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Tien, James

Publications and source records attributed to Tien, James.

Measurement and evaluation of the radiative properties of a thin solid fuel

Accurate modeling of combustion systems requires knowledge of the radiative properties of the system. Gas phase properties are well known, but detailed knowledge of surface properties is limited. Recent work has provided spectrally resolved data for some solid fuels, but only for the unburned material at room temperature, and for limited sets of previously burned and quenched samples. Due to lack of knowledge of the spectrally resolved properties at elevated temperatures, as well as processing limitations in the modeling effort, graybody values are typically used for the fuels surface radiative properties. However, the spectrally resolved properties for the fuels at room temperature can be used to give a first-order correction for temperature effects on the graybody values. Figure 1 shows a sample of the spectrally resolved emittance/absorptance for a thin solid fuel of the type commonly used in combustion studies, from approximately 2 to 20 microns. This plot clearly shows a strong spectral dependence across the entire range. By definition, the emittance is the ratio of the emitted energy to that of a blackbody at the same temperature. Therefore, to determine a graybody emittance for this material, the spectrally resolved data must be applied to a blackbody curve. The total area under the resulting curve is ratioed to the total area under the blackbody curve to yield the answer. Due to the asymmetry of the spectrally resolved emittance and the changing shape of the blackbody curve as the temperature increases, the relative importance of the emittance value at any given wavelength will change as a function of temperature. Therefore, the graybody emittance value for a given material will change as a function of temperature even if the spectral dependence of the radiative properties remains unchanged. This is demonstrated in Figures 2 and 3, which are plots of the spectrally resolved emittance for KimWipes (shown in Figure 1) multiplied by the blackbody curves for 300 K (Figure 2) and 800 K (Figure 3). Each figure also shows the blackbody curve for that temperature. Ratioing the areas under the curve for each of these figures give a graybody emittance of 0.64 at 300 K, and 0.46 at 800 K. It is recognized that materials undergoing pyrolysis will change in composition as they heat up, and that the radiative properties of the materials may have inherent temperature dependence. Both of these effects will contribute to changes in the radiative characteristics of a given material, and are not accounted for here. However, this paper demonstrates the temperature dependence of graybody radiative properties, and provides a method for a first-order correction (for temperature) to the graybody values if the spectrally resolved properties are known.

Pettegrew, Richard↗

The Effect of Velocity on the Extinction Behavior of a Diffusion Flame during Transient Depressurization

Current fire suppression plans for the International Space Station include the use of venting (depressurization) as a method for extinguishing a fire. Until recently this process had only been examined as part of a material flammability experiment performed on Skylab in the early 1970's. Due to the low initial pressure (0.35 Atm) and high oxygen concentration (65%), the Skylab experimental results are not applicable for understanding the effects of venting on a fire in a space station environment (21%O2, 1 Atm). Recent research examined the extinction behavior of a diffusion flame over a polymethyl methacrylate (PMMA) cylinder during a transient depressurization in low-gravity. The numerical model was used to examine extinction limits as a function of depressurization rate, forced flow velocity, and initial solid phase temperature. The experimental and numerically predicted extinction data indicated that as the solid phase temperature increased the pressure required to extinguish the flame decreased. The numerical model was also used to examine conditions not obtainable in the low-gravity experiments. From these simulations, a series of extinction boundaries were generated that showed a region of increased flammability existed at a forced flow of 10 cm/s. Analysis of these extinction boundaries indicated that they were quasi-steady in nature, and that the final extinction conditions were independent of the transient process. The velocity range in the previous study was limited and thus the results did not examine the effects of velocities less than 1 cm/s or greater than 20 cm/s. This study utilized low-gravity experiments performed on NASA's Reduced-gravity Research Aircraft Laboratory and numerical simulations to examine conditions applicable to the Space Station environment. This paper extends the analysis of the previous study to a comprehensive examination of the effect of increased velocity on extinction behavior and extinction limits during a transient depressurization in low-gravity. This is achieved by examining extinction data from buoyant (normal-gravity) and low-buoyant (low-gravity) depressurization. experiments, as well as from numerical predictions of flame behavior during depressurization in a non-buoyant (zero-gravity) environment.

Goldmeer, Jeffrey S.↗

Large Diameter, Radiative Extinction Experiments with Decane Droplets in Microgravity

The extinction of a diffusion flame is of fundamental interest in combustion science. Linan, Law, and Chung and Law analytically and experimentally determined an extinction boundary in terms of droplet diameter and pressure for a single droplet due to Damkohler, or blowoff, extinction. More recently, other researchers demonstrated extinction due to finite rate kinetics in reduced gravity for free droplets of heptane. Chao modeled the effect of radiative heat loss on a quasi-steady spherically symmetric single droplet burning in the absence of buoyancy. They determined that for increasing droplet diameter, a second limit can be reached such that combustion is no longer possible. This second, larger droplet diameter limit arises due to radiative heat loss, which increases with increasing droplet and flame diameter. This increase in radiative heat loss arises due to an increase in the surface area of the flame. Recently, Marchese modeled fuel droplets with detailed chemistry and radiative effects, and compared the results to other work. The modeling also showed the importance of radiative loss and radiative extinction Experiments examined the behavior of a large droplet of decane burning in reduced gravity onboard the NASA Lewis DC-9 aircraft, but did not show a radiative extinction boundary due to g-jitter (Variations in gravitational level and direction) effects. Dietrich conducted experiments in the reduced gravity environment of the Space Shuttle. This work showed that the extinction diameter of methanol droplets increased when the initial diameter of the droplets was large (in this case, approximately 5 mm). Theoretical results agreed with these experimental results only when the theory included radiative effects . Radiative extinction was experimentally verified by Nayagam in a later Shuttle mission. The following work focuses on the combustion and extinction of a single fuel droplet. The goal is to experimentally determine a large droplet diameter limit that arises due to radiative heat loss from the flame to the surroundings.

Easton, John↗

Burning Candles in the Microgravity of Space

The Candle Flames in Microgravity (CFM) experiment was designed to study how long candle flames can be sustained in microgravity, how the flames behave prior to extinction, and the how two closely spaced candle flames behave. The scientists hope that one day the results will help resolve age-old questions regarding the effects of gravity on certain types of flames (low momentum diffusion flames, or candle flames) and their ability to burn without the presence of gravity. This information will provide a better understanding of fires on spacecraft and could lead to advances in fire detection and extinction techniques.

Dietrich, Daniel↗

Effect of pressure on a burning solid in low-gravity

Venting, or depressurization, has been discussed as a possible technique for extinguishing fires on aircraft and spacecraft. Fire suppression plans for the International Space Station Alpha (ISSA) discuss the use of depressurization as a method for extinguishing fires. In the case of an uncontrollable fire, the affected compartment would be vented from an initial pressure of 1.0 atm (14.7 psia) to a final pressure 0.33 atm (4.8 psia) within 10 minutes. However, the lack of low pressure flammability data for solid materials in a low-gravity environment presents an uncertainty for the use of the venting technique. There are also transient effects that need to be considered. It is possible that the flows induced by the venting could intensify the fire. This occurred during flammability tests conducted on board Skylab. In addition, the extinction pressure could be a function of the depressurization rate. Studies conducted with solid propellants have shown that if the pressure is reduced quickly enough, the pressure at extinction will be greater than the steady-state extinction limit. This project, which was started in 1992, is examining both the quasi steady-state and transient effects of pressure reduction on a burning solid in low-gravity. This research will provide low-g extinguishment data upon which policies and practices can be formulated for fire safety in orbiting spacecraft.

Goldmeer, Jeffrey S.↗