere.

Summers, Michael E.↗

Nitrogen airglow sources - Comparison of Triton, Titan, and earth

The individual contributions of direct solar excitation, photoelectron excitation, and magnetospheric electron excitation of Triton and Titan airglow observed by the Voyager Ultraviolet Spectrometer (UVS) are quantified. The principal spectral features of Triton's airglow are shown to be consistent with precipitation of magnetospheric electrons with power dissipation about 500 million W. Solar excitation rates of the dominant N2 and N(+) emission features are factors of 2-7 weaker than magnetospheric electron excitation. On Titan, the calculated disk center and bright limb N(+) 1085 A intensities due to solar excitation agree with observed values, while the 970 A feature is mostly N21 c5 band emission. The calculated LBH intensity by photoelectrons suggests that magnetospheric electrons play a minor role in Titan's UV airglow. On earth, solar/photoelectron excitation explains the observed N(+) 1085 A and LBH intensites and accounts for only 40 percent of the N(+) 916 A intensity.

Strobel, Darrell F.↗

Magnetospheric interaction with Triton's ionosphere

The large electron densities measured by the Voyager radio occultation experiment are attributed to the precipitation of magnetospheric electrons with energy above 10 keV. Because the ionospheric electric Pedersen conductivity of Triton is about 10,000-20,000 mho and the Alfven conductance is about 3.5 mho, direct convective flow of plasma into the essentially infinitely conducting ionosphere is negligible. Magnetospheric electrons are transported to Triton's ionopause by curvature drift as a result of weak magnetic field line draping in a sub-Alfvenic plasma interaction with Triton. At the ionopause energetic electrons have a high probability of elastic and inelastic scattering and precipitate into the upper atmosphere. The average power dissipation is estimated to be about (2 - 3) x 10 to the 8th W.

Strobel, Darrell F.↗

The photochemistry of methane in the atmosphere of Triton

The model of Summers and Strobel (1989) for photochemical reactions in the Uranus atmosphere was modified and used for quantitative calculations of methane in the atmosphere of Triton. The principal adjustable parameters in the new model are the surface CH4 concentrations and the vigor of vertical mixing in Triton's lower atmosphere. It is shown the rate of methane photolysis that was calculated is sufficient to generate a smog of condensed C2H2, C2H4, C2H6, and C4H2 particles in the lowest 30 km of Triton's atmosphere, with an optical depth consistent with the Voyager imaging results.

Strobel, Darrell F.↗

The seasonal variation of water vapor and ozone in the upper mesosphere - Implications for vertical transport and ozone photochemistry

This paper reviews the data base supplied by ground-based microwave measurements of water vapor in the mesosphere obtained in three separate experiments over an eight-year period. These measurements indicate that the seasonal variation of water vapor in the mesosphere is dominated by an annual component with low values in winter and high values in summer, suggesting that the seasonal variation of water vapor in the mesosphere (below 80 km) is controlled by advective rather than diffusive processes. Both the seasonal variation and the absolute magnitude of the water vapor mixing ratios obtained in microwave measurements were corroborated by measurements obtained in the Spacelab GRILLE and ATMOS experiments, and were found to be consistent with several recent mesospheric dynamics studies.

Bevilacqua, Richard M.↗

Photochemistry of the atmosphere of Uranus

A detailed one-dimensional photochemical model incorporating vertical transport by eddy and molecular diffusion is used to study the importance of chemical and physical processes that control the hydrocarbon abundances in the stratosphere of Uranus. The study includes updated photochemical reaction rates and photolysis branching ratios; explicit calculation of the condensation rate of condensing species; and appropriate boundary conditions at the tropopause. It is found that the basic photochemical process generally produces low net conversion efficiencies of methane to higher hydrocarbons. However, even with these low efficiencies, the total condensation rate, which represents the net rate of conversion of methane to hydrocarbons, is roughly 2 x 10 to the -16th g/cm sec, in agreement with the upper range of the low condensation rate for the production of the stratospheric aerosol layer as determined by Pollack et al. (1987). Furthermore, a range of vertical transport rates is required to separately match the observational constraints on hydrocarbon abundances. The solar reflection data refer to the sunlit polar region of Uranus and require an eddy diffusion coefficient of K approx. = 50 sq cm/sec for globally averaged insolation or K approx = 1500 (Nh/N) exp 1/2 for overhead sun. The Voyager 2 Utraviolet Spectrometer solar occultation data refer to the equatorial regions, thus implying a large latitudinal gradient in stratospheric hydrocarbon abundance.

Summers, Michael E.↗

Vertical constituent transport in the mesosphere

Ground-based microwave spectroscopy measurements of mesospheric CO and H2O vertical mixing ratio profiles are used to infer vertical mixing rates in the upper mesosphere. The CO and H2O data consistently imply vertical eddy diffusion coefficients in the 70- to 85-km region of 100,000-200,000 sq cm/s during spring through summer at midlatidues. Although chemical acceleration of vertical transport is substantial for O and O3, below the mesopause, the divergences of their associated fluxes are modest, with at most a factor of 2 effect on the concentrations of O and O3 for measured variability in gravity wave activity. Comparison of Solar Mesosphere Explorer (SME) O3 data with model results reinforces the conclusions of slow vertical mixing in the upper mesosphere as a consequence of the reduced HO(x) catalytic loss of odd oxygen. The changes in chemical rate constants recommended by Rusch and Eckman (1985), in conjunction with slow vertical mixing, yield good agreement with SME O3 data. The slow vertical mixing deduced in this study is consistent with upper limits obtained from studies of the mesospheric heat budget and could be construed as evidence for an advectively controlled mesosphere. A comparison of the vertical eddy diffusion coefficients for momentum stresses, constituent transport, and heat transport suggests that the eddy Prandtl number must be of order 10.

Strobel, Darrell F.↗