Engineering topics

Toon, Owen B.

Publications and source records attributed to Toon, Owen B..

At least 73 records · Page 4

NASA NTRS1994

Microphysical modeling of cirrus. 1: Comparison with 1986 FIRE IFO measurements

We have used a one-dimensional model of cirrus formation to study the development of cirrus clouds during the 1986 First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment (FIRE) intensive field observations (IFO). The cirrus model includes microphysical, dynamical, and radiative processes. Sulfate aerosols, solution drops, ice crystals, and water vapor are all treated as interactive elements in the model. Ice crystal size distributions are fully resolved based on calculations of homogeneous freezing nucleation, growth by water vapor deposition, evaporation, coagulation, and vertical transport. We have focused on the cirrus observed on November 1, 1986. Vertical wind speed for the one-dimensional simulation is taken from a mesoscale model simulation for the appropriate time period. The mesoscale model simulation suggested that strong upward motions over Wyoming and subsequent horizontal transport of upper level moisture were responsible for the cirrus observed over Wisconsin on this date. We assumed that our one-dimensional model could be used to represent a vertical column moving from Wyoming to Wisconsin over a period of several hours. Ice crystal nucleation occurs in our model in the 8 to 10-km region as a result of the strong updrafts (and cooling) early in the simulation. Growth, coagulation, and sedimentation of these ice crystals result in a broad cloud region (5-10 km thick) with an optical depth of 1-2 after a few hours, in agreement with the FIRE measurements. Comparison with aircraft microphysical measurements made over Wisconsin indicates that the simulation generated reasonable ice water content, but the predicted ice number densities are too low, especially for radii less than about 50 microns. Sensitivity tests suggest that better agreement between simulated and observed microphysical properties is achieved if the nucleation rate is higher or stronger vertical mixing (perhaps associated with multidimensional motions) is present.

Jensen, Eric J.↗

NASA NTRS1994

Microphysical modeling of cirrus. 2: Sensitivity studies

The one-dimensional cirrus model described in part 1 of this issue has been used to study the sensitivity of simulated cirrus microphysical and radiative properties to poorly known model parameters, poorly understood physical processes, and environmental conditions. Model parameters and physical processes investigated include nucleation rate, mode of nucleation (e.g., homogeneous freezing of aerosols and liquid droplets or heterogeneous deposition), ice crystal shape, and coagulation. These studies suggest that the leading sources of uncertainty in the model are the phase change (liquid-solid) energy barrier and the ice-water surface energy which dominate the homogeneous freezing nucleation rate and the coagulation sticking efficiency at low temperatures which controls the production of large ice crystals (radii greater than 100 mcirons). Environmental conditions considered in sensitivity tests were CN size distribution, vertical wind speed, and cloud height. We found that (unlike stratus clouds) variations in the total number of condensation nuclei (NC) have little effect on cirrus microphysical and radiative properties, since nucleation occurs only on the largest CN at the tail of the size distribution. The total number of ice crystals which nucleate has little or no relationship to the number of CN present and depends primarily on the temperature and the cooling rate. Stronger updrafts (more rapid cooling) generate higher ice number densities, ice water content, cloud optical depth, and net radiative forcing. Increasing the height of the clouds in the model leads to an increase in ice number density, a decrease in effective radius, and a decrease in ice water content. The most prominent effect of increasing cloud height was a rapid increase in the net cloud radiative forcing which can be attributed to the change in cloud temperature as well as change in cloud ice size distributions. It has long been recognized that changes in cloud height or cloud area have the greatest potential for causing feedbacks on climate change. Our results suggest that variations in vertical velocity or cloud microphysical changes associatd with cloud height changes may also be important.

Jensen, Eric J.↗

NASA NTRS1994

Radiatively forced dispersion of the Mt. Pinatubo volcanic cloud and induced temperature perturbations in the stratosphere during the first few months following the eruption

A combined 3-dimensional circulation model and aerosol microphysical/transport model is used to simulate the dispersion of the Mt. Pinatubo volcanic cloud in the stratosphere for the first few months following the eruption. Radiative heating of the cloud due to upwelling infrared radiation from the troposphere is shown to be an important factor affecting the transport. Without cloud heating, cloud material stays mostly north of the equator, whereas with cloud heating, the cloud is transported southward across the equator within the first two weeks following the eruption. Generally the simulations agree with Total Ozone Mapping Spectrometer (TOMS), Advanced Very High Resolution Radiometer (AVHRR), and Stratospheric Aerosol and Gas Experiment (SAGE) satellite observations showing the latitude distribution of cloud material to be between about 20 deg S and 30 deg N within the first few months. Temperature perturbations in the stratosphere induced by the aerosol heating are generally 1-4 K, in the range of those observed.

Young, Richard E.↗

NASA NTRS1994

Modeling the Relationships Between Aerosol Properties and the Direct and Indirect Effects of Aerosols on Climate

Aerosols may affect climate directly by scattering and absorbing visible and infrared energy, They may also affect climate indirectly by modifying the properties of clouds through microphysical processes, and by altering abundances of radiatively important gases through heterogeneous chemistry. Researchers understand which aerosol properties control the direct effect of aerosols on the radiation budget. Unfortunately, despite an abundance of data on certain types of aerosols, much work remains to be done to determine the values of these properties. For instance we have little idea about the global distribution, seasonal variation, or interannual variability of the aerosol optical depth. Also we do not know the visible light absorption properties of tropical aerosols which may contain much debris from slash and burn agriculture. A positive correlation between aerosol concentrations and albedos of marine stratus clouds is observed, and the causative microphysics is understood. However, models suggest that it is difficult to produce new particles in the marine boundary layer. Some modelers have suggested that the particles in the marine boundary layer may originate in the free troposphere and be transported into the boundary layer. Others argue that the aerosols are created in the marine boundary layer. There are no data linking aerosol concentration and cirrus cloud albedo, and models suggest cirrus properties may not be very sensitive to aerosol abundance. There is clear evidence of a radiatively significant change in the global lower stratospheric ozone abundance during the past few decades. These changes are caused by heterogeneous chemical reactions occurring on the surfaces of particles. The rates of these reactions depend upon the chemical composition of the particles. Although rapid advances in understanding heterogeneous chemistry have been made, much remains to be done.

Toon, Owen B.↗

NASA NTRS1994

Environmental Perturbations Caused by the Impacts of Comets and Asteroids on Earth

The extinction mechanisms proposed at the Cretaceous-Tertiary geological boundary are reviewed and related to the impact of asteroids or comets in general. For impact energies below 10(exp 4) Megatons (less than 6 x 10(exp 4) years; asteroid diameter less than 650 m), blast, earthquake, and fire may destroy local areas up to 10(exp 5) square m. Tidal waves could flood a kilometer inland over entire ocean basins. The energy range from 105 to 106 Megatons (less than 2 x 10(exp 6) years; asteroid diameter less than 3 km) is transitional. Dust lifted, sulfur released from within impacting asteroids, and soot from fires started by comets can produce climatologically significant optical depths of 10. At energies beyond 10(exp 7) Megatons, blast and earthquake damage is regional (10(exp 6) square cm). Tsunami cresting to 100 m and flooding 20 km inland will sweep the coastal zones of the world's oceans. Fires will be set globally. Light levels may drop so low from the smoke, dust and sulfate that vision is not possible. At energies approaching 10(exp 9) Megatons the ocean surface waters may be acidified by sulfur. The combination of these effects would be devastating.

Toon, Owen B.↗

NASA NTRS1993

Three dimensional modeling of cirrus during the 1991 FIRE IFO 2: Detailed process study

A three-dimensional model of cirrus cloud formation and evolution, including microphysical, dynamical, and radiative processes, was used to simulate cirrus observed in the FIRE Phase 2 Cirrus field program (13 Nov. - 7 Dec. 1991). Sulfate aerosols, solution drops, ice crystals, and water vapor are all treated as interactive elements in the model. Ice crystal size distributions are fully resolved based on calculations of homogeneous freezing of solution drops, growth by water vapor deposition, evaporation, aggregation, and vertical transport. Visible and infrared radiative fluxes, and radiative heating rates are calculated using the two-stream algorithm described by Toon et al. Wind velocities, diffusion coefficients, and temperatures were taken from the MAPS analyses and the MM4 mesoscale model simulations. Within the model, moisture is transported and converted to liquid or vapor by the microphysical processes. The simulated cloud bulk and microphysical properties are shown in detail for the Nov. 26 and Dec. 5 case studies. Comparisons with lidar, radar, and in situ data are used to determine how well the simulations reproduced the observed cirrus. The roles played by various processes in the model are described in detail. The potential modes of nucleation are evaluated, and the importance of small-scale variations in temperature and humidity are discussed. The importance of competing ice crystal growth mechanisms (water vapor deposition and aggregation) are evaluated based on model simulations. Finally, the importance of ice crystal shape for crystal growth and vertical transport of ice are discussed.

Jensen, Eric J.↗

NASA NTRS1993

Airborne Arctic Stratospheric Expedition 2: An overview

The sudden onset of ozone depletion in the antarctic vortex set a precedent for both the time scale and the severity of global change. The Airborne Antarctic Ozone Experiment (AAOE), stages from Punta Arenas, Chile, in 1987, established that CFCs, halons, and methyl bromide, the dominant sources of chlorine and bromide radicals in the stratosphere, control the rate of ozone destruction over the Antarctic; that the vortex is depleted in reactive nitrogen and water vapor; and that diabatic cooling during the antarctic winter leads to subsidence within the vortex core, importing air from higher altitudes and lower latitudes. This last conclusion is based on observed dramatic distortion in the tracer fields, most notably N2O. In 1989, the first Airborne Arctic Stratospheric Expedition (AASE-1), staged from Stavanger, Norway, and using the same aircraft employed for AAOE (the NASA ER-2 and the NASA DC-8), discovered that while NO(x) and to some degree NO(y) were perturbed within the arctic vortex, there was little evidence for desiccation. Under these (in contrast to the antarctic) marginally perturbed conditions, however, ClO was found to be dramatically enhanced such that a large fraction of the available (inorganic) chlorine resided in the form of ClO and its dimer ClOOCl. This leaves two abiding issues for the northern hemisphere and the mission of the second Airborne Arctic Stratospheric Expedition (AASE-2): (1) Will significant ozone erosion occur within the arctic vortex in the next ten years as chlorine loading in the stratosphere exceeds four parts per billion by volume? (2) Which mechanisms are responsible for the observed ozone erosion poleward of 30 deg N in the winter/spring northern hemisphere reported in satellite observations?

Anderson, James G.↗

NASA NTRS1993

Airborne Arctic Stratospheric Expedition 2: An Overview

The sudden onset of ozone depletion in the antarctic vortex set a precedent for both the time scale and the severity of global change. The Airborne Antarctic Ozone Experiment (AAOE), staged from Punta Arenas, Chile, in 1987, established that CFCs, halons, and methyl bromide, the dominant sources of chlorine and bromine radicals in the stratosphere, control the rate of ozone destruction over the Antarctic; that the vortex is depleted in reactive nitrogen and water vapor; and that diabatic cooling during the antarctic winter leads to subsidence within the vortex core, importing air from higher altitudes and lower latitudes. This last conclusion is based on observed dramatic distortion in the tracer fields, most notably N2O. In 1989, the first Airborne Arctic Stratospheric Expedition (AASE-I), staged from Stavanger, Norway, and using the same aircraft employed for AAOE (the NASA ER-2 and the NASA DC-8), discovered that while NO(x) and to some degree NO(y) were perturbed within the arctic vortex, there was little evidence for desiccation. Under these (in contrast to the antarctic) marginally perturbed conditions, however, Cl0 was found to be dramatically enhanced such that a large fraction of the available (inorganic) chlorine resided in the form of Cl0 and its dimer ClOOCl. This leaves two abiding issues for the northern hemisphere and the mission of the second Airborne Arctic Stratospheric Expedition (AASE-II): (1) Will significant ozone erosion occur within the arctic vortex in the next ten years as chlorine loading in the stratosphere exceeds four parts per billion by volume? and (2) Which mechanisms are responsible for the observed ozone erosion poleward of 30 deg N in the winter/spring northern hemisphere reported in satellite observations?

Anderson, James G.↗

NASA NTRS1993

Ozone and aerosol changes during the 1991-1992 airborne Arctic stratospheric expedition

Stratospheric ozone and aerosol distributions were measured across the wintertime Arctic vortex from January to March 1992 with an airborne lidar system as part of the 1992 Airborne Arctic Stratospheric Expedition (AASE II). Aerosols from the Mount Pinatubo eruption were found outside and inside the vortex with distinctly different distributions that clearly identified the dynamics of the vortex. Changes in aerosols inside the vortex indicated advection of air from outside to inside the vortex below 16 kilometers. No polar stratospheric clouds were observed and no evidence was found for frozen volcanic aerosols inside the vortex. Between January and March, ozone depletion was observed inside the vortex from 14 to 20 kilometers with a maximum average loss of about 23 percent near 18 kilometers.

Browell, Edward V.↗

NASA NTRS1993

Numerical simulations of the formation and evolution of water ice clouds in the Martian atmosphere

A model of the formation, evolution, and description of Martian water ice clouds is developed which well reproduces the physical processes governing the microphysics of water ice cloud formation on Mars. The model is used to show that the cloud properties are most sensitive to the temperature profile, the number of days for which condensation previously occurred, the contact angle, and the presence of incoming meteoritic debris at the top of the atmosphere. The AM-PM differences in optical depths measured at the Viking Lander site were successfully simulated with the model, obtaining total column optical depths of ice of a few tenths in agreement with observations.

Michelangeli, Diane V.↗

NASA NTRS1993

Martian global dust storms - Zonally symmetric numerical simulations including size-dependent particle transport

A zonally symmetric primitive-equation grid-point model of the Martian atmosphere is coupled with an aerosol transport/microphysical model in order to numerically investigate the size-dependent transport of dust particles in the Martian atmosphere. The coupled model accounts for diabatic heating due to a radiatively active evolving dust field, but neglects feedbacks between atmosphere-surface interactions and surface dust lifting. The differing suspension lifetimes of dust particles of various sizes (radius = 1-80 microns), in conjunction with spatially varying atmospheric dynamics, result in latitudinal differences in several measurements of the column integrated particle concentration. This work indicates the importance of considering the full range of particle sizes (and shapes) of the suspended dust during Martian global dust storms and their impact upon the spatial extent and wavelength-dependent radiative influence of such storms.

Murphy, James R.↗

NASA NTRS1992

The potential effects of volcanic aerosols on cirrus cloud microphysics

The potential impact of volcanic aerosols on nucleation of ice crystals in upper tropospheric cirrus clouds is examined from a microphysical perspective. The sulfuric acid aerosols which form in the stratosphere are presumably transported into the troposphere by sedimentation and tropopause folding. The tropospheric volcanic aerosol size distribution is estimated from 10-micron lidar backscatter and in situ measurements. Microphysical simulations suggest that at temperatures below about -50 C the concentration of ice crystals which nucleate may be as much as a factor of 5 larger when volcanic aerosols are present. The simulations suggest that the presence of volcanic aerosols may increase the net radiative forcing (surface warming) of certain types of cirrus near the tropopause by as much as 8 W/sq m. Further observations are required to determine whether these effects actually occur, and their global impact.

Jensen, Eric J.↗

NASA NTRS1992

Titan's organic haze

The optical properties of the laboratory tholin is considered, and an attempt is made to critically evaluate the analog between laboratory tholin and Titan tholin. The processes that form the solid haze material from the gaseous atmosphere are considered. It is suggested that the N/C ratio may be a useful signature of the processes that determine the haze production rate.

Mckay, Christopher P.↗

NASA NTRS1991

Simulations of microphysical, radiative, and dynamical processes in a continental-scale forest fire smoke plume

The impact of a large forest fire smoke plume on atmospheric processes is studied through a numerical model of meteorology, aerosols, and radiative transfer. The simulated smoke optical depths at 0.63-micron wavelength are in agreement with analyses of satellite data and show values as high as 1.8. The smoke has an albedo of 35 percent, or more than double the clear-sky value, and cools the surface by as much as 5 K. An imaginary refractive index, n sub im, of 0.01 yields results which closely match the observed cooling, single scattering albedo, and the Angstrom wavelength exponent. An n exp im of 0.1, typical of smoke from urban fires, produces 9 K cooling. Coagulation causes the geometric mean radius by number to increase from the initial value of 0.08 micron to a final value of 0.15 micron, while the specific extinction and absorption increase by 40 and 25 percent, respectively.

Westphal, Douglas L.↗

NASA NTRS1991

Polar stratospheric clouds and the ozone hole

An account is given of physical processes governing the formation of stratospheric particles, in order to dramatize the interactions between polar stratospheric clouds and the Antarctic ozone-destruction mechanism. Attention is given to the successive stages of particle nucleation, condensation/evaporation and sedimentation/coagulation phenomena, and the ways in which polar stratospheric clouds are observed. Considerable evidence exists that polar stratospheric cloud particles are composed of nitric acid. The relatively small Arctic ozone hole depletion is due to the much smaller duration of Arctic stratospheric clouds.

Hamill, Patrick↗

NASA NTRS1991

Homogeneous freezing nucleation of stratospheric solution droplets

The classical theory of homogeneous nucleation was used to calculate the freezing rate of sulfuric acid solution aerosols under stratospheric conditions. The freezing of stratospheric aerosols would be important for the nucleation of nitric acid trihydrate particles in the Arctic and Antarctic stratospheres. In addition, the rate of heterogeneous chemical reactions on stratospheric aerosols may be very sensitive to their state. The calculations indicate that homogeneous freezing nucleation of pure water ice in the stratospheric solution droplets would occur at temperatures below about 192 K. However, the physical properties of H2SO4 solution at such low temperatures are not well known, and it is possible that sulfuric acid aerosols will freeze out at temperatures ranging from about 180 to 195 K. It is also shown that the temperature at which the aerosols freeze is nearly independent of their size.

Jensen, Eric J.↗

NASA NTRS1991

The short-term temperature response to smoke from oil fires

The short-term effect of smoke, similar to that being emitted from the Kuwaiti oil fields, on the ground temperature of the afffected region was investigated using a numerical model of atmospheric dynamics, aerosol microphysics, and radiative transfer similar to that used previosly by Westphal and Toon (1991). Results show that, after one diurnal cycle beneath smoke plumes of moderate visible absorption, ground cooling and ground warming were both possible; the response of the ground temperature and the boundary layer dynamics depended on the surface characteristics, with desert exhibiting the strongest cooling of all the land types used.

Westphal, Douglas L.↗

NASA NTRS1991

Application of physical adsorption thermodynamics to heterogeneous chemistry on polar stratospheric clouds

Laboratory isotherms for the binding of several nonheterogeneously active atmospheric gases and for HCl to water ice are translated into adsorptive equilibrium constants and surface enthalpies. Extrapolation to polar conditions through the Clausius Clapeyron relation yields coverage estimates below the percent level for N2, Ar, CO2, and CO, suggesting that the crystal faces of type II stratospheric cloud particles may be regarded as clean with respect to these species. For HCl, and perhaps HF and HNO3, estimates rise to several percent, and the adsorbed layer may offer acid or proton sources alternate to the bulk solid for heterogeneous reactions with stratospheric nitrates. Measurements are lacking for many key atmospheric molecules on water ice, and almost entirely for nitric acid trihydrate as substrate. Adsorptive equilibria enter into gas to particle mass flux descriptions, and the binding energy determines rates for desorption of, and encounter between, potential surface reactants.

Elliott, Scott↗