Engineering topics

Thompson, Anthony B.

Publications and source records attributed to Thompson, Anthony B..

4 records

DOE OSTI2023

Benchmarking Hydrogen Isotope Separation Efficiency of Pd/k–Packed TCAP Columns

By leveraging the large isotope effect in the palladium hydrogen isotope system, the Thermal Cycling Absorption Process (TCAP) provides an efficient and advantageous means to separate protium, deuterium, and tritium. To meet increased future tritium processing demands, such as those needed for fusion power plants, current designs of the separation columns need to be adapted and optimized using the progress made in understanding hydrogen isotope science. One key to this optimization lies in understanding the baseline performance for currently employed separation packing materials. Pd/k and molecular sieves, as commonly used for the separation of hydrogen isotopes, are herein evaluated to establish a baseline for their separation efficiency. Van Deemter plots are formulated, and the influence of each parameter is evaluated to determine areas for improvement.

Thermal Cycling Absorption Process (TCAP)↗

DOE OSTI2022

Understanding Photocarrier and Gas Dynamics to Rationally Design Heterostructured Nanocatalysts for Efficient Solar CO 2 Conversion

Recent research in CO 2 photocatalysis has largely focused on exploring new catalysts; however, details of the relationship between charge carrier dynamics and gas dynamics on the surface of nanomaterials often remain unclear. Knowledge of these processes will allow one to rationally design highly efficient catalysts for solar CO 2 conversion. This project aimed to develop state-of-the-art techniques and establish new capabilities in SRNL to enable the study of photocatalysts and other materials in detail. In FY21, we developed two new in situ techniques that are unique to SRNL, allowing the study of reaction intermediates and adsorbed gases during photocatalysis at various wavelengths of excitation. We also established a new in-house capability for catalyst synthesis and product evaluation which enables a deep understanding of how catalyst preparation methodologies impact product generation. In FY22, we gained in-house expertise and knowledge on the newly constructed a physical vapor deposition device, i.e. glancing angle deposition (GLAD) system, and constructed a flow photoreactor system for CO 2 photoconversion and other photocatalytic studies.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2021

Understanding Photocarrier and Gas Dynamics to Rationally Design Heterostructured Nanocatalysts for Solar CO 2 Conversion

Recent research in CO 2 photocatalysis has largely focused on exploring new catalysts; however, details of how these materials work often remain unclear. Knowledge of these processes will allow one to rationally design highly efficient catalysts for solar CO 2 conversion. This project aims to develop new techniques and establish new capabilities in SRNL to enable the study of photocatalysts and other materials in extreme detail. In FY21, we developed two new in situ techniques that are unique to SRNL, allowing the study of reaction intermediates and adsorbed gases during photocatalysis. We also established new in-house capabilities for catalyst synthesis and transient absorption (TA) spectroscopy, which enables the study of very short-lived excited states on photocatalysts. These capabilities will be used extensively for this project and in other current projects relevant to clean energy technologies such as photovoltaic cells, providing a good return on investment in the coming years.

14 SOLAR ENERGY↗

DOE OSTI2020

SR19007 - Future TCAP Implementation Issues

This project demonstrates the success of the PDRD program in bringing a concept from the R&D phase to direct plant funding. Although Mini-TCAP technology is overall at a TRL of ~6.5, the specific questions addressed in this project were brought from a low (2-3 TRL) to a TRL 5 over the course of the project. This project successfully completed all initial goals ahead of schedule (inventory control, guard bed, ammonia impact, and cycle time) and furthermore addressed additional scope (continued TCAP evaluation, ion chamber) in FY20. First, this project resolved minor inventory control issues by introducing a new parameter tracking and correcting for inventory changes over multiple cycles. This project also involved modification of the previously constructed plant-configured Mini-TCAP in order to allow ammonia impurity studies. TCAP was tested with ammonia in the feed stream both with and without a guard bed present to determine guard bed efficacy and the effect of ammonia if it enters TCAP. The TCAP columns were then replaced with brazed columns, where the LN2 cooling coil is brazed to the column and the column is self-brazed along the coils. This drastically improved heat transfer and consequently reduced cycle time compared to the previous columns, in which the coils were mechanically held in place. Finally, additional scopes were taken on in FY20, including evaluation of TCAP with faster cycle time and procurement of ion chambers for future TCAP integration.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗