A Stable Aluminum Tris(dithiolene) Triradical
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Engineering topics
Tran, Phuong M.
Publications and source records attributed to Tran, Phuong M..
Unusual nucleophilic reactivity of a dithiolene-based N-heterocyclic silane
Dithiolene-based N-heterocyclic silane demonstrates unusual dual nucleophilic reactivity toward boron halides.
Chemistry↗
From Carbene-Dithiolene Zwitterion Mediated B–H Bond Activation to BH 3 ·SMe 2 -Assisted Boron–Boron Bond Formation
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Germanium(II) Dithiolene Complexes
The 1 : 2 reaction of the imidazole-based dithiolate (2) with GeCl 2 • dioxane in THF/TMEDA gives 3, a TMEDA-complexed dithiolene-based germylene. Compound 3 is converted to monothiolate-complexed (5) and N-heterocyclic carbene-complexed (7) germanium(II) dithiolene complexes via Lewis base ligand exchange. A bis-dithiolene-based germylene (8), involving a 3c–4e S-Ge-S bond, has also been synthesized through controlled hydrolysis of 7. The bonding nature of 3, 5, and 8 was investigated by both experimental and theoretical methods.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗