Engineering topics

Toon, Owen B.

Publications and source records attributed to Toon, Owen B..

102 records · Page 6

NASA NTRS1989

Relation between increasing methane and the presence of ice clouds at the mesopause

The possiblity is investigated that a substantial change has occurred in middle-atmospheric water vapor as a result of the increase in atmospheric methane over the past century and a half. It is shown from modeling of mesospheric ice-particle formation that noctilucent cloud brightness should be a sensitive indicator of the water content at the high-latitude summertime mesopause. From an examination of the historical record of noctilucent cloud occurrence, it is found that such clouds are absent from the record before 1885, a finding which is consistent with the hypothesis proposed in this paper.

Thomas, Gary E.↗

NASA NTRS1988

Methane rain on Titan

The atmosphere of Titan is characterized by means of model computations based on Voyager IRIS IR spectra and published data from laboratory determinations of absorption coefficients and cloud refractive indices. The results are presented in tables and graphs, and it is pointed out that the presence of Ar is not required in the model. Particular attention is given to the role of CH4, which is found to form patchy clouds (with particle radii of 50 microns or greater and visible/IR optical depths of 2-5) at altitudes up to about 30 km. The mechanisms by which such rain-sized particles could form are discussed, and it is suggested that the observed 500-600/cm spectrum is affected much less by the CH4 clouds than by H2 or variations in the temperature of the high-altitude haze.

Toon, Owen B.↗

NASA NTRS1988

A case study of mobilization and transport of Saharan dust

The mobilization and transport of the Saharan dust over the West Africa and the tropical Atlantic Ocean during the days of August 23-28, 1974, were investigated using the data set developed by GFDL, together with numerical models of the atmosphere and aerosol. It was found that the mobilization of dust during this period was related to the passage of a shallow easterly wave; mobilization was effected by dry convective mixing of low-level jets associated with the easterly wave. Model simulations show that the aerosol at any one point can be a complicated mixture of particles lifted at different times and different places; bimodal size distributions developed when dust was mobilized within a dust plume that was generated on a previous day.

Westphal, Douglas L.↗

NASA NTRS1988

On the size and composition of particles in polar stratospheric clouds

Attenuation measurements of the solar radiation between 1.5 and 15 micron wavelengths were performed with the airborne (DC-8) JPL MARK 4 interferometer during the 1987 Antarctic Expedition. The opacities not only provide information about the abundance of stratospheric gases but also about the optical depths of polar stratospheric clouds (PSCs) at wavelengths of negligible gas absorption (windows). The optical depth of PSCs can be determined for each window once the background attenuation, due to air-molecules and aerosol has been filtered out with a simple extinction law. The ratio of optical thicknesses at different wavelengths reveals information about particle size and particle composition. Among the almost 700 measured spectra only a few PSC cases exist. PSC events are identified by sudden reductions in the spectrally integrated intensity value and are also verified with backscattering data from an upward directed lidar instrument, that was mounted on the DC-8. For the selected case on September 21st at 14.40 GMT, lidar data indicate an optically thin cloud at 18k and later an additional optically thick cloud at 15 km altitude. All results still suffer from: (1) often arbitrary definitions of a clear case, that often already may have contained PSC particles and (2) noise problems that restrict the calculations of optical depths to values larger than 0.001. Once these problems are handled, this instrument may become a valuable tool towards a better understanding of the role PSCs play in the Antarctic stratosphere.

Kinne, Stefan↗

NASA NTRS1988

Physical processes in polar stratospheric ice clouds

A one dimensional model of cloud microphysics was used to simulate the formation and evolution of polar stratospheric ice clouds. Some of the processes which are included in the model are outlined. It is found that the clouds must undergo preferential nucleation upon the existing aerosols just as do tropospheric cirrus clouds. Therefore, there is an energy barrier between stratospheric nitric acid particles and ice particles implying that nitric acid does not form a continuous set of solutions between the trihydrate and ice. The Kelvin barrier is not significant in controlling the rate of formation of ice particles. It was found that the cloud properties are sensitive to the rate at which the air parcels cool. In wave clouds, with cooling rates of hundreds of degrees per day, most of the existing aerosols nucleate and become ice particles. Such clouds have particles with sizes on the order of a few microns, optical depths on order of unity and are probably not efficient at removing materials from the stratosphere. In clouds which form with cooling rates of a few degrees per day or less, only a small fraction of the aerosols become cloud particles. In such clouds the particle radius is larger than 10 microns, the optical depths are low and water vapor is efficiently removed. Seasonal simulations show that the lowest water vapor mixing ratio is determined by the lowest temperature reached, and that the time when clouds disappear is controlled by the time when temperatures begin to rise above the minimum values.

Toon, Owen B.↗

NASA NTRS1988

How climate evolved on the terrestrial planets

It is argued that the difference in the climates of Venus, earth, and Mars is due largely to differences in their ability to cycle CO2 between the crust and atmosphere. It is suggested that the earth has always had a moderate climate primarily because its cycling mechanism increases the amount of CO2 in the atmosphere when the surface of the planet cools and reduces the amount when the ground temperature rises. Mars is now frozen because it has lost the ability to cycle the gas back into its atmosphere, and Venus is a hothouse because it has no way of removing CO2 from its atmosphere.

Kasting, James F.↗

NASA NTRS1988

Atmospheric effects of a Canadian forest fire smoke plume

In 1982, a northern British Columbia forest fire created a massive smoke plume that could be detected for several days in satellite imagery. The radiative and dynamical impacts of this large forest fire smoke plume are investigated using interactive prognostic models of atmospheric circulation, aerosol microphysics and transport, and radiative heat transfer.

Westphal, Douglas L.↗

NASA NTRS1987

A two-dimensional numerical investigation of the dynamics and microphysics of Saharan dust storms

Two-dimensional numerical simulations of the spatial and temporal distributions of Saharan dust size distributions over the desert and the eastern Atlantic Ocean are presented. The simulations show that during mobilization the soil size distribution is modified by either a size-dependent lifting mechanism or by mixing of local soil with aged aerosols or with aerosols originating from nearby soils which have different size distributions. When the source region is near the coast, as opposed to the central Sahara, the highest mass concentration achieved at Sal Island is more than doubled. However, in the two-dimensional simulations the central Saharan storms seem to be equally as important as coastal sources in terms of the optical properties of an outbreak.

Westphal, Douglas L.↗

NASA NTRS1987

The sulfur cycle in the marine atmosphere

The simulation of the sulfur cycle in the marine atmosphere using a one-dimensional photochemical model is described and evaluated. Theoretical uncertainties concerning the operation of the marine sulfur cycle are examined, and measurements of sulfur gases in the marine atmosphere necessary for developing the model are derived. Previous modeling studies are reviewed, and the data from these studies are compared to the model simulations. Recommendations for improving the simulation of the sulfur cycle in the marine atmosphere are discussed.

Toon, Owen B.↗

NASA NTRS1986

Condensation of HNO3 and HCl in the winter polar stratospheres

Nitric acid and hydrochloric acid vapors may condense in the winter polar stratospheres. Nitric acid clouds, unlike water ice clouds, would form at the temperatures at which polar stratospheric clouds (PSCs) are observed and would have optical depths of the magnitude observed suggesting that HNO3 is a dominant component of PSCs. ClO, N2O5 and ClNO3 may react on cloud particle surfaces yielding additional HNO3, HCl, and HOCL. In the vicinity of PSCs these reactions could deplete the stratosphere of photochemically active NO(x) species. The sedimentation of PSCs may remove these materials from the stratosphere. The loss of vapor phase NO(x) might allow halogen-based chemistry to create the ozone hole.

Toon, Owen B.↗

NASA NTRS1985

Theoretical studies of the marine sulfur cycle

Several reduced sulfur compounds are produced by marine organisms and then enter the atmosphere, where they are oxidized and ultimately returned to the ocean or the land. The oceanic dimethyl sulfide (DMS) flux, in particular, represents a significant fraction of the annual global sulfur input to the atmosphere. In the atmosphere, this gas is converted to sulfur dioxide (SO2), methane sulfonic acid, and other organic acids which are relatively stable and about which little is known. SO2 is a short lived gas which, in turn, is converted to sulfuric acid and other sulfate compounds which contribute significantly to acid rain. Because of the complexity of the sulfur system, it is not well understood even in the unperturbed atmosphere. However, a number of new observations and experiments have led to a significant increase in the understanding of this system. A number of one dimensional model experiments were conducted on the gas phase part of the marine sulfur cycle. The results indicate the measured concentration of DMS and the amplitude of its diurnal cycle are in agreement with estimates of its global flux. It was also found that DMS can make a large contribution to the background SO2 concentration in the free troposphere. Estimates of CS2 concentrations in the atmosphere are inconsistent with estimated fluxes; however, measured reaction rates are consistent with the observed steep tropospheric gradient in CS2. Observations of CS2 are extremely sparse. Further study is planned.

Toon, Owen B.↗

NASA NTRS1984

The numerical simulation of the evolution of a Saharan dust outbreak by using a general prognostic aerosol model

A three-dimensional model is developed that explicitly predicts the evolution of the spatial distributions of aerosols utilizing a time-dependent, initial value prognostic aerosol model based on aerosol physicochemical processes, a knowledge of aerosol sinks and sources, and the predicted motions of the atmosphere. These models serve a useful purpose in determining standardized aerosol spectra for utilization in radiative transfer calculations. The first numerical prediction of a Saharan dust outbreak evolution is described. It is shown that the results are in qualitative agreement with measurements despite the fact that in this preliminary simulation the generation of the dust depended upon several empirically based assumptions. IR satellite photographs taken during GATE are being examined in an attempt to determine the sources of the dust.

Westphal, Douglas L.↗