Columbia CO survey - Molecular clouds and spiral structure
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Cohen, R. S.↗
Engineering topics
Thaddeus, P.
Publications and source records attributed to Thaddeus, P..
Interstellar methyl mercaptan
Methyl mercaptan (CH3SH) has been identified in Sgr B2 from observations of six lines in its millimeter-wave spectrum. The CH3SH rotational temperature and column density in Sgr B2 are T(rot) = 9 plus or minus 3 K and N = 1.5 plus or minus 0.2 x 10 to the 14th per sq cm, respectively. The CH3SH/CH3OH ratio is apparently not greatly different from the cosmic S/O ratio.
Linke, R. A.↗
Interstellar isothiocyanic acid
Isothiocyanic acid (HNCS) has been identified in Sgr B2 from millimeter-wave spectral line observations. We have definitely detected three rotational lines, and have probably detected two others. The rotational temperature of HNCS in Sgr B2 is 14 plus or minus 5 K, its column density is 2.5 plus or minus 1.0 x 10 to the 13th per sq cm, and its abundance relative to HNCO is consistent with the cosmic S/O ratio, 1/42.
Frerking, M. A.↗
Detection of HC/O-18//plus/ in Sagittarius B2
Line emission at 85.1 GHz attributed to the J equals 1-0 rotational transition of the formyl ion HC(O-18)(plus) has been detected in Sgr B2 (OH). The double isotopic ratio (O-16/O-18)/(C-12/C-13) in the formyl ion in Sgr B2 is estimated to be in the range 5-10, hence within a factor 2 of the terrestrial value of 5.5. This determination implies that the C-13/C-12 ratio near the galactic center does not differ greatly from that in local molecular clouds.
Guelin, M.↗
An out-of-plane CO survey of the first galactic quadrant
An out-of-plane survey of 2.6-mm CO emission from the first quadrant of the galactic disk carried out at Columbia University with a 1.2-meter telescope is reported. Longitude-velocity diagrams for the galactic plane and for latitude b + or - 0.5 deg are given. The half-thickness of the CO plane, its displacement, and the emissivity of CO, all as functions of galactic radius, are shown. New results are generally consistent with those reported before.
Cohen, R. S.↗
Molecular clouds in the vicinity of W3, W4, and W5
An extensive and well-sampled map of CO emission over the entire complex consisting of the H II regions W3 (IC 1795), W4 (IC 1805), and W5 (IC 1848) is presented which was obtained at an angular resolution of 8 arcmin. A contour map of integrated (C-12)O emission overlaid on the corresponding fields of the Palomar Sky Survey is provided along with a map of the peak (C-12)O brightness temperature for the W3-W4 region. Two large cloud complexes are found within the area surveyed, and three bright CO condensations are resolved in the peak-temperature map. Column densities and masses are estimated for the cloud complex in the W3-W4 region, and it is suggested that the ionization front of W4 and the molecular cloud are interacting physically. Two condensations associated, respectively, with W3 and W3 (OH) are shown to contain unmistakable evidence for recent OB star formation.
Lada, C. J.↗
Detection of the C4H radical toward IRC plus 10216
Four emission doublets in the millimeter-wave spectrum of IRC plus 10216 are identified as successive rotational transitions of the linear butadiynyl radical (C4H). The identifications are made on the basis of the agreement to within about 1 part in 1000 between the observed rotation constant of C4H and the value obtained from a Hartree-Fock calculation. A rough estimate of the amounts of C4H and C3N in the molecular envelope of IRC plus 10216 is given. The results indicate that C4H seems to be the more abundant species by about a factor of 4.
Guelin, M.↗
Detection of interstellar ethyl cyanide
Twenty-four millimeter-wave emission lines of ethyl cyanide (CH3CH2CN) have been detected in the Orion Nebula (OMC-1) and seven in Sgr B2. To derive precise radial velocities from the astronomical data, a laboratory measurement of the rotational spectrum of ethyl cyanide has been made at frequencies above 41 GHz. In OMC-1, the rotational temperature of ethyl cyanide is 90 K (in good agreement with other molecules), the local-standard-of-rest radial velocity is 4.5 + or - 1.0 km/s (versus 8.5 km/s for most molecules), and the column density is 1.8 by 10 to the 14th power per sq cm (a surprisingly high figure for a complicated molecule). The high abundance of ethyl cyanide in the Orion Nebula suggests that ethane and perhaps larger saturated hydrocarbons may be common constituents of molecular clouds and have escaped detection only because they are nonpolar or only weakly polar.
Johnson, D. R.↗
An out-of-plane galactic carbon monoxide survey
Galactic CO line emission at 115 GHz has been surveyed in the region from 15 to 60 deg galactic longitude and from about -1.5 to 1.5 deg latitude. In addition to confirming the findings of previous in-plane surveys that galactic CO emission is concentrated in a ring 6 kpc in radius, a fit of a cylindrically symmetric galactic model to the observational data has provided a determination of the thickness of this molecular ring and its displacement from the conventional galactic plane, both as functions of galactocentric distance. The average half-thickness at half-maximum of the molecular ring is 59 pc, and the average displacement of the ring with respect to the galactic equatorial plane is -40 pc.
Cohen, R. S.↗
Indirect observation of unobservable interstellar molecules
It is suggested that the abundances of neutral nonpolar interstellar molecules unobservable by radio astronomy can be systematically determined by radio observation of the protonated ions. As an example, observed N2H(+) column densities are analyzed to infer molecular nitrogen abundances in dense interstellar clouds. The chemistries and expected densities of the protonated ions of O2, C2, CO2, C2H2, and CH4 are then discussed. Microwave transition frequencies for HCO2(+) and C2H3(+) are estimated, and a preliminary astronomical search for HCO2(+) is described.
Herbst, E.↗
The molecular complexes in Orion
Line emission from CO at 2.6 mm is observed over an area of 28 square degrees in the Orion region. Most of the emission comes from two giant molecular complexes, roughly associated with Ori B and Ori A. The latter provides the best example of a giant molecular complex at the end of a sequence of OB association subgroups of decreasing age. This complex is apparently rotating with an angular velocity 4.5 by 10 to the -15th power per sec, but in a direction opposed to the Galactic rotation. The apparently denser parts of the cloud are rotating at a somewhat greater angular velocity. The total mass of the molecular gas derived from the observations is 200,000 solar masses, implying that roughly half the matter in this region is in the form of molecular hydrogen.
Kutner, M. L.↗
On the relationship of interstellar N2H/+/, HCO/+/, HCN, and CN
A survey of 73 sources has been made in the emission lines of N2H(+) and HCO(+), including detailed maps of four sources (Ori A, OMC-2, DR 21 OH, and NGC 6334). These data are combined with equally extensive data for HCN and CN to make a detailed study of the spatial relationship of these four species. Actual abundance ratios are shown to vary, often sharply, over small scale lengths (of the order of 1 arcmin) within the mapped sources. Excitation temperatures also vary. All four species appear to be subthermally excited. The abundance ratios and their spatial variations are interpreted in terms of ion-molecular formation and destruction processes. It is concluded that the relative abundances of CO may be considerably lower in some regions than previously believed. No evidence is found for variations in the C/O ratio over small scale lengths in Ori A. The degree of ionization of the Ori A molecular cloud may be significantly different from that of other molecular clouds.
Turner, B. E.↗
Indirect observation of unobservable interstellar molecules
It is suggested that the abundances of neutral non-polar interstellar molecules unobservable by radio astronomy can be systematically determined by radio observation of the protonated ions. As an example, observed N2H(+) column densities are analyzed to infer molecular nitrogen abundances in dense interstellar clouds. The chemistries and expected densities of the protonated ions of O2, C2, CO2, C2H2 and CH4 are then discussed. Microwave transition frequencies fo HCO2(+) and C2H3(+) are estimated, and a preliminary astronomical search for HCO2(+) is described.
Herbst, E.↗
Molecular clouds
An attempt is made to understand star formation in the context of the dense interstellar molecular gas from which stars are made. Attention is given to how molecular observations (e.g., UV spectroscopy and radio 21-cm and recombination line observations) provide data on the physical state of the dense interstellar gas; observations of H II regions, stellar associations, and dark nebulae are discussed. CO clouds are studied with reference to radial velocity, temperature, density, ionization, magnetic field.
Thaddeus, P.↗
Rotational excitation of CO by collisions with He, H, and H2 under conditions in interstellar clouds
Cross sections for rotational excitation of small molecules by low-energy collisions with helium and hydrogen can currently be obtained via accurate numerical solution of the quantum equations that describe both intermolecular forces and collision dynamics. The relevant methods are discussed in some detail and applied to compute excitation rates for carbon monoxide. These calculations also predict collision-induced spectral pressure-broadening constants which are in excellent agreement with available experimental data.
Green, S.↗
Theoretical investigation of protonated carbon dioxide
The equilibrium structure of CO2H(+) has been obtained from self-consistent field and configuration interaction wave functions. Only one stable form has been found, a linear O-C-O chain with the hydrogen bonded to oxygen and slightly off axis, in analogy with known isoelectronic species. A second structure protonated at carbon, which has been inferred from mass spectrometric studies, is found to be unstable with respect to spontaneous rearrangement. The proton affinity of CO2 is calculated to be 136 kcal/mole, in reasonable agreement with the most recent experimental value.
Green, S.↗
Confirmation of interstellar N2H/+/
The proposed identification of the triplet of interstellar lines recently discovered at 93.174 GHz with the molecular ion N2H(+) is confirmed by resolving the predicted hyperfine structure of the inner nitrogen nucleus in the narrow-line molecular source OMC-2 in the Orion Nebula. The hyperfine constants of N2H(+) are derived from the observational data, and the rest center frequency of the J = 1-0 rotational transition is determined. It is noted that the full width at half-maximum of the weakest line (F sub 1 = 0-1) is only 230 kHz (0.74 km/sec in radial velocity), making it the narrowest molecular emission line (excluding maser point sources) thus far observed in the direction of a H II region or IR source.
Thaddeus, P.↗
The ethynyl radical C2H - A new interstellar molecule
Four new interstellar lines have been detected near 87.3 GHz. Based on laboratory ESR data these lines have been positively defined as hyperfine components of the lowest rotational transition of the ethynyl radical C2H. The observations gave precise values for the C2H rotation, spin-doubling, and hyperfine constants. C2H is probably one of the most abundant interstellar polyatomic molecules yet detected.
Tucker, K. D.↗