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Tokunaga, A. T.

Publications and source records attributed to Tokunaga, A. T..

At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

A Deep Search for the Release of Volcanic Gases on Mars Using Ground-Based High-Resolution Infrared and Submillimeter Spectroscopy: Sensitive Upper Limits for OCS and SO2

Recent volcanic activity has long been considered a distinct possibility that would place major constraints on the evolution of Mars’ interior. Volcanic activity would result in the outgassing of sulfur-bearing species. As part of our multi-band search for active release of volcanic gases on Mars, we looked for carbonyl sulfide (OCS) at its combination band (v1 + v3) at 3.42 micrometers (2924 cm(exp -1), and sulfur dioxide (SO2) at 346.652 GHz, in two successive Mars years during its late Northern spring and mid Northern summer seasons (L(sub)s= 43 deg - 44 deg). The targeted volcanic districts, Tharsis and Syrtis Major, were observed during the two intervals, 15 Dec. 2011 to 6 Jan. 2012 in the first year, and 23 May 2014 to 12 June 2014 in the second year using the high resolution infrared spectrometer CSHELL on the NASA Infrared Telescope Facility, and the high resolution heterodyne receiver HARP at the James Clerk Maxwell Telescope atop Maunakea, Hawaii. No active release of such gases was detected, and we report 2 sigma upper limits of 1.8 ppbv and 3.1 ppbv for OCS and SO2, respectively, compared to 0.3 ppbv for SO2 (Encrenaz, T. et al. [2011] Astron. & Astrophys. 530, A37; Krasnopolsky, V.A. [2012] Icarus 217, 144-152) over the disk of Mars. Our retrieved upper limit on the SO2 outgassing rate of 156 tons/day (1.8 kg/s), corresponds to a mass rate of magma that is able to degas the SO2 of 104 kilotons/day (1200 kg/s), or 40,000 cu m/day (0.46 cu m/s). Our campaign places stringent limits on the concentration of sulfur-bearing species into the atmosphere of Mars.

Khayat, A. S. J.↗
NASA NTRS1999

The interstellar 4.62 micron band

We present new 4.5-5.1 micron (2210-1970 cm-1) spectra of embedded protostars, W33 A, AFGL 961 E, AFGL 2136, NGC 7538 IRS 9, and Mon R2 IRS 2, which contain a broad absorption feature located near 4.62 micron (2165 cm-1), commonly referred to in the literature as the "X-C triple bond N" band. The observed peak positions and widths of the interstellar band agree to within 2.5 cm-1 and 5 cm-1, respectively. The strengths of the interstellar 4.62 micrometers band and the ice absorption features in these spectra are not correlated, which suggests a diversity of environmental conditions for the ices we are observing. We explore several possible carriers of the interstellar band and review possible production pathways through far-ultraviolet photolysis (FUV), ion bombardment of interstellar ice analog mixtures, and acid-base reactions. Good fits to the interstellar spectra are obtained with an organic residue produced through ion bombardment of nitrogen-containing ices or with the OCN- ion produced either through acid-base reactions or FUV photolysis of NH3-containing ices.

NASA Center ARC↗
NASA NTRS1997

8-13 Micron Spectroscopy of Young Stars

We present 8-13 mue spectra of 23 young Stars acquired with the UKIRT CGS3 spectrometer, including T Tauri, Herbig Ae/Be, and FU Ori Stars.

Micron Spectroscopy↗
NASA NTRS1997

8-13 Micron Spectroscopy of Young Stars

We presen 8-13 meu spectra of 23 young stars acquired with the UKIRT CGS3 spectromere, including T Tauri, Herbig Ae/Be, and FU Ori stars. Silicate emission and absorption features can generally be matched with the Trapezium emissivity, by employing simple models to account for optical depth effects.

Infrared Spectra Stars T Tauri↗
NASA NTRS1996

Detection of acetylene in the infrared spectrum of comet Hyakutake

Comets are rich in volatile materials, of which roughly 80% (by number) are water molecules. Considerable progress is being made in identifying the other volatile species, the abundances of which should enable us to determine whether comets formed primarily from ice-covered interstellar grains, or from material that was chemically processed in the early solar nebula. Here we report the detection of acetylene (C2H2) in the infrared spectrum of comet C/1996 B2 (Hyakutake). The estimated abundance is 0.3-0.9%, relative to water, which is comparable to the predicted solid-phase abundance in cold interstellar clouds. This suggests that the volatiles in comet Hyakotake may have come from ice-covered interstellar grains, rather than material processed in the accretion disk out of which the Solar System formed.

Acetylene/analysis↗
NASA NTRS1996

Raman Spectrum of Quenched Carbonaceous Composites

Quenched Carbonaceous Composites (QCC's) are products from the ejecta of a hydrocarbon plasma. Two types of QCC, dark QCC and thermally-altered (heated) filmy QCC, have been shown to have a 220 nm absorption feature similar to that seen in the interstellar extinction curve. We present here Raman spectra of the QCCs and compare them with various carbonaceous materials to better understand the structure QCC. We find that structure of QCC is different from that of graphite and more similar to carbonaceous material found in some interplanetary dust particles and chondritic meteorites.

Wada, S.↗
NASA NTRS1995

10 micron spectroscopy of younger stars in the rho Ophiuchi cloud

Spectra in the 10 micrometer region were obtained of 14 young stars associated with the central core of the rho Oph dark cloud complex. Silicate dust emission and absorption features can be fairly well reproduced with simple models using the emissivity of the silicates in the Orion Trapezium region, believed to be typical of molecular cloud dust. A spectrum of the Trapezium star theta(sup 1) Ori D was obtained to define the emissivity more precisely. The emissivity of silicate dust around the late-type giant Mu Cep does not improve the fits to the absorption features and provides a poorer match to the emission features. None of the sources display a strong 11.2 micrometer peak like that seen in comet Halley and attributed to crystalline olivine. A broad weak feature near 11.2 micrometer, possibly related to the comet feature, may be present in the emission spectrum of the Herbig Ae star HD 150193. Absorption features toward two of the objects are narrower than would be expected from Trapezium-like silicates, suggesting differences in the composition of the silicates. The relation between the silicate extinction band depth and H2O ice band depths is determined for the deeply embedded objects. One late-type object, Elias 14, clearly shows the 11.25 micrometer aromatic hydrocarbon emission feature, possibly excited by the nearby B star, HD 147889, though the latter does not exhibit the feature.

Hanner, M. S.↗
NASA NTRS1995

Solid Carbonyl Sulphide (OCS) in W33A

We present ground-based observations of the 2041/cm (4.9 micrometer) absorption feature toward the deeply embedded protostar W33A. We attribute this interstellar feature to solid carbonyl sulphide (OCS) embedded in icy grain mantles along the line of sight. We have made an extensive laboratory study of the infrared characteristics of OCS in various ice mixtures. Studies of the 2041/cm band of solid OCS and solid mixtures containing OCS show that its shape and peak position are sensitive to the molecular environment of the OCS molecule. Mie scattering calculations show that the peak position and profile of the OCS band depend on the shape and size of the absorbing grain when the OCS concentration is larger than 0.05. For lower OCS concentrations, laboratory-measured bulk spectra agree very well with the absorption spectra of small grains. We have compared the observed feature with laboratory and theoretical spectra of astrophysically relevant mixtures. The best agreement is obtained for mixtures with traces of OCS in a methanol-rich matrix. This would suggest the presence of independent grain components and in particular of a minor fraction of methanol-rich icy grain mantles in which OCS is embedded. From the strength of the absorption feature we deduce a OCS/H 20 ratio, along the line of sight, of 4 x 10(exp -4).

Palumbo, M. E.↗
NASA NTRS1995

Solid Carbonyl Sulphide (OCS) in W33A

We present ground-based observations of the 2041 cm(exp -1) (4.9 mm) absorption feature toward the deeply embedded protostar W33A. We attribute this interstellar feature to solid carbonyl sulphide (OCS) embedded in icy grain mantles along the line of sight. We have made an extensive laboratory study of the infrared characteristics of OCS in various ice mixtures. Studies of the 2041 cm(exp -1) band of solid OCS and solid mixtures containing OCS show that its shape and peak position are sensitive to the molecular environment of the OCS molecule. Mie scattering calculations show that the peak position and profile of the OCS band depend on the shape and size of the absorbing grain when the OCS concentration is larger than 0.05. For lower OCS concentrations, laboratory-measured bulk spectra agree very well with the absorption spectra of small grains. We have compared the observed feature with laboratory and theoretical spectra of astrophysically relevant mixtures. The best agreement is obtained for mixtures with traces of OCS in a methanol-rich matrix. This would suggest the presence of independent grain components and in particular of a minor fraction of methanol-rich icy grain mantles in which OCS is embedded. From the strength of the absorption feature we deduce a OCS/H2O ratio, along the line of sight, of 4 x 10(exp -4).

Palumbo, M. E.↗
NASA NTRS1994

Detection of absorption by H2 in molecular clouds: A direct measurement of the H2:CO ratio

Vibrational absorption by H2 and CO has been searched for toward infrared sources embedded in molecular clouds. H2 was detected toward NGC 2024 IRS 2 and possibly toward NGC 2264 (GL 989). CO was detected toward both sources. The results are consistent with the H2 ortho:para ratio being equilibrated at the cloud temperature. Toward NGC 2024, H2:CO = (3700(sub -2600)(sup +3100)) (2 sigma limits), and toward NGC 2264, H2:CO less than 6000. Approximately one-third of all carbon is in gas-phase CO.

Lacy, J. H.↗
NASA NTRS1994

High resolution spectroscopy with CSHELL

The NASA Infrared Telescope Facility Cryogenic Echelle Spectrograph (CSHELL) was designed to fill a need for high sensitivity, high resolution, long slit near-infrared spectroscopy. Scientific programs in the areas of comets, planetary atmospheres, young stellar objects, the interstellar medium, and galactic dynamics have been pursued with CSHELL and are described herein. The future of the instrument is also discussed.

Greene, T. P.↗
NASA NTRS1993

Dust emission features in 3-micron spectra of Herbig Ae/Be stars

Attention is given to low- and medium-resolution spectra in the 3-micron region of 24 Herbig Ae/Be stars obtained in a search for organic features from the dust around young stars. The 3.29-micron emission feature from aromatic hydrocarbons was detected in three objects: Lk H-alpha 25, XY Per, and AS 310. Two other stars, HD 245185 and HK Ori, may have weak features. About 20 percent of the Herbig Ae/Be surveyed to date have firmly detected 3.29-micron features. The available data indicate that the 3.29-micron feature is more extended around Herbig Ae/Be stars of earlier spectral type, possibly due to dehydrogenization or destruction of the aromatics near these stars. It is suggested that the total number of aromatics excited by the stars is also greater around the earlier-type objects.

Brooke, T. Y.↗
NASA NTRS1993

Infrared and optical imaging of IRAS sources with CO outflow - A snapshot of early star formation

We present multiband imaging of three IRAS sources associated with CO molecular outflows. We find stellar density enhancements around all three IRAS sources. Optical and near-IR photometry indicates that at least 60 percent of the near-IR sources in the vicinity of the IRAS sources are pre-main-sequence stars. Using the photometric data at nbL and M, we are able to identify candidates for the near-IR counterparts of the IRAS sources. We also find that (1) the spectral energy distribution of the deeply embedded sources could be complicated by source confusion and scattered light from the young stellar objects; (2) star formation in the vicinity of the IRAS sources is a continuous process with an age span of 0.5-3 Myr; and (3) stellar density enhancement is probably a phenomenon found at the earliest stage of star formation.

Chen, H.↗
NASA NTRS1992

Infrared monitoring of Comet P/Tempel 2

Observations of P/Tempel 2 at 1.25-20.0 micron during its 1983 and 1988 apparitions are presented. The thermal emission from the nucleus was monitored, and the dust production rate during the 1988 apparition is estimated. We find that the nucleus can contribute up to 40 percent of the total 10 micron flux even near perihelion and that P/Tempel 2 has a dust production rate that is typical of short-period comets. The J - H color of the nucleus, 0.65 +/- 0.05, is the reddest of any observed so far. The geometric albedo of the nucleus at 1.25-2.20 micron was found to be 0.04-0.07.

Tokunaga, A. T.↗
NASA NTRS1992

The 8-13 micron spectrum of the young stellar object WL 16

Spectroscopy of WL 16 in the 8-13-micron region reveals a spectrum dominated by the hydrocarbon emission features at 7.7, 8.6, 11.25, and 12.7 microns. The emission plateau between the latter two features is detected, the first such detection in a young stellar object. The expected silicate feature is badly masked by the strong emission bands. Combining our spectra with the infrared spectral energy distribution indicates that silicate absorption is probably present.

Hanner, M. S.↗
NASA NTRS1992

The dust coma of Comet P/Giacobini-Zinner in the infrared

The paper presents 1-20-micron photometry of P/Giacobini-Zinner obtained at the NASA Infrared Telescope Facility, during 1985 June-September (r = 1.57-1.03 AU). A broad, weak 10-micron silicate emission feature was detected on August 26.6; a similar weak emission feature could have been hidden in the broadband photometry on other dates. The total scattering and emitting cross section of dust in the inner coma was similar to that in other short-period comets, but a factor of 10 (r = 1.56 AU) to 100 (r = 1.03 AU) lower than the amount of dust in Comet Halley. The thermal emission continuum can be fit with models weighted toward either small or large absorbing grains. The dust production rate near perihelion was about 100,000 g/s (small-grain model) to about 1,000,000 g/s (large-grain model). The corresponding dust/gas mass ratio on August 26 was about 0.1-1. A silicate-rich heterogeneous grain model with an excess of large particles is compatible with the observed spectrum of Giacobini-Zinner on August 26. Thus, weak or absent silicate emission does not necessarily imply an absence of silicates in the dust, although the abundance of silicate particles not greater than 1 micron radius must have been lower than in Comet Halley.

Hanner, M. S.↗
NASA NTRS1992

A strong 3.4 micron emission feature in comet Austin 1989c1

High resolution 2.8-4.0 micron spectra of the 'new' comet Austin 1989c1, taken on 15-16 May 1990 confirm the presence of the broad emission features around 3.4 and 3.52 micron seen in a number of bright comets and ascribed to organic material. Both the 3.4 micron band strength and the 3.52/3.36 micron flux ratios are among the largest so far observed. The data are consistent with the relationship between band strength and water production rate that was recently derived. Excess emission at 3.28 and 3.6 micron cannot be unambiguously identified as features due to the poor signal-to-noise ratio.

Green, S. F.↗