Engineering topics

Thompson, Alan K.

Publications and source records attributed to Thompson, Alan K..

6 records

DOE OSTI2023

H 2 generation by the 10 B(n,α) 7 Li reaction in high temperature water

H 2 produced in water from the 10 B(n,α) 7 Li fission reaction has been measured up to 300 °C. Thermal energy neutrons from the Rhode Island Nuclear Science Center's 2 MW reactor interact with boric acid-containing water in temperature-controlled high-pressure cells made from tubing of either titanium or zirconium alloy. After exposure for a minimum of 1 h, the solution sample is extracted and sparged with argon. The H 2 entrained by the sparging gas is sampled with a small mass spectrometer. A small amount of sodium is included in the boric acid solution so that after sparging, samples can be collected for 24 Na activation measurements in a gamma spectrometer to determine the neutron exposure and thus the total energy deposited in solution. The G-value (μmol/J) for H 2 production is obtained for water at a pressure of 25 MPa, over a temperature range from 20 °C to 300 °C. The weak temperature dependence of this yield between 150 °C and 200 °C demonstrates that the bimolecular reaction of pairs of e$^{–}_{aq}$ is a very minor source of H 2 in high LET tracks.

10B↗

DOE OSTI2017

Beyond Californium—A Neutron Generator Alternative for Dosimetry and Instrument Calibration in the U.S.

Many evaluations of neutron survey instruments, area monitors and personal dosimeters rely on neutron reference radiations from 252Cf, a source of spontaneous fission neutrons that produces high dose rates from an almost point source geometry. Its characteristics are generally more favorable when compared to (a,n), photoneutron and reactor-based sources of neutrons. The source is typically used in two standardized configurations: unmoderated, to yield a fission energy spectrum, or placed within a heavy-water moderating sphere to produce a softened spectrum that is more appropriate for evaluating devices used in nuclear power plant work environments. The U.S. Department of Energy (DOE) 252Cf Loan/Lease Program was terminated in 2009, and the replacement of high-activity sources is increasingly cost prohibitive for laboratories that formerly benefited from that program, including the Pacific Northwest National Laboratory (PNNL) and National Institute of Standards and Technology (NIST). Neutron generators, based on the D-T and D-D fusion reactions, are becoming economically competitive with 252Cf and are recognized internationally as important calibration and test standards. Researchers from NIST and PNNLare jointly considering the practicality and technical challenges of implementing neutron generators as calibration standards in the U.S. This article reviews characteristics of isotope-based sources, leading to rationale behind increasing favor of electronically-generated neutron options. The evaluation of a D-T system at PNNL has revealed primary challenges in adapting generators to the task of calibration and testing in which neutron characteristics must be accurately determined. Concepts for modifying the generated neutron spectra to achieve particular targeted spectra, simulating 252Cf or workplace environments, are discussed.

Calibration, californium-252, Dosimeter Irradiatio↗

DOE OSTI2015

Demonstration of neutron detection utilizing open cell foam and noble gas scintillation

We present results demonstrating neutron detection via a closely spaced converter structure coupled to low pressure noble gas scintillation instrumented by a single photo-multiplier tube (PMT). The converter is dispersed throughout the gas volume using a reticulated vitreous carbon foam coated with boron carbide (B{sub 4}C). A calibrated cold neutron beam is used to measure the neutron detection properties, using a thin film of enriched {sup 10}B as a reference standard. Monte Carlo computations of the ion energy deposition are discussed, including treatment of the foam random network. Results from this study indicate that the foam shadows a significant portion of the scintillation light from the PMT. The high scintillation yield of Xe appears to overcome the light loss, facilitating neutron detection and presenting interesting opportunities for neutron detector design.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2014

High-resolution, vacuum-ultraviolet absorption spectrum of boron trifluoride

In the course of investigations of thermal neutron detection based on mixtures of {sup 10}BF{sub 3} with other gases, knowledge was required of the photoabsorption cross sections of {sup 10}BF{sub 3} for wavelengths between 135 and 205 nm. Large discrepancies in the values reported in existing literature led to the absolute measurements reported in this communication. The measurements were made at the SURF III Synchrotron Ultraviolet Radiation Facility at the National Institute of Standards and Technology. The measured absorption cross sections vary from 10{sup −20} cm{sup 2} at 135 nm to less than 10{sup −21} cm{sup 2} in the region from 165 to 205 nm. Three previously unreported absorption features with resolvable structure were found in the regions 135–145 nm, 150–165 nm, and 190–205 nm. Quantum mechanical calculations, using the TD-B3LYP/aug-cc-pVDZ variant of time-dependent density functional theory implemented in Gaussian 09, suggest that the observed absorption features arise from symmetry-changing adiabatic transitions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2014

Noble gas excimer scintillation following neutron capture in boron thin films

Far-ultraviolet scintillation signals have been measured in heavy noble gases (argon, krypton, xenon) following boron-neutron capture ({sup 10}B(n,α){sup 7}Li) in {sup 10}B thin films. The observed scintillation yields are comparable to the yields from some liquid and solid neutron scintillators. At noble gas pressures of 107 kPa, the number of photons produced per neutron absorbed following irradiation of a 1200 nm thick {sup 10}B film was 14 000 for xenon, 11 000 for krypton, and 6000 for argon. The absolute scintillation yields from the experimental configuration were calculated using data from (1) experimental irradiations, (2) thin-film characterizations, (3) photomultiplier tube calibrations, and (4) photon collection modeling. Both the boron films and the photomultiplier tube were characterized at the National Institute of Standards and Technology. Monte Carlo modeling of the reaction cell provided estimates of the photon collection efficiency and the transport behavior of {sup 10}B(n,α){sup 7}Li reaction products escaping the thin films. Scintillation yields increased with gas pressure due to increased ionization and excitation densities of the gases from the {sup 10}B(n,α){sup 7}Li reaction products, increased frequency of three-body, excimer-forming collisions, and reduced photon emission volumes (i.e., larger solid angle) at higher pressures. Yields decreased for thicker {sup 10}B thin films due to higher average energy loss of the {sup 10}B(n,α){sup 7}Li reaction products escaping the films. The relative standard uncertainties in the measurements were determined to lie between 14% and 16%. The observed scintillation signal demonstrates that noble gas excimer scintillation is promising for use in practical neutron detectors.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DOE OSTI2011

Nuclear Data Verification and Standardization

The objective of this interagency program is to provide accurate neutron interaction verification and standardization data for the U.S. Department of Energy Division of Nuclear Physics programs which include astrophysics, radioactive beam studies, and heavy-ion reactions. The measurements made in this program are also useful to other programs that indirectly use the unique properties of the neutron for diagnostic and analytical purposes. These include homeland security, personnel health and safety, nuclear waste disposal, treaty verification, national defense, and nuclear based energy production. The work includes the verification of reference standard cross sections and related neutron data employing the unique facilities and capabilities at NIST and other laboratories as required; leadership and participation in international intercomparisons and collaborations; and the preservation of standard reference deposits. An essential element of the program is critical evaluation of neutron interaction data standards including international coordinations. Data testing of critical data for important applications is included. The program is jointly supported by the Department of Energy and the National Institute of Standards and Technology.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗