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Tang, Wei

Publications and source records attributed to Tang, Wei.

At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

The application of macroscopic flakes for Fe-6.5%Si bulk magnetics with superior magnetic properties

Inductors are used in power electronics to convert current to different frequency and voltage. They are used extensively from where power is generated all the way to electric vehicles and portable electronic devices. The soft magnetic materials used in the inductors is critical for the performance of the inductors. Currently, a majority of the inductor uses powder core. The use of powder is not ideal as the 3D granule powders generate large demagnetization field working against the applied field, resulting in reduced permeability and efficiency. In this paper, 2D flakes were used to replace the 3D granules as the feedstock for fabricating inductor core. The crystalline Fe-Si based crystalline soft magnetic material in the form of flakes approximately 0.1mm thick, 1mm long and 2mm wide were prepared via melt spinning. The flakes were then coated with insulating materials before compacted into a toroid. The effect of coating thickness and concentration on magnetic properties of the toroidal sample are studied. It was also found that the magnetic cores made by flakes surpass the cores made by same size powder with larger permeability and lower iron losses.

Fe-6.5%Si Steel↗
DOE OSTI2018

Complete Status Report Documenting the Development of Friction Stir Welding for Producing a Butt Joint in Thin Wall Tubing of ODS Alloys

A challenging attempt using friction stir welding to produce a butt joint between two 1.0 mm thick plates of 14YWT was nearly successful. The modified tool pin mostly penetrated the thickness of the adjoined thin plate samples resulting in a small blunt notch on the bottom surface of the butt joint. A bend occurred in the thin plate sample due to formation of stresses from clamping the thin plate sample during FSW. The peak displacement of the bend occurred along the center line of the butt joint. The weld zone showed good microstructure mixing with some flashing mostly on the retreating side that suggested excess heat input by friction between the traveling and spinning tool pin and thin plates of 14YWT. Neutron diffraction experiments were performed on the bent sample of 14YWT to measure the residual stresses in the butt joint on the HB-2B beam line at the Neutron Residual Stress Facility at HFIR. However, the neutron scattering to background noise ratio was very low during data acquisition. Measurements of lattice strains were obtained in the rolling (RD) and normal (ND) directions but not in the extrusion direction (ED) of the thin plate sample. Unfortunately, the quality of the data was not sufficient for determining the residual stresses in the butt joint. From the previous neutron scattering experiments conducted on four hot rolled plates (R1, R2, R3 and R4) of 14YWT, the residual stresses were calculated from lattice strain data and plotted in 2-D color contour maps for ED, RD and ND. The results showed variations in the magnitude and spatial position of residual stresses in the microstructure of the four plates. The magnitude in residual stresses in ED and RD increased gradually with increasing rolling deformation for R1 (50%) to R2 (76%), followed by larger increases in R3 (89%) and R4 (95%). The maximum peaks in residual stresses for R4 was ~710-730 MPa in ED and RD. The residual stresses in ND were below ~300 MPa for each of the 4 rolled plates, with a maximum residual stress in R4 (95%) of ~400 MPa. These results indicated that significant residual stresses representing ~57% of the yield stress of 14YWT (SM13) had accumulated in the 14YWT plate after hot rolling to the 1 mm thickness, which was used in the FSW experiments. The microstructure analysis of the 1.0 mm thick plate of 14YWT containing the butt joint produced by FSW revealed significant changes in the grain structure and texture between the unaffected zone (UZ) of the rolled plate and the butt joint weld. In the UZ, the grains were severely elongated after 95% deformation and mainly possessed the {101} texture component in the ED. Two predominant grain misorientation angles were observed: one consisting of small misorientations of <5º between highly elongated grains and the other consisting of large misorientations of >15º in pockets of small grains that might have formed by dynamic recrystallization processes during rolling of the plate at 1000ºC. The morphology and texture of grains in the heat affected zone (HAZ) were similar to those in UZ, except the grains had coarsened due to excess heat input during FSZ. A population of pores formed and the grains both coarsened and changed to isotropic morphology in the microstructure of the butt joint on both the advancing and retreating sides. The texture of grains in both regions were randomly orientated between the 3 poles {001}, {101} and {111}. The main difference in texture of grains between the advancing side and retreating side was with the misorientation angles of neighboring grains. Most of the grains in the advancing side had misorientation angles of >5º indicating that these grains experienced recrystallization. On the retreating side, areas containing larger grains showed high misorientation angles of >15º compared to areas appearing as bands of grains with misorientation angles of <5º and between 5º-15º. Numerous small pockets of grains with low misorientation angles of <5º were distributed in the microstructure among the grains showing high misorientation angles of >15º. It was determined that the grains associated with low misorientation angles contained sub-grain structures, which was consistent with both recrystallization and recovery mechanisms for grains located on the retreating side of the butt joint. These results demonstrate the complex microstructure that evolves in the microstructure of 14YWT resulting from the input of high temperatures and severe deformations during FSW.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Light Water Reactor Sustainability Program: Complete Report on Development of Weld Repair Technology

This report summarizes recent post-welding activities on irradiated alloys at the Irradiated Materials Examination and Testing (IMET) and the Low Activation Materials Development and Analysis (LAMDA) facilities at Oak Ridge National Laboratory. Equipment and capabilities were developed jointly by the U.S. Department of Energy, Office of Nuclear Energy, Light Water Reactor Sustainability Program, the Electric Power Research Institute, Long Term Operations Program (and the Welding and Repair Technology Center), and Oak Ridge National Laboratory. The preliminary helium measurements and microstructure characterization revealed successful advanced laser and friction stir welding procedures on high helium content stainless steel. The significant, on-going effort to weld irradiated alloys with high helium concentrations and comprehensively analyze the results will eventually yield validated repair techniques and guidelines for use by the nuclear industry in extending the operational lifetimes of nuclear power plants. The nuclear industry welding workshop was successfully held at ORNL on September 18 – 19, 2018.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2018

On spinodal decomposition in alnico - A transmission electron microscopy and atom probe tomography study

Here, alnico is a prime example of a finely tuned nanostructure whose magnetic properties are intimately connected to magnetic annealing (MA) during spinodal transformation and subsequent lower temperature annealing (draw) cycles. Using a combination of transmission electron microscopy and atom probe tomography, we show how these critical processing steps affect the local composition and nanostructure evolution with impact on magnetic properties. The nearly 2-fold increase of intrinsic coercivity (H ci ) during the draw cycle is not adequately explained by chemical refinement of the spinodal phases. Instead, increased Fe-Co phase (α 1 ) isolation, development of Cu-rich spheres/rods/blades and additional α 1 rod precipitation that occurs during the MA and draw, likely play a key role in Hci enhancement. Chemical ordering of the Al-Ni-phase (α 2 ) and formation of Ni-rich (α 3 ) may also contribute. Unraveling of the subtle effect of these nano-scaled features is crucial to understanding on how to improve shape anisotropy in alnico magnets.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Report on the Progress of Weld Development of Irradiated Materials at the Oak Ridge National Laboratory

This report summarizes recent welding activities on irradiated alloys in the advanced welding facility at the Radiochemical Engineering Development Center of Oak Ridge National Laboratory and the development of post-weld characterization capabilities and procedures that will be critical for assessing the ability of the advanced welding processes housed within the facility to make successful repairs on irradiated alloys. This facility and its capabilities were developed jointly by the U.S. Department of Energy, Office of Nuclear Energy, Light Water Reactor Sustainability Program and the Electric Power Research Institute, Long Term Operations Program (and the Welding and Repair Technology Center), with additional support from Oak Ridge National Laboratory. The significant, on-going effort to weld irradiated alloys with high Helium concentrations and comprehensively analyze the results will eventually yield validated repair techniques and guidelines for use by the nuclear industry in extending the operational lifetimes of nuclear power plants.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2018

ADVANCED WELDING TECHNOLOGY DEVELOPMENT FOR NUCLEAR REACTOR REPAIR

Welding is widely used for repair, maintenance, and upgrade of nuclear reactor components. As a critical technology for supporting the extension of nuclear power plant service lifetimes beyond 60 years, there has been an industry need in further developing welding technology for highly irradiated materials. During welding of irradiated materials, Helium, which is a transmutation byproduct from Boron and Nickel contained in the structural alloys, can coalesce into bubbles along grain boundaries in the material under driving forces of high temperature and thermal tensile stress. This leads to embrittlement and potential intergranular cracking in the Heat Affected Zone (HAZ) of the weld. In this paper, irradiated 304 stainless steel coupons containing 5, 10 and 20 ppm Boron prior to radiation were successfully welded by advanced laser beam welding (LBW) and friction stir welding (FSW). Facilities and welding machine design, welding processes development, cold material welded joints evaluation, process safety control and documentation, and irradiated material welding are discussed. Both laser and friction stir welded coupons of the irradiated material exhibited high welding quality and surface finish. No Helium induced welding defects were observed on the weld surfaces or adjacent base metals.

Tang, Wei↗
DOE OSTI2018

Effect of cooling rate on the magnetic and mechanical properties of melt spun Fe-6.5 wt.% electric steel

The superior magnetic and electric properties of 6.5 wt.% high silicon steel may improve efficiency and power density of electric machines. However, the brittleness due to the formation of B2 and D03 ordered phases make it difficult for the application of high silicon steel. These ordered phases can be fully or partially suppressed by rapid cooling. However, further study is needed to understand the effect of cooling rate on magnetic and mechanical properties. By tuning the melt spinning wheel speed from 1m/s to 30m/s, varying degrees of cooling rate were achieved. The obtained ribbons with various degree of ordering were tested for mechanical, magnetic and electrical properties. The correlation between the cooling rate, ordering, and physical properties are established.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Controllable deuteration of halogenated compounds by photocatalytic D2O splitting

Deuterium labeling is of great value in organic synthesis and the pharmaceutical industry. However, the state-of-the-art C–H/C–D exchange using noble metal catalysts or strong bases/acids suffers from poor functional group tolerances, poor selectivity and lack of scope for generating molecular complexity. Herein, we demonstrate the deuteration of halides using heavy water as the deuteration reagent and porous CdSe nanosheets as the catalyst. The deuteration mechanism involves the generation of highly active carbon and deuterium radicals via photoinduced electron transfer from CdSe to the substrates, followed by tandem radicals coupling process, which is mechanistically distinct from the traditional methods involving deuterium cations or anions. Our deuteration strategy shows better selectivity and functional group tolerances than current C–H/C–D exchange methods. Extending the synthetic scope, deuterated boronic acids, halides, alkynes, and aldehydes can be used as synthons in Suzuki coupling, Click reaction, C–H bond insertion reaction etc. for the synthesis of complex deuterated molecules.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2017

Texture development and coercivity enhancement in cast alnico 9 magnets

The effect of Y addition and magnetic field on texture and magnetic properties of arc-melted alnico 9 magnets has been investigated. Small additions of Y (1.5 wt.%) develop a (200) texture for the arc-melted alnico 9 magnet. Such a texture is hard to form in cast samples. To achieve this goal, we set up a high-field annealing system with a maximum operation temperature of 1250 °C. This system enabled annealing in a field of 45 kOe with subsequent draw annealing for the solutionized buttons; we have been able to substantially increase remanence ratio and coercivity, from 0.70 and 1200 Oe for the Y-free alnico 9 to 0.90 and 1400 Oe for the Y-doped alnico 9, respectively. A high energy product of 7.3 MGOe has been achieved for the fully heat-treated Y-doped alnico 9. The enhancement of coercivity is believed to arise from the introduction of magnetocrystalline anisotropy from 80 nm Y 2 Co 17 -type grains, which are exchange-coupled to the main-phase alnico rods.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Effect of wheel speed on magnetic and mechanical properties of melt spun Fe-6.5 wt.% Si high silicon steel

Here, Fe-Si electric steel is the most widely used soft magnetic material in electric machines and transformers. Increasing the silicon content from 3.2 wt.% to 6.5 wt.% brings about large improvement in the magnetic and electrical properties. However, 6.5 wt.% silicon steel is inherited with brittleness owing to the formation of B2 and D0 3 ordered phase. To obtain ductility in Fe-6.5wt.% silicon steel, the ordered phase has to be bypassed with methods like rapid cooling. In present paper, the effect of cooling rate on magnetic and mechanical properties of Fe-6.5wt.% silicon steel is studied by tuning the wheel speed during melt spinning process. The cooling rate significantly alters the ordering and microstructure, and thus the mechanical and magnetic properties. X-ray diffraction data shows that D0 3 ordering was fully suppressed at high wheel speeds but starts to nucleate at 10m/s and below, which correlates with the increase of Young’s modulus towards low wheel speeds as tested by nanoindentation. The grain sizes of the ribbons on the wheel side decrease with increasing wheel speeds, ranging from ~100 μm at 1m/s to ~8 μm at 30m/s, which lead to changes in coercivity.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Evaluating the Potential for Remote In-Process Monitoring of Tool Wear in Friction Stir Welding of Stainless Steel

A wear characterization study was performed to determine the useful lifetime of Polycrystalline Cubic Boron Nitride tooling for the friction stir welding (FSW) of stainless steel samples in support of a nuclear repair welding research and development program. In-situ and ex-situ laser profilometry were utilized as primary methods of monitoring tool geometry degradation, and volumetric defects were detected through both non-destructive and destructive techniques, as repeated welds of a standard sample configuration were produced. The spectral content of weld forces were examined to search for indications of evolving material flow conditions, caused by significant tool wear, that would result in the formation of defects, and an artificial neural network was trained and evaluated as a means of automatically detecting these conditions. Here, the resulting performance constituted a successful demonstration of in-process monitoring of tool wear and weld quality in FSW of a high melting temperature, high hardness material.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Novel mechanisms for solid-state processing and grain growth with microstructure alignment in alnico-8 based permanent magnets

An estimated 750,000 new hybrid electric and plug-in battery vehicles, most with permanent magnet synchronous alternating current (PMAC) drive motors, took to the road in 2016 alone. Accompanied by 40% year over year growth in the EV market significant challenges exist in producing large quantities of permanent magnets (on the order of tens of millions) for reliable, low-cost traction motors [IE Agency, Energy Technology Perspectives (2017)]. Since the rare earth permanent magnet (REPM) market is essentially 100% net import reliant in the United States and has proven to have an unstable cost and supply structure in recent years, a replacement RE-free PM material must be designed or selected, fully developed, and implemented. Alnico, with its high saturation magnetization and excellent thermal stability, appears to be uniquely suited for this task. Further, while alnico typically has been considered a relatively low coercivity hard magnet, strides have been made to increase the coercivity to levels suitable for traction drive motors [W Tang, IEEE Trans. Magn., 51 (2015)]. If a simple non-cast approach for achieving near [001] easy axis grain aligned permanent magnets can be found, this would allow massproduced final-shape anisotropic high energy product magnets suitable for usage in compact high RPM rotor designs. Therefore, a powder metallurgical approach is being explored that uses classic compression molding with “de-bind and sinter” methods, where a novel applied uniaxial loading, and an applied magnetic field may create final-shape magnets with highly textured resulting microstructures by two different mechanisms. Results indicate a positive correlation between applied uniaxial load and resulting texture (Fig. 1), along with benefits from using an applied magnetic field for improved texture, as well. Lastly, the apparent mechanisms and resulting properties will be described using closed loop hysteresisgraph measurements, EBSD orientation mapping, and high-resolution SEM.

42 ENGINEERING↗
DOE OSTI2017

Cluster-Expansion Model for Complex Quinary Alloys: Application to Alnico Permanent Magnets

An accurate and transferable cluster-expansion model for complex quinary alloys is developed. Lattice Monte Carlo simulation enabled by this cluster-expansion model is used to investigate temperature-dependent atomic structure of alnico alloys, which are considered as promising high-performance non-rare-earth permanent-magnet materials for high-temperature applications. The results of the Monte Carlo simulations are consistent with available experimental data and provide useful insights into phase decomposition, selection, and chemical ordering in alnico. The simulations also reveal a previously unrecognized D 0 3 alloy phase. This phase is very rich in Ni and exhibits very weak magnetization. In conclusion, manipulating the size and location of this phase provides a possible route to improve the magnetic properties of alnico, especially coercivity.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Complete Report on the Development of Welding Parameters for Irradiated Materials

The advanced welding facility at the Radiochemical Engineering Development Center of Oak Ridge National Laboratory, which was conceived to enable research and development of weld repair techniques for nuclear power plant life extension, is now operational. The development of the facility and its advanced welding capabilities, along with the model materials for initial welding trials, were funded jointly by the U.S. Department of Energy, Office of Nuclear Energy, Light Water Reactor Sustainability Program, the Electric Power Research Institute, Long Term Operations Program and the Welding and Repair Technology Center, with additional support from Oak Ridge National Laboratory. Welding of irradiated materials was initiated on November 17, 2017, which marked a significant step in the development of the facility and the beginning of extensive welding research and development campaigns on irradiated materials that will eventually produce validated techniques and guidelines for weld repair activities carried out to extend the operational lifetimes of nuclear power plants beyond 60 years. This report summarizes the final steps that were required to complete weld process development, initial irradiated materials welding activities, near-term plans for irradiated materials welding, and plans for post-weld analyses that will be carried out to assess the ability of the advanced welding processes to make repairs on irradiated materials.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Single crystalline ZnO radial homojunction light-emitting diodes fabricated by metalorganic chemical vapour deposition

ZnO radial p–n junction architecture has the potential for forward-leap of light-emitting diode (LED) technology in terms of higher efficacy and economical production. Here, we report on ZnO radial p–n junction-based light emitting diodes prepared by full metalorganic chemical vapour deposition (MOCVD) with hydrogen-assisted p-type doping approach. The p-type ZnO(P) thin films were prepared by MOCVD with the precursors of dimethylzinc, tert-butanol, and tertiarybutylphosphine. Controlling the precursor flow for dopant results in the systematic change of doping concentration, Hall mobility, and electrical conductivity. Moreover, the approach of hydrogen-assisted phosphorous doping in ZnO expands the understanding of doping behaviour in ZnO. Ultraviolet and visible electroluminescence of ZnO radial p–n junction was demonstrated through a combination of position-controlled nano/microwire and crystalline p-type ZnO(P) radial shell growth on the wires. Lastly, the reported research opens a pathway of realisation of production-compatible ZnO p–n junction LEDs.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Compression Molding and Novel Sintering Treatments for Alnico Type-8 Permanent Magnets in Near-Final Shape with Preferred Orientation

We present economic uncertainty in the rare earth (RE) permanent magnet marketplace, as well as in an expanding electric drive vehicle market that favors permanent magnet alternating current synchronous drive motors, motivated renewed research in RE-free permanent magnets like “alnico,” an Al-Ni-Co-Fe alloy. Thus, high-pressure, gas-atomized isotropic type-8H pre-alloyed alnico powder was compression molded with a clean burn-out binder to near-final shape and sintered to density >99% of cast alnico 8 (full density of 7.3 g/cm 3 ). To produce aligned sintered alnico magnets for improved energy product and magnetic remanence, uniaxial stress was attempted to promote controlled grain growth, avoiding directional solidification that provides alignment in alnico 9. Lastly, successful development of solid-state powder processing may enable anisotropically aligned alnico magnets with enhanced energy density to be mass-produced.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Simulation of alnico coercivity

Micromagnetic simulations of alnico show substantial deviations from Stoner-Wohlfarth behavior due to the unique size and spatial distribution of the rod-like Fe-Co phase formed during spinodal decomposition in an external magnetic field. Furthemore, the maximum coercivity is limited by single-rod effects, especially deviations from ellipsoidal shape, and by interactions between the rods. In both the exchange interaction between connected rods and magnetostatic we consider the interaction between rods, and the results of our calculations show good agreement with recent experiments. Unlike systems dominated by magnetocrystalline anisotropy, coercivity in alnico is highly dependent on size, shape, and geometric distribution of the Fe-Co phase, all factors that can be tuned with appropriate chemistry and thermal-magnetic annealing.

36 MATERIALS SCIENCE↗